Phosphorus free flame retardant composition
View Patent ↗Phosphorus free polycarbonate compositions having flame retardant properties and a desirable balance of flow, impact resistance, and heat deflection properties are disclosed.
1. A polycarbonate composition having two or more of the following:
(a) a melt volume rate of a polycarbonate component of at least about 16 cc/10 min, when measured at 260° C. and utilizing a 5 kg load;
(b) a notched Izod impact value of at least about 500 J/m; or
(c) a heat deflection temperature at 1.8 MPa flatwise mode of at least about 105° C.;
wherein the polycarbonate composition is free of a phosphorus based additive, wherein the polycarbonate composition is free of bromine; and wherein the polycarbonate composition comprises one or more of a nitrile polycarbonate, a phthalimide copolymer, or a combination thereof; and one or more of (i) a polymethyl methacrylate grafted silicone having a siloxane content from about 50 weight % to about 75 wt % and acrylic rubber, or (ii) a polyalkylene glycol having a molecular weight (Mn) of about 2,000 g/mol; and wherein the polycarbonate composition has a flame resistance rating of V0 when measured at 1.6 mm thickness, according to UL94 standards.
2. The polycarbonate composition of claim 1 , having a, b, and c.
3. The polycarbonate composition of claim 1 , having a melt volume rate of the polycarbonate component of at least about 30/cc. 10 min, when measured at 260° C. and utilizing a 5 kg load.
4. The polycarbonate composition of claim 1 , having a notched Izod impact value of at least about 600 J/m.
5. The polycarbonate composition of claim 1 , having a melt volume rate of the polycarbonate component of at least about 30 cc/10 min, when measured at 260° C. and utilizing a 5 kg load, and at least one of b and c.
6. The polycarbonate composition of claim 1 , wherein a polycarbonate component has a melt volume rate of from about 4 cc/10 min to about 14 cc/10 min, when measured at 300° C. with a 1.2 kg load.
7. The polycarbonate composition of claim 6 , wherein the polycarbonate component has from about 55 wt. % to about 80 wt. % of a bisphenol A-based polycarbonate.
8. The polycarbonate composition of claim 1 , wherein the phthalimide copolymer comprises a copolymer of 2-phenyl-3,3′-bis(4-hydroxyphenyl)phthalimide and bisphenol-A.
9. The polycarbonate composition of claim 8 , wherein the phthalimide copolymer comprises up to about 20 wt. % of 2-phenyl-3,3′-bis(4-hydroxyphenyl)phthalimide and bisphenol-A copolymer.
10. The polycarbonate composition of claim 1 , comprising a polycarbonate siloxane copolymer and/or a combination of a polycarbonate siloxane copolymer and a polycarbonate resin, wherein the siloxane content in the copolymer is from about 10 wt. % to about 30 wt. %.
11. The polycarbonate composition of claim 10 , wherein the siloxane content in the copolymer is from about 8 wt. % to about 18 wt. %.
12. The polycarbonate composition of claim 1 , comprising a poly(styrene-co-acrylonitrile) copolymer having a styrene content of about 75 wt. % and an acrylonitrile content of about 25 wt. %.
13. The polycarbonate composition of claim 12 having up to about 5 wt. % of the poly(styrene-co-acrylonitrile) copolymer.
14. The polycarbonate composition of claim 1 , having up to about 5 wt. % of a siloxane based impact modifier.
15. The polycarbonate composition of claim 1 , comprising polytetrafluoroethylene encapsulated (72:28 w/w) styrene-acrylonitrile copolymer.
16. The polycarbonate composition of claim 15 having up to about 0.5 wt. % of the polytetrafluoroethylene encapsulated (72:28 w/w) styrene-acrylonitrile copolymer.
17. The polycarbonate composition of claim 1 , wherein the polyalkylene glycol comprises polyethylene glycol.
18. The polycarbonate composition of claim 1 , wherein the nitrile polycarbonate comprises from about 5 wt. % to about 10 wt. % of the composition.
19. The polycarbonate composition of claim 1 , having a Vicat softening temperature of at least about 110° C. and a heat deflection temperature of at least about 100° C.
20. The polycarbonate composition of claim 1 , having a Vicat softening temperature of at least about 110° C. and having greater than 4 KJ/m 2 notched Izod impact strength at 4 after exposure to water for about 500 hours.
21. The polycarbonate composition of claim 1 , having improved retention of molecular weight and notched Izod impact strength after exposure to water for at least about 500 hours.
22. The polycarbonate composition of claim 1 , having a melt volume rate of at least about 34 cc/10 min, when measured at 260° C. and utilizing a 5 kg load.
23. An article comprising the polycarbonate composition of claim 1 .
24. An article comprising the polycarbonate composition of claim 6 .
25. An article comprising the polycarbonate composition of claim 3 .
26. An article comprising up to about 5 wt. % of the polycarbonate composition of claim 1 .
27. A polycarbonate composition comprising:
(a) from about 55 wt. % to about 80 wt. % of a bisphenol A based polycarbonate having a melt viscosity rate of from about 4 cc to about 14 cc/10 min when measured at 300° C. with a 1.2 kg load;
(b) at least one of from greater than 0 wt. % to about 20 wt. % of a phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP) copolymer and/or from greater than 0 wt. % to about 20 wt. % of a nitrile capped bisphenol A based polycarbonate;
(c) from about 8 wt. % to about 18 wt. % of a polycarbonate siloxane copolymer and/or a mixture thereof, wherein the siloxane content in the copolymer is from about 10 wt. % to about 30 wt. %;
(d) from 0 wt. % to about 5 wt. % of a poly(styrene-co-acrylonitrile) having a styrene content of about 75% and an acrylonitrile content of about 25 wt. %;
(e) from 0.5 wt. % to about 5 wt. % of a siloxane based impact modifier with polymethyl methacrylate grafted siloxane and acrylic rubber having a siloxane content of from about 50% to about 75%;
(f) from 0 wt. % to about 0.5 wt. % of a polytetrafluoroethylene encapsulated styrene-acrylonitrile copolymer (72:28 w/w); and
(g) from 0.5 wt. % to about 5 wt. % of a poly(alkylene glycol).
28. The polycarbonate composition of claim 27 , wherein a) comprises from about 55 wt. % to about 75 wt. % of a bisphenol A based polycarbonate having a melt viscosity rate of from about 4 cc to about 14 cc/10 min when measured at 300° C. with a 1.2 kg load.
29. The polycarbonate composition of claim 27 , wherein b) comprises from greater than 0 wt. % to about 20 wt. % of a 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP)-bisphenol A (BPA) polycarbonate copolymer.
30. The polycarbonate composition of claim 27 , wherein b) comprises from greater than 0 wt. % to about 20 wt. % of a nitrile capped bisphenol A based polycarbonate.
31. The polycarbonate composition of claim 27 , wherein b) comprises from about 5 wt. % to about 10 wt. % of a nitrile capped bisphenol A based polycarbonate.
32. The polycarbonate composition of claim 27 , being free of phosphorus based additive.
33. The polycarbonate composition of claim 27 , having less than about 0.1 wt. % phosphorus based additive.
34. The polycarbonate composition of claim 27 , having less than about 100 ppm phosphorus based additive.
35. The polycarbonate composition of claim 27 , having less than about 0.5 wt. % of a phosphate additive.
36. The polycarbonate composition of claim 27 , being free of bromine.
37. A polycarbonate composition having two or more of the following:
(a) a melt volume rate of a polycarbonate component of at least about 16 cc/10 min, when measured at 260° C. and utilizing a 5 kg load;
(b) a notched Izod impact value of at least 500 J/m; or
(c) a heat deflection temperature of 1.8 MPa flatwise mode of at least 105° C.;
wherein the polycarbonate composition is free of a flame retardant additive comprising phosphorous or bromine and wherein the polycarbonate composition further comprises one or more of a nitrile polycarbonate, a phthalimide copolymer, or a combination thereof; and one or more of (i) a polymethyl methacrylate grafted silicone having a siloxane content from about 50 weight % to about 75 wt % and acrylic rubber, or (ii) a polyalkylene glycol having a molecular weight (Mn) of about 2,000 g/mol, and wherein the polycarbonate composition has a flame resistance rating of V0 when measured at 1.6 mm thickness according to UL94 standards.
38. A polycarbonate composition having two or more of the following:
(a) a melt volume rate of a polycarbonate component of at least about 16 cc/10 min, when measured at 260° C. and utilizing a 5 kg load;
(b) a notched Izod impact value of at least 500 J/m; or
(c) a heat deflection temperature of 1.8 MPa flatwise mode of at least 105° C.;
wherein the polycarbonate composition is free of a resorcinol 1,3-diphenylphosphate and bisphenol A bis(diphenyl)phosphate and bromine; and wherein the polycarbonate composition further comprises one or more of a nitrile polycarbonate, a phthalimide copolymer, or a combination thereof; and one or more of (i) a polymethyl methacrylate grafted silicone having a siloxane content from about 50 weight % to about 75 wt % and acrylic rubber, or (ii) a polyalkylene glycol having a molecular weight (Mn) of about 2,000 g/mol, and wherein the polycarbonate composition has a flame resistance rating of V0 when measured at 1.6 mm thickness according to UL94 standards.