Flame retardant flash spun sheets
View Patent ↗The present invention relates to a flame retardant plexifilamentary film-fibril strand comprising at least one polyolefin and at least one flame retardant selected from the group consisting of: phosphate esters, phosphonate esters, phosphinate esters, polyphosphazines, nitrogen-containing polyphosphates, hindered amines and mixtures thereof. The present invention also relates to flame retardant sheet made from the flame retardant plexifilamentary film-fibril strands. The sheet can be made into a flame retardant building substrate, garment, banner, light reflector and cover.
1. A flame retardant plexifilamentary film-fibril strand consisting of at least one polyolefin, from about 0.5 to about 15 weight percent of ethylene maleic anhydride compatibilizer based upon the total weight of polyolefin composition, and at least one flame retardant selected from the group consisting of:
a) a liquid resorcinol bis(diphenyl phosphate) of the general formula (1):
wherein n has an average value of from about 1 to about 7;
(b) a liquid bis-phenol A-bis(diphenyl phosphate) of the general formula (2):
wherein n has an average value of from about 1 to about 2;
(d) a solid phosphate ester of the general formula (4):
wherein n has an average value of from about 1.0 to about 2.0 and X is a divalent arylene moiety bonded to both of the oxygen atoms of any one of hydroquinone, resorcinol, 4,4′-biphenol, bisphenol S, or bisphenol F, and wherein the phosphate ester is in the absence of halogen;
(e) a liquid aromatic polyphosphate of the formula (5):
and mixtures thereof.
2. The flame retardant plexifilamentary film-fibril strand of claim 1 , wherein the polyolefin is selected from the group consisting of polyethylene, polypropylene and their copolymers.
3. The flame retardant plexifilamentary film-fibril strand of claim 1 , wherein the flame retardant is present in an amount of from about 0.5 weight percent to about 15 weight percent based on the total weight of polyolefin composition.
4. The flame retardant plexifilamentary film-fibril strand of claim 1 , wherein the solid phosphate ester of the general formula (4) is hydroquinone bis(diphenyl phosphate).
5. The flame retardant plexifilamentary film-fibril strand of claim 4 , wherein the solid phosphate ester of the general formula (4) has a melting temperature of at least 80° C.
6. A flame retardant sheet comprising the flame retardant plexifilamentary film-fibril strands of claim 1 .
7. A flame retardant article comprising the flame retardant sheet of claim 6 selected from the group consisting of: building substrate, garment, banner, light reflector and cover.