Nanoscopic wire-based devices and arrays
View Patent ↗Electrical devices comprised of nanoscopic wires are described, along with methods of their manufacture and use. The nanoscopic wires can be nanotubes, preferably single-walled carbon nanotubes. They can be arranged in crossbar arrays using chemically patterned surfaces for direction, via chemical vapor deposition. Chemical vapor deposition also can be used to form nanotubes in arrays in the presence of directing electric fields, optionally in combination with self-assembled monolayer patterns. Bistable devices are described.
1. An article, comprising:
a nonvolatile memory element comprising an electrical crossbar junction defined by a conductor and a carbon nanotube crossing the conductor at an intersection, wherein the carbon nanotube is movable to a first configuration in direct physical contact with the conductor by application of dissimilar biasing electrical potential to the conductor and the carbon nanotube, and the carbon nanotube is movable to a second configuration not in direct physical contact with the conductor by application of similar biasing electrical potential to the conductor and the carbon nanotube.
2. The article of claim 1 , wherein the conductor and the carbon nanotube, when in direct physical contact with each other, maintain direct physical contact via a van der Waals interaction.
3. The article of claim 1 , wherein the carbon nanotube has sufficient stiffness to remain free of contact with the conductor in the absence of dissimilar biasing electrical potential.
4. The article of claim 1 , wherein the conductor is positioned on a substrate.
5. The article of claim 4 , wherein the conductor is positioned intermediate the substrate and the carbon nanotube.
6. The article of claim 5 , wherein the carbon nanotube is supported above the conductor, relative to the substrate.
7. The article of claim 1 , wherein the first configuration and the second configuration are each stable without the need for applied energy to maintain either the first configuration or the second configuration.
8. An article comprising:
an electrical crossbar array comprising a conductor and a nanotube crossing the conductor at an intersection defining a memory element capable of being switched reversibly between at least two readable states, wherein the nanotube is constructed and arranged to be reversibly movable from a first configuration to a second configuration.
9. The article of claim 8 , wherein the nanotube is a carbon nanotube.
10. The article of claim 9 , wherein the carbon nanotube is a single-walled carbon nanotube.
11. The article of claim 9 , wherein the carbon nanotube is a multiwall carbon nanotube.
12. The article of claim 8 , wherein the nanotube is a semiconducting nanotube.
13. The article of claim 8 , wherein the nanotube is a metallic nanotube.
14. The article of claim 8 , wherein the conductor is a metallic conductor.
15. The article of claim 8 , wherein the conductor is a semiconductor.
16. The article of claim 8 , wherein the conductor is a second nanotube.
17. The article of claim 8 , wherein the conductor and the nanotube are in direct physical contact with each other.
18. The article of claim 17 , wherein the conductor and the nanotube maintain direct physical contact with each other via a van der Waals interaction.
19. The article of claim 8 , wherein the conductor and the nanotube are capable of being brought into direct physical contact with each other by biasing the conductor and the nanotube with dissimilar electrical potential, and released from direct physical contact with each other by biasing the conductor and the nanotube with similar electrical potential.
20. The article of claim 8 , wherein information stored in the memory element is non-volatile.