Polyamide-sheathed structural steel tubes for offshore structures
View Patent ↗The foundation structure of an offshore structure, for example of an offshore wind energy system, is composed of steel tubes sheathed by an extruded layer made of a polyamide moulding composition. This simultaneously ensures both good protection from corrosion and good protection from mechanical effects, giving the foundation structure markedly prolonged lifetime.
1. An offshore structure comprising a foundation structure wherein a steel tube sheathed by an extruded layer is incorporated into the foundation structure, wherein said extruded layer comprises a polyamide moulding composition.
2. The offshore structure of claim 1 , wherein the extruded layer comprises the polyamide moulding composition having a thickness of from 0.5 to 30 mm.
3. The offshore structure of claim 2 , wherein the offshore structure is an offshore wind energy system.
4. The offshore structure of claim 3 , wherein the foundation structure is a monopile, a jacket, a tripod, a quadropod or a tripile.
5. The offshore structure of claim 2 , wherein the extruded layer is prepared by a process comprising:
a) mixing the polyamide moulding composition and a molecular-weight-increasing additive to form a mixture,
b) extruding the mixture, and
c) condensing the mixture, wherein the condensation process to increase molecular weight is delayed until extrusion has begun.
6. The offshore structure of claim 1 , wherein between the steel tube and the extruded layer comprising the polyamide moulding composition there is at least one further layer selected from the group consisting of
a ceramic layer
a primer layer
an adhesion-promoter layer and
a textile reinforcement layer.
7. The offshore structure of claim 6 , wherein between the steel tube and the layer comprising the polyamide moulding composition there is a textile reinforcement layer that is woven or matted.
8. The offshore structure of claim 1 , wherein the extruded polyamide moulding composition has a viscosity at 240° C. and at a shear rate of 0.1 1/s in accordance with ASTM D4440-3 is at least 2000 Pa·s.
9. The offshore structure of claim 1 , wherein the relative solution viscosity η rel of the polyamide in the extruded moulding composition has a relative solution viscosity η rel in accordance with ISO 307 of at least 1.5.
10. The offshore structure of claim 1 , wherein the polyamide moulding composition further comprises at least one other component selected from the group consisting of an impact modifier, a thermoplastic, and a plasticizer.
11. The offshore structure of claim 1 , wherein the polyamide moulding composition comprises
a) from 60 to 96.5 parts by weight of polyamide,
b) from 3 to 39.5 parts by weight of an impact-modifying component which comprises anhydride groups, where the impact-modifying component has been selected from the group consisting of ethylene/α-olefin copolymers and styrene-ethylene/butylene block copolymers,
c) from 0.5 to 20 parts by weight of a copolymer which comprises:
i) from 20to 94.5% by weight of one or more α-olefins having from 2 to 12 carbon atoms,
ii) from 5 to 79.5% by weight of one or more acrylic compounds selected from
acrylic acid, methacrylic acid and salts thereof,
esters of acrylic acid or, respectively, methacrylic acid with a C 1 -C 12 alcohol, which optionally bear a free hydroxy or epoxy function,
acrylonitrile or methacrylonitrile,
acrylamides or methacrylamides,
iii) from 0.5 to 50% by weight of an olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline or oxazinone,
where the total of the parts by weight of components a) b) and c) is 100.
12. The offshore structure of claim 1 , wherein the polyamide moulding composition comprises:
a) from 65 to 90 parts by weight of polyamide,
b) from 5 to 30 parts by weight of an impact-modifying component,
c) from 0.6 to 15 parts by weight of a copolymer comprising units of the following monomers:
i) from 30 to 80% by weight of an α-olefin,
ii) from 7 to 70% by weight of an acrylic compound, and
iii) from 1 to 40% by weight of the olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline, or oxazinone.
13. The offshore structure of claim 1 , wherein the extruded layer is formed by a process comprising:
a) mixing the polyamide moulding composition and a molecular-weight-increasing additive to form a mixture,
b) extruding the mixture, and
c) condensing the mixture, wherein the condensation process to increase molecular weight is delayed until extrusion has begun.
14. The offshore structure of claim 13 , wherein the molecular-weight-increasing additive is a compound having at least two carbonate units.
15. The offshore structure of claim 1 , wherein the polyamide moulding composition comprises from 1 to 25% by weight of plasticizer.
16. The offshore structure of claim 1 , wherein said offshore structure is an offshore wind energy system.
17. The offshore structure of claim 1 , wherein the polyamide moulding composition comprises:
a) from 60 to 96.5 parts by weight of polyamide,
b) from 3 to 39.5 parts by weight of an impact-modifying component which comprises anhydride groups, where the impact-modifying component has been selected from the group consisting of ethylene/α-olefin copolymers and styrene-ethylene/butylene block copolymers,
c) from 0.5 to 20 parts by weight of a copolymer which comprises:
i) from 20 to 94.5% by weight of one or more α-olefins having from 2 to 12 carbon atoms,
ii) from 5 to 79.5% by weight of one or more acrylic compounds selected from
acrylic acid, methacrylic acid and salts thereof,
esters of acrylic acid or, respectively, methacrylic acid with a C 1 -C 12 alcohol, which optionally bear a free hydroxy or epoxy function,
acrylonitrile or methacrylonitrile,
acrylamides or methacrylamides,
iii) from 0.5 to 50% by weight of an olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline or oxazinone,
where the total of the parts by weight of components a) b) and c) is 100.
18. The offshore structure of claim 1 , wherein the polyamide moulding composition comprises:
a) from 65 to 90 parts by weight of polyamide,
b) from 5 to 30 parts by weight of an impact-modifying component,
c) from 0.6 to 15 parts by weight of a copolymer comprising units of the following monomers:
i) from 30 to 80% by weight of an α-olefin,
ii) from 7 to 70% by weight of an acrylic compound, and
iii) from 1 to 40% by weight of the olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline, or oxazinone.
19. The offshore structure of claim 1 , which is a drilling platform.
20. The offshore structure of claim 1 , which is a lighthouse.