Phase-changing material microcapsules by using PMMA prepolymer and organic-solvent free synthesis process
Phase change material microcapsules are obtained using a PMMA prepolymer and an organic-solvent free synthesis process. A polymer monomer and an initiator are subject to pre-polymerization in a water bath to form Polymethyl methacrylate (PMMA) prepolymer which is then prepared to be a stabilizer aqueous solution. A phase change material is added to the stabilizer aqueous solution and liquefied in advance, and stirred to form an emulsion by a homogenizing mixer. A starting agent, a cross-linking agent and a Polymethyl methacrylate methyl ester prepolymer are added to the emulsion containing the phase-change material. The emulsion is further stirred by the homogenizing mixer for micro-emulsification which then aggregates in water bath. In this way, the process may use organic-solvent free process to pre-polymerize the polymer monomer into a Polymethyl methacrylate prepolymer and carries out encapsulation and polymerization at an oil-water interface to achieve the preparation of phase change material microcapsules.
1. A method of synthesizing phase change material microcapsules using polymethyl methacrylate (PMMA) pre-polymer, the method comprising:
pre-polymerizing a polymer monomer and a first initiator of benzoyl peroxide (BPO) in an organic-solvent free water bath so as to form PMMA prepolymers;
preparing a stabilizer aqueous solution;
adding a phase change material to the stabilizer aqueous solution for liquefaction; and
adding a second initiator, a cross-linking agent and the polymethyl methacrylate prepolymer are added to the emulsion containing the phase change material, and the emulsion is further stirred for 3 minutes by a homogenizing mixer for micro-emulsion and followed by subject to polymerization in a water bath to produce phase change material microcapsules,
wherein the cross-linking agent is selected from one of 1,4-butanediol diacrylate, triallyl isocyanurate, butyl acrylate, 2-hydroxyethyl acrylate, hydroxygropvl acrylate, 2-hydroxyethyl methacrylate, and hydrolyzed golymaleic anhydride.
2. The method of claim 1 , wherein the polymer monomer is methyl methacrylate (MMA).
3. The method of claim 1 , wherein the amount of the first initiator based on the polymer monomer is 0.1 wt. %.
4. The method of claim 1 , comprising preparing the polymethyl methacrylate prepolymer at 60° C. to 90° C.
5. The method of claim 1 , comprising preparing the polymethyl methacrylate prepolymer for 5 minutes to 90 minutes.
6. The method of claim 1 , wherein the concentration of the stabilizer in water is between 0.01 to 1%.
7. The method of claim 1 , wherein the stabilizer is selected from one of polyvinyl pyrrolidone (PVP), polyethylene glycol (PEG), TWEEN, and SPAN.
8. The method of claim 1 , wherein the phase change material is organic paraffin having 14-44 carbons.
9. The method of claim 1 , comprising stirring the stabilizer aqueous solution after liquefaction for 1 minute by a homogenizing mixer at 3000-12000 r.p.m. to form the emulsion.
10. The method of claim 1 , wherein the second initiator is benzoyl peroxide (BPO), or 2,2-azobisisobutyronitrile (AIBN).
11. The method of claim 1 , wherein the amount of the second initiator based on the polymer monomer is 0.5-5 wt. %.
12. The method of claim 1 , wherein the amount of the cross-linking agent based on the polymer monomer is between 5 wt. % to 30 wt. %.
13. The method of claim 1 , further comprising stirring the emulsion for 3 minutes by a homogenizing mixer at 3000-12000 r.p.m. for micro-emulsion.
14. The method of claim 1 , wherein the temperature for the polymerization in water bath is carried out at 60° C. to 90° C.
15. The method of claim 1 , wherein the phase change material microcapsules produced have a particle size of 2 to 22 micrometers.