Alloy, magnetic core and process for the production of a tape from an alloy
View Patent ↗An alloy is provided which consists of Fe 100-a-b-c-d-x-y-z Cu a Nb b M c T d Si x B y Z z and up to 1 at % impurities, M being one or more of the elements Mo, Ta and Zr, T being one or more of the elements V, Mn, Cr, Co and Ni, Z being one or more of the elements C, P and Ge, 0 at %≦a<1.5 at %, 0 at %≦b<2 at %, 0 at %≦(b+c)<2 at %, 0 at %≦d<5 at %, 10 at %<x<18 at %, 5 at %<y<11 at % and 0 at %≦z<2 at %. The alloy is configured in tape form and has a nanocrystalline structure in which at least 50 vol % of the grains have an average size of less than 100 nm, a hysteresis loop with a central linear region, a remanence ratio Jr/Js of <0.1 and a coercive field strength H c to anisotropic field strength H a ratio of <10%.
1. A process for producing a nanocrystalline alloy tape, comprising the steps:
providing a tape made of an amorphous alloy with a composition consisting of Fe 100-a-b-c-d-x-y-z Cu a Nb b M c T d Si x B y Z z and up to 1 at % impurities, wherein M is at least one element selected from the group consisting of Mo, Ta and Zr, wherein T is at least one element selected from the group consisting of V, Mn, Cr, Co and Ni, wherein Z is at least one element selected from the group consisting of C, P and Ge, and wherein 0 at %≦a<1.5 at %, 0 at %≦b≦1.5 at %, 0 at %≦(b+c)<2 at %, 0 at %≦d<5 at %, 10 at %<x<18 at %, 5 at %<y<11 at % and 0 at %≦z<2 at %, and
heat treating the amorphous alloy tape under tensile stress in a continuous furnace at a temperature T a such that 450° C. ≦T a ≦750° C. wherein the tape is passed through the continuous furnace at a speed such that a period of time which the tape spends in a temperature zone of the continuous furnace is between 2 seconds and 2 minutes, wherein the temperature zone is T a ±5% T a ,
determining magnetic properties comprising determining a desired permeability, anisotropic field value, a maximum remanence ratio Jr/Js value of less than 0.1, wherein Jr is remanent magnetization and Js is saturation polarization, determining a maximum value of the ratio of coercive field strength to anisotropic field strength H c /H a of less than 10%, and determining a permitted deviation range for each of these values,
continuously measuring the magnetic properties of the tape as it leaves the continuous furnace, and
where deviations from the permitted magnetic properties deviation are observed, adjusting the tensile stress at the tape accordingly to bring the measured magnetic property values back within the permitted deviation range.
2. The process in accordance with claim 1 , wherein the tape is passed through the continuous furnace under a tensile stress of 5 MPa to 800 MPa.
3. The process in accordance with claim 1 , wherein the temperature T a is selected dependent on the niobium content b of the amorphous alloy tape according to the relationship (T x1 +50° C.)≦T a ≦(T x2 +30° C.), wherein T a is the heat treating temperature, and T x1 and T x2 correspond to crystallization temperatures of the amorphous alloy tape defined by maximum transformation heat.
4. The process according to claim 1 , wherein the nanocrystalline alloy tape has a nanocrystalline structure having grains in which at least 50% vol of the grains have an average size of less than 100 nm, wherein the nanocrystalline alloy tape exhibits a J-H hysteresis loop having a central linear part, wherein the nanocrystalline alloy tape exhibits a remanence ratio Jr/Js <0.1, and wherein the nanocrystalline alloy tape exhibits a ratio of coercive field strength Hc to anisotropic field strength Ha of less than 10%.