Dissimilar Material Battery Enclosure for Improved Weld Structure
An electrochemical cell having an enclosure comprised of an enclosure body portion composed of a relatively high electrical resistivity material and an enclosure lid portion composed of a ductile material is discussed. The body portion of the enclosure preferably comprises Grade 5 or 23 titanium and the lid portion preferably comprises Grade 1 or 2 titanium. The enclosure lid is joined to the body of the enclosure through a welding process such as laser welding. The combination of these differing materials provides an enclosure that effectively retards the occurrence of eddy current induced heating as well as provides an enclosure that is more mechanically robust.
1 . An electrochemical cell comprising:
a) an enclosure having a body portion and a lid portion, the lid portion joined to the body portion;
b) an anode and a cathode separated from direct physical contact by a separator positioned within the enclosure body, and activated with an electrolyte; and
c) wherein the enclosure body portion is comprised of a first material of a greater electrical resistivity than a second material comprising the enclosure lid portion.
2 . The electrochemical cell of claim 1 wherein the body enclosure portion is composed of Grade 5 or 23 titanium and the lid enclosure portion is composed of Grade 1 or 2 titanium.
3 . The electrochemical cell of claim 1 wherein the body portion is composed of a titanium material comprising vanadium and aluminum.
4 . The electrochemical cell of claim 1 wherein the body enclosure portion is composed of a material having an electrical resistivity ranging from about 1.0×10 −4 ohm-cm to about 2.0×10 −1 ohm-cm.
5 . The electrochemical cell of claim 1 wherein a laser weld joint forms a hermetic seal between the body portion and the lid portion of the enclosure.
6 . The electrochemical cell of claim 5 wherein the laser weld joint has a Vickers (HK100) hardness ranging from 150-350.
7 . The electrochemical cell of claim 1 wherein the lid portion is joined to either a top end or a bottom end of the body portion of the enclosure.
8 . The electrochemical cell of claim 1 of either a primary or a secondary chemistry.
9 . The electrochemical cell of claim 1 of a primary chemistry having the anode of an alkali metal and the cathode of a cathode active material selected from the group consisting of a carbonaceous material, a fluorinated carbon, a metal, a metal oxide, a mixed metal oxide, a metal sulfide, and mixtures thereof.
10 . The electrochemical cell of claim 1 wherein one of the anode or the cathode is electrically connected to a terminal lead insulated from the lid portion of the enclosure by a glass-to-metal seal comprising an insulating glass.
11 . The electrochemical cell of claim 1 of a secondary chemistry having the anode of carbon or graphite and the cathode of a cathode active material selected from the group consisting of LiNiO 2 , LiMn 2 O 4 , LiCoO 2 , LiCo 0.92 Sn 0.08 O 2 , LiCo 1-x Ni x O 2 , LiFePO 4 , LiNi x Mn y Co 1-x-y O 2 , and LiNi x Co y Al 1-x-y O 2 .
12 . An electrochemical cell comprising:
a) an enclosure having a body portion and a lid portion, the lid portion joined to the body portion;
b) an anode and a cathode separated from direct physical contact by a separator positioned within the enclosure body, and activated with an electrolyte; and
c) wherein the enclosure lid portion is comprised of a first material of a greater electrical resistivity than a second material comprising the enclosure body portion.
13 . The electrochemical cell of claim 12 wherein the lid enclosure portion is composed of Grade 5 or 23 titanium and the body enclosure portion is composed of Grade 1 or 2 titanium.
14 . The electrochemical cell of claim 12 wherein the lid enclosure portion is composed of a material having an electrical resistivity ranging from about 1.0×10 −4 ohm-cm to about 2.0×10 −1 ohm-cm.
15 . The electrochemical cell of claim 12 of either a primary or a secondary chemistry.
16 . The electrochemical cell of claim 12 wherein a laser weld joint forms a hermetic seal between the body portion and the lid portion of the enclosure.
17 . The electrochemical cell of claim 16 wherein the laser weld joint has a Vickers (HK100) hardness ranging from 150-350.
18 . An electrochemical cell enclosure comprising:
a) a body enclosure portion having a body portion sidewall encompassing an enclosure space therewithin;
b) a lid portion having an elongated length and a lid width, joined to a top and/or a bottom end of the body portion such that the elongated length and lid width of the lid portion seals the enclosure space therewithin; and
c) wherein the enclosure body portion is comprised of a first material of a greater electrical resitivity than a second material comprising the enclosure lid portion.
19 . The electrochemical cell enclosure of claim 18 wherein the body enclosure portion is composed of Grade 5 or 23 titanium and the lid enclosure portion is composed of Grade 1 or 2 titanium.
20 . The electrochemical cell enclosure of claim 18 wherein the body portion is composed of a titanium material comprising vanadium and aluminum.
21 . The electrochemical cell enclosure of claim 18 wherein a laser weld joint forms a hermetic seal between the body portion and the lid portion of the enclosure.
22 . The electrochemical cell enclosure of claim 21 wherein the laser weld joint has a Vickers (HK100) hardness ranging from 150-350.
23 . The electrochemical cell enclosure of claim 18 wherein an anode and a cathode, separated from direct physical contact by a separator, are positioned within the enclosure body, one of the anode and the cathode electrically connected to a terminal lead insulated from the lid portion of the enclosure by a glass-to-metal seal comprising an insulating glass.
24 . The electrochemical cell enclosure of claim 23 wherein the anode and the cathode are of either a primary or a secondary chemistry.
25 . A method of providing an electrochemical cell, comprising the steps of:
a) providing a body enclosure portion having a body portion comprising a sidewall encompassing an enclosure space therewithin;
b) providing an anode and a cathode separated from direct physical contact with each other by a separator housed inside the body enclosure portion and activated with an electrolyte;
c) providing an enclosure lid portion having an elongated length and a lid width; and
d) joining the lid portion to the body enclosure, forming a seal therebetween.
26 . The method of claim 25 including providing the body enclosure portion is composed of Grade 5 or 23 titanium and the lid enclosure portion is composed Grade 1 or 2 titanium.
27 . The method of claim 25 including providing a laser weld joint forming a hermetic seal between the body portion and the lid portion of the enclosure.
28 . The method of claim 27 including providing the laser weld joint with a Vickers (HK100) hardness ranging from 150-350.
29 . The method of claim 25 including providing the body enclosure portion composed of a material having an electrical resistivity ranging from about 1.0×10 −4 ohm-cm to about 2.0×10 −1 ohm-cm.