Modified diphenylmethane diisocyanate-based adhesives
View Patent ↗Adhesive compositions using modified diphenylmethane diisocyanate are disclosed along with methods and articles using the adhesive compositions. The adhesive compositions are especially suited for making flexible laminates for use in food packaging.
1. A method of making a laminate that comprises a first flexible substrate and a second flexible substrate, said method comprising
applying a two-part adhesive composition to a surface of the first substrate to form an adhesive bearing surface of the first substrate, and
contacting a surface of the second substrate with the adhesive bearing surface of the first substrate to form the laminate,
the two-part adhesive composition comprising
Part A, a first polyol, and
Part B, an isocyanate-terminated polyurethane prepolymer that is a reaction product of a second polyol and a modified diphenylmethane diisocyanate selected from the group consisting of a carbodiimide-modified diphenylmethane diisocyanate, an allophanate-modified diphenylmethane diisocyanate, a biuret-modified diphenylmethane diisocyanate, a polymeric diphenylmethane diisocyanate, and mixtures thereof.
2. The method of claim 1 , wherein the laminate exhibits a PAA (primary aromatic amines) Food Migration Value that is less than 50% relative to that of a control within 3 days from the time of lamination.
3. The method of claim 1 , wherein the prepolymer comprises from 0 to about 0.5% by weight of 2,2′-diphenylmethane diisocyanate, and from 0 to about 10% by weight of 2,4′-diphenylmethane diisocyanate.
4. The method of claim 1 , wherein the first polyol has a viscosity of no greater than 25,000 mPas at 25° C.±5° C.
5. The method of claim 1 , wherein the prepolymer is a liquid at an ambient temperature and has a viscosity of no greater than 25,000 mPas at 25° C.±5° C.
6. The method of claim 1 , wherein the modified diphenylmethane diisocyanate is a carbodiimide-modified diphenylmethane diisocyanate that contains no greater than 2% by weight triethylphosphate.
7. The method of claim 1 , wherein the modified diphenylmethane diisocyanate is a carbodiimide-modified diphenylmethane diisocyanate that contains no greater than 0.5% by weight of 2,2′-diphenylmethane diisocyanate and no greater than 10% by weight of 2,4′-diphenylmethane diisocyanate.
8. The method of claim 1 , wherein the modified diphenylmethane diisocyanate is an allophanate-modified diphenylmethane diisocyanate that contains no greater than 0.5% by weight of 2,2′-diphenylmethane diisocyanate and no greater than 10% by weight of 2,4′-diphenylmethane diisocyanate.
9. The method of claim 1 , wherein the first and the second polyols are the same or different polyols, each being selected from the group consisting of polyester polyols, polyether polyols, polyesterether polyols, and combinations thereof.
10. The method of claim 1 , wherein the first and the second substrates are the same or different material, each being selected from the group consisting of polyethylene, polypropylene, polyester, nylon, surlyn, aluminum foil, cellophane, polylactic acid, metalized polyester, metalized polypropylene, aclar, paper, and combinations thereof.