Carbon nanocomposite sorbent and methods of using the same for separation of one or more materials from a gas stream
The present invention relates to carbon nanocomposite sorbents. The present invention provides carbon nanocomposite sorbents, methods for making the same, and methods for separation of a pollutant from a gas that includes that pollutant. Various embodiments provide a method for reducing the mercury content of a mercury-containing gas.
1. A method for reducing the pollutant content of a pollutant-containing gas, comprising:
providing or obtaining a carbon nanocomposite sorbent material comprising
providing or obtaining a carbon precursor comprising a carbohydrate,
providing or obtaining a substrate material,
contacting the carbon precursor and the substrate material, to provide a nanocomposite starting material, and
heating the nanocomposite starting material, to provide the carbon nanocomposite sorbent;
providing or obtaining a halogen or halide promoter;
promoting at least a portion of the sorbent material by chemically reacting the portion of the sorbent material with the halogen or halide promoter to form a promoted sorbent;
contacting at least part of the promoted sorbent with the pollutant, to form a pollutant-sorbent composition; and
separating at least some of the pollutant-sorbent composition from the pollutant-containing gas, to give a cleaned gas.
2. The method of claim 1 , wherein the pollutant is mercury.
3. The method of claim 2 , wherein the promoted sorbent combines with at least about 70 wt % of the mercury present in the mercury-containing gas.
4. The method of claim 1 , wherein promoting comprises injecting the carbon nanocomposite sorbent material at an injection rate and injecting separately at least one promoter at an injection rate into a gas stream whereby in-flight reaction produces the promoted sorbent, wherein the promoter is selected from the group consisting of molecular halogens, halides, and combinations thereof, wherein the promoter is reacted in gas phase or as a vapor, wherein the promoter is added at from about 1 gram to about 30 grams per about 100 grams of carbon nanocomposite sorbent material.
5. The method of claim 1 , wherein the carbon precursor comprises brown sugar, barley sugar, caramel, cane sugar, corn syrup, molasses, starch, or a sugar waste product.
6. The method of claim 1 , wherein the substrate material comprises diatomaceous earth, clay, zeolite, or mineral.
7. The method of claim 1 , wherein separating at least some of the pollutant-sorbent composition from the pollutant-containing gas comprises separating particulates from the pollutant-containing gas, the particulates comprising at least some of the pollutant-sorbent composition.
8. The method of claim 1 , further comprising reducing the concentration of SO 2 or SO 3 in the pollutant-containing gas.
9. The method of claim 1 , wherein the halogen or halide promoter is in a form comprising a vapor form, a solid form, in a solvent, or a combination thereof.
10. The method of claim 1 , wherein the halogen or halide promoter comprises at least one of Group V halide, Group VI halide, or a mixture thereof.
11. The method of claim 1 , wherein a promoter precursor transforms into the halogen or halide promoter that reacts with the sorbent.
12. The method of claim 1 , wherein the halogen or halide promoter is NH 4 Br, NaBr, CaBr 2 , HBr, NaCl, CaCl 2 , or HCl.
13. The method of claim 1 , wherein the contacting occurs in a gas phase, a liquid phase, or a combination thereof.
14. A method for reducing the mercury content of a mercury-containing gas, comprising:
providing or obtaining a carbon nanocomposite sorbent, comprising
providing or obtaining a carbon precursor comprising a carbohydrate,
providing or obtaining a substrate material,
contacting the carbon precursor and the substrate material, to provide a nanocomposite starting material, and
heating the nanocomposite starting material, to provide the carbon nanocomposite sorbent;
providing or obtaining a halogen or halide promoter;
promoting at least a portion of the sorbent material by chemically reacting the portion of the sorbent material with the halogen or halide promoter to form a promoted sorbent;
contacting at least part of the promoted sorbent with the mercury, to form a mercury-sorbent composition; and
separating at least some of the mercury-sorbent composition from the pollutant-containing gas.