Optoelectronic devices and coatings therefore
View Patent ↗An optoelectronic device assembly can include: a coated element and an optoelectronic device on the coated element. The coated element can include a thermoplastic substrate and a protective weathering layer. The thermoplastic substrate can include a bisphenol-A polycarbonate homopolymer and a polycarbonate copolymer, and wherein the polycarbonate copolymer is selected from a copolymer of tetrabromobisphenol A carbonate and BPA carbonate; a copolymer of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine carbonate and BPA carbonate; a copolymer of 4,4′-(1-phenylethylidene) biphenol carbonate and BPA carbonate; a copolymer of 4,4′-(1-methylethylidene) bis[2,6-dimethyl-phenol]carbonate and BPA carbonate; and combinations comprising at least one of the foregoing. The protective weathering layer can include resorcinol polyarylate and polycarbonate.
1. An optoelectronic device assembly comprising:
a coated element, comprising
thermoplastic substrate comprising a bisphenol-A polycarbonate homopolymer and a polycarbonate copolymer, and wherein the polycarbonate copolymer is selected from a copolymer of tetrabromobisphenol A carbonate and BPA carbonate; a copolymer of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine carbonate and BPA carbonate; a copolymer of 4,4′-(1-phenylethylidene)biphenol carbonate and BPA carbonate; a copolymer of 4,4′-(1-methylethylidene)bis[2,6-dimethyl-phenol]carbonate and BPA carbonate; and combinations comprising at least one of the foregoing; and
a protective weathering layer comprising resorcinol polyarylate and polycarbonate; and
an optoelectronic device on the coated element, wherein the optoelectronic device is selected from a light emitting diode and a photovoltaic cell.
2. The assembly of claim 1 , wherein the protective weathering layer comprises greater than or equal to 2.5 wt % of a UV absorbers, based upon a total weight of the protective weathering layer, wherein the UV absorber is selected from 4,6-dibenzoylresorcinol, silylated 4,6-dibenzoylresorcinols, 2,4-diphenyl-6-(2′-hydroxy-4′alkoxyphenyl)-1,3,5-triazines, and combinations comprising at least one of the foregoing.
3. The assembly of claim 1 , wherein the protective weathering layer comprises triazine of the formula:
wherein R 1 =H, R 2 , R 3 =independently H, aliphatic C 1 -C 12 , cycloaliphatic C 3 -C 12 , or aromatic, R 4 =H, C 1 -C 24 aliphatic, or C 3 -C 24 cycloaliphatic.
4. The assembly of claim 3 , wherein R 1 , R 2 , and R 3 =H.
5. The assembly of claim 4 , wherein R 4 =C 6 H 13 .
6. The assembly of claim 4 , wherein R 4 =CH 2 CH 2 OOCC 7 H 15 .
7. The assembly of claim 1 , wherein the protective weathering layer comprises a block copolymer comprising the resorcinol polyarylate and the polycarbonate, and wherein the block copolymer has a resorcinol polyarylate block content of less than or equal to 40 wt %.
8. The assembly of claim 1 , wherein the protective weathering layer further comprises a matrix selected from silicone, poly(meth)acrylates, polycarbonates, and combinations comprising at least one of the foregoing.
9. The assembly of claim 1 , wherein the protective weathering layer has an engineered surface texture selected from a plurality of lenses, microlenses, linear prisms, prisms, pyramids, lenticular structures, and combinations comprising at least one of the foregoing.
10. The assembly of claim 9 , wherein the engineered surface texture is on a side of the protective weathering layer opposite the thermoplastic substrate.
11. The assembly of claim 1 , wherein the thermoplastic substrate has a thermal shrinkage ratio less than 1% along both the extrusion direction and the cross-web direction after a 30-minute treatment at 150° C.
12. The assembly of claim 1 , wherein the thermoplastic substrate and protective weathering layer are co-extruded.
13. The assembly of claim 1 , further comprising a barrier coating layer comprising at least one zone substantially organic in composition and at least one zone substantially inorganic in composition.
14. The assembly of claim 1 , further comprising a planarizing layer selected from an epoxy based resin, an acrylic based resin, a silicone resin, and a combination comprising at least one of the foregoing.
15. The assembly of claim 14 , wherein the planarizing layer has a thickness of 1 nm to 100 μm.
16. The assembly of claim 1 , further comprising a UV-cured acrylic-colloidal silica coating layer.
17. The assembly of claim 1 , wherein the protective weathering layer comprises dibenzoylresorcinol of the formula:
wherein R 5 =H, aliphatic C 1 -C 12 , cycloaliphatic C 3 -C 12 , CH 2 CH 2 CH 2 SiR n (OR 8 ) 3-n , n=0-2, R 8 =H, aliphatic C 1 -C 12 ; and R 6 , R 7 =independently H, aliphatic C 1 -C 12 , cycloaliphatic C 3 -C 12 , or aromatic.
18. The assembly of claim 17 , wherein R 5 , R 6 , and R 7 =H.
19. The assembly of claim 1 , wherein the protective weathering layer comprises dibenzoylresorcinol of the formula:
wherein R 9 , R 10 , R 11 , R 12 are independently H, aliphatic C 1 -C 12 , cycloaliphatic C 3 -C 12 , or aromatic.
20. The assembly of claim 19 , wherein the thermoplastic polycarbonate comprises a bisphenol-A polycarbonate homopolymer and a polycarbonate copolymer, and wherein the polycarbonate copolymer is selected from a copolymer of tetrabromobisphenol A carbonate and BPA carbonate; a copolymer of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine carbonate and BPA carbonate; a copolymer of 4,4′-(1-phenylethylidene)biphenol carbonate and BPA carbonate; a copolymer of 4,4′-(1-methylethylidene)bis[2,6-dimethyl-phenol]carbonate and BPA carbonate; and combinations comprising at least one of the foregoing.
21. The assembly of claim 1 , further comprising a primer located between the weathering layer and the thermoplastic substrate.
22. The assembly of claim 1 , further comprising an adhesive layer located between the optoelectronic device and the thermoplastic substrate.
23. An optoelectronic device assembly comprising:
a coated element, comprising
thermoplastic substrate comprising a material selected from aromatic polycarbonate and polyester, and combinations comprising at least one of the foregoing materials; and
a protective weathering layer comprises a UV absorber and a block copolymer comprising the resorcinol polyarylate and the polycarbonate, wherein the block copolymer has a resorcinol polyarylate block content of less than or equal to 40 wt %;
an optoelectronic device on the coated element, wherein the optoelectronic device is selected from a light emitting diode and a photovoltaic cell.
24. The assembly of claim 23 , wherein the thermoplastic substrate comprises a bisphenol-A polycarbonate homopolymer and a polycarbonate copolymer, and wherein the polycarbonate copolymer is selected from a copolymer of tetrabromobisphenol A carbonate and BPA carbonate; a copolymer of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine carbonate and BPA carbonate; a copolymer of 4,4′-(1-phenylethylidene)biphenol carbonate and BPA carbonate; a copolymer of 4,4′-(1-methylethylidene)bis[2,6-dimethyl-phenol]carbonate and BPA carbonate; and combinations comprising at least one of the foregoing.
25. The assembly of claim 23 , wherein the protective weathering layer has a UV absorbance loss rate at 330 nm of less than or equal to 0.15 A/year as estimated from filtered xenon arc exposure and/or having a rate of erosion of less than or equal to 5 μm per year as estimated from filtered xenon arc exposure.