Fluorinated compound and fluorinated polymer
View Patent ↗To provide a fluorinated compound having an R F group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH 2 ═C(M)COO(CH 2 ) n PhXPhZC r F 2r+1 (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, X is CH 2 O or OCH 2 , Z is a single bond, a C 1-4 alkylene group containing an etheric oxygen atom, or COO(CH 2 ) m (wherein m is an integer of from 1 to 4), and r is an integer of from 1 to 6).
1. A fluorinated compound represented by the following formula (I):
CH 2 ═C(M)COO(CH 2 ) n PhXPhZC r F 2r+1 (I)
wherein M is a hydrogen atom, a methyl group or a halogen atom, n is 1 or 2, each Ph is a phenylene group, X is CH 2 O or OCH 2 , Z is a single bond, a C 1-4 alkylene group containing an etheric oxygen atom, or COO(CH 2 ) m ,
wherein m is an integer of from 1 to 4, and r is an integer of from 1 to 6.
2. The fluorinated compound according to claim 1 , wherein at least one Ph in the formula (I) is a 1,4-phenylene group.
3. The fluorinated compound according to claim 1 , wherein r in the formula (I) is an integer of from 2 to 6.
4. The fluorinated compound according to claim 3 , wherein r in the formula (I) is an integer of from 4 to 6.
5. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by any one of the following formulae (I-1) to (I-5):
6. The fluorinated compound according to claim 1 , wherein in the formula (I), r is an integer of from 4 to 6, and C r F 2r+1 is linear.
7. The fluorinated compound according to claim 1 , wherein each Ph in the formula (I) is a 1,4-phenylene group.
8. The fluorinated compound according to claim 1 , wherein M in the formula (I) is a methyl group.
9. The fluorinated compound according to claim 1 , wherein X in the formula (I) is OCH 2 .
10. The fluorinated compound according to claim 1 , wherein Z in the formula (I) is —(CH 2 ) p —O—(CH 2 ) q —, wherein p an integer of is from 0 to 2, and q is an integer of from 1 to 4, provided that p+q=1 to 4.