Lubricant composition and bearing using same
A lubricant composition capable of effectively preventing a rolling surface of a bearing from flaking owing to hydrogen embrittlement. The bearing is lubricated with the lubricant composition. The lubricant composition is lubricating oil or grease. The lubricant composition contains a molybdate. The lubricant composition also contains an organic acid salt. At least one molybdate is selected from sodium molybdate, potassium molybdate, and lithium molybdate. The organic acid salt is a sodium salt of an organic acid having one to 20 carbon atoms. 0.01 to 5 wt % of the molybdate is added to the entirety of the lubricant composition. 5 wt % to 70 wt % of the organic acid salt is added to the addition amount of the molybdate. The lubricant composition forms a film containing a molybdenum compound in addition to an iron oxide film on a worn surface of the bearing.
1. A rolling bearing lubricated with a grease, wherein said grease comprises a base oil, a thickener, a molybdate and an organic acid salt; said thickener is a urea-based thickener; said molybdate is represented by M 2 Mo O 4 where M denotes any one of Na,K, and Li; said base oil being present in said grease in an amount of from 80 wt % to 87 wt % based on the total amount of said base oil and said thickener; said thickener being present in said grease in an amount of from 13 wt % to 20 wt % based on the total amount of said base oil and said thickener; said molybdate being present in said grease in an amount of from 0.5 wt % to 3 wt % based on the total amount of said base oil and said thickener; and said organic acid salt being sodium benzoate that is present in said grease in an amount of from 0.1 wt % to 0.3 wt % based on the total amount of said base oil and said thickener, or said organic acid salt being sodium sebacate that is present in said grease in an amount of 0.1 wt % based on the total amount of said base oil and said thickener, or said organic acid salt being sodium succinate that is present in said grease in an amount of 0.1 wt % based on the total amount of said base oil and said thickener.
2. A rolling bearing according to claim 1 , wherein said rolling bearing is used for electric parts and auxiliary machines of a vehicle to rotatably support a rotation shaft driven by an output of an engine on a stationary member.
3. A rolling bearing according to claim 1 , wherein said rolling bearing is used for supporting a rotor of a motor.
4. A rolling bearing lubricated with a grease according to claim 1 , said grease being capable of restraining flaking owing to hydrogen embrittlement, wherein said molybdate can form a film containing a molybdenum compound in addition to an iron oxide film on a worn surface of said bearing or on a generated fresh surface of an iron-based metal by wear.
5. A rolling bearing lubricated with a grease according to claim 1 wherein said sodium sebacate is monosodium sebacate or disodium sebacate, and said sodium succinate is monosodium succinate or disodium succinate.
6. A rolling bearing lubricated with a grease according to claim 1 , wherein said urea-based thickener is a diurea compound prepared by reaction between diisocyanate and monoamine.
7. A rolling bearing lubricated with a grease according to claim 6 , wherein said monoamine is p-toluidine, cyclohexylamine or octylamine.
8. A rolling bearing lubricated with a grease according to claim 6 wherein said diisocyanate is 4,4-diphenylmethane diisocyanate.
9. A rolling bearing lubricated with a grease according to claim 1 wherein said base oil is any one of alkyldiphenyl ether oil, poly-α-olefin oil, polyolester oil, mineral oil, a mixture of alkyldiphenyl ether oil and poly-α-olefin oil and a mixture of alkyldiphenyl ether oil and polyolester oil.
10. A rolling bearing lubricated with a grease according to claim 1 wherein said base oil comprises alkyldiphenyl ether oil.