Modified binders for making fiberglass products
View Patent ↗Binder compositions for making fiberglass products and methods for making and using same are provided. The binder composition can include a phenol-aldehyde resin or a mixture of Maillard reactants and one or more modifiers selected from the group consisting of a copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid; an adduct of styrene, at least one of maleic anhydride and maleic acid, and at least one of an acrylic acid and an acrylate; and one or more latexes.
1. A fiberglass product, comprising:
a plurality of fibers; and
a binder composition, wherein the binder composition, prior to curing, comprises:
a phenol-aldehyde resin; and
one or more modifiers selected from the group consisting of:
a copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid;
an adduct of styrene, at least one of maleic anhydride and maleic acid, and at least one of an acrylic acid and an acrylate; and
a combination thereof,
wherein the fiberglass product is an insulation product, and
wherein the fiberglass product contains about 3 wt % to about 45 wt % of the binder composition, based on a dry weight of the fiberglass product.
2. The fiberglass product of claim 1 , wherein the one or more modifiers comprises the copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid, and wherein the copolymer comprises styrene maleic anhydride.
3. The fiberglass product of claim 2 , wherein the styrene maleic anhydride has a weight average molecular weight of about 5,000 to about 500,000.
4. The fiberglass product of claim 1 , wherein the one or more modifiers comprises the adduct of styrene, at least one of maleic anhydride and maleic acid, and at least one of an acrylic acid and an acrylate.
5. The fiberglass product of claim 2 , wherein the styrene maleic anhydride has a partial esterification of about 10% to about 80%.
6. The fiberglass product of claim 1 , wherein the phenol-aldehyde resin is present in an amount of about 92 wt % to about 99.8 wt %, based on a total weight of the phenol-aldehyde resin and the one or more modifiers.
7. The fiberglass product of claim 1 , wherein the phenol-aldehyde resin comprises phenol-formaldehyde resin pre-reacted with urea, and wherein a concentration of the urea is about 15 wt % to about 35 wt %, based on the combined weight of the urea and the phenol-aldehyde resin.
8. The fiberglass product of claim 1 , wherein the fiberglass product contains about 5 wt % to about 30 wt % of the binder composition, based on the dry weight of the fiberglass product.
9. The fiberglass product of claim 1 , wherein the fiberglass product is a non-woven fiberglass mat.
10. The fiberglass product of claim 1 , wherein the fiberglass product is a non-woven fiberglass mat having a thickness of from about 0.1 mm to about 30 cm and a density of about 0.1 g/cm 3 to about 0.15 g/cm 3 .
11. The fiberglass product of claim 1 , wherein the one or more modifiers comprises the copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid, and wherein the copolymer has a weight average molecular weight of about 20,000 to about 150,000.
12. The fiberglass product of claim 1 , wherein the one or more modifiers comprises the copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid, and wherein a weight ratio of the phenol-aldehyde resin to the one or more modifiers is about 99.8:0.2 to about 95:5.
13. The fiberglass product of claim 1 , wherein the binder composition further comprises a mixture of Maillard reactants.
14. The fiberglass product of claim 1 , wherein the one or more modifiers comprises the copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid, wherein the copolymer comprises styrene maleic anhydride having a weight average molecular weight of about 5,000 to about 500,000, and wherein the binder composition comprises about 92 wt % to about 99.8 wt % of the phenol-aldehyde resin, based on the total weight of the phenol-aldehyde resin and the one or more modifiers.
15. A method for making a fiberglass product, comprising:
contacting a plurality of fibers with a binder composition, wherein the binder composition comprises:
a phenol-aldehyde resin; and
one or more modifiers selected from the group consisting of:
a copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid;
an adduct of styrene, at least one of maleic anhydride and maleic acid, and at least one of an acrylic acid and an acrylate; and
a combination thereof;
collecting the contacted fibers to form a non-woven mat; and
heating the non-woven mat to at least partially cure the binder composition, wherein the fiberglass product is an insulation product, and wherein the fiberglass product contains about 3 wt % to about 45 wt % of the binder composition, based on a dry weight of the fiberglass product.
16. A fiberglass product, comprising:
a plurality of fibers; and
a binder composition, wherein the binder composition, prior to curing, comprises:
a phenol-aldehyde resin; and
one or more modifiers selected from the group consisting of:
a copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid;
an adduct of styrene, at least one of maleic anhydride and maleic acid, and at least one of an acrylic acid and an acrylate; and
a combination thereof, wherein the binder composition comprises about 92 wt % to about 99.8 wt % of the phenol-aldehyde resin, based on the combined weight of the phenol-aldehyde resin and the one or more modifiers.
17. The fiberglass product of claim 16 , wherein the modifier comprises the copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid, and wherein the copolymer has a weight average molecular weight of about 5,000 to about 500,000.
18. The fiberglass product of claim 16 , wherein the modifier comprises the copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid, wherein the copolymer comprises styrene maleic anhydride, and wherein the styrene maleic anhydride has a weight average molecular weight of about 10,000 to about 500,000.
19. The fiberglass product of claim 16 , wherein the fiberglass product is a non-woven fiberglass mat having a thickness of about 0.1 mm to about 30 cm and a density of about 0.1 g/cm 3 to about 0.15 g/cm 3 , and wherein the fiberglass product contains about 3 wt % to about 35 wt % of the binder composition, based on a dry weight of the fiberglass product.
20. The fiberglass product of claim 16 , wherein the binder composition further comprises a mixture of Maillard reactants.