Glass substrate for display cover glass and its production process
View Patent ↗To provide a glass substrate for a display cover glass not only having excellent strength and antibacterial properties but also having a high transparency and a high visible transmittance suitable as a cover glass for a display device. A glass substrate for a display cover glass, which comprises a surface compressive stress layer and an antibacterial substance-containing layer formed on the glass substrate surface, characterized by having a ratio (T1/T2) of the transmittance T1 at a wavelength of 428 nm to the transmittance T2 at a wavelength of 650 nm of the glass substrate of at least 0.95, and a transmittance at a wavelength of 428 nm of at least 86% when the thickness of the glass substrate is from 0.1 to 3.0 mm.
1. A process for producing a glass substrate, comprising:
chemically tempering a glass substrate in a molten salt comprising at least KNO 3 to provide a chemically tempered glass substrate,
cleaning the chemically tempered glass substrate to provide a cleaned glass substrate,
forming a silver film on the surface of the cleaned glass substrate to provide a glass substrate having a silver film formed thereon,
subjecting the glass substrate having the silver film formed thereon to heat treatment to diffuse silver ions from the glass substrate surface to the inside, and
after said heat treatment washing and removing silver remaining on the glass substrate surface which was not diffused in the inside of the glass substrate,
wherein the glass substrate produced has a silver amount of from 0.2 to 100 μg/cm 2 at a depth of 40 μm from the glass substrate surface, and
wherein the glass substrate produced comprises a surface compressive stress layer, and has a ratio (T1/T2) of the transmittance T1 at a wavelength of 428 nm to the transmittance T2 at a wavelength of 650 nm of at least 0.95, and a transmittance at a wavelength of 428 nm of at least 86% when the thickness of the glass substrate is from 0.1 to 3.0 mm.
2. The process for producing a glass substrate according to claim 1 , wherein the glass substrate produced has a glass composition comprising, as represented by mol % as calculated as oxides, from 55 to 80% of SiO 2 , from 0.1 to 15% of Al 2 O 3 , from 0 to 15% of B 2 O 3 , from 0 to 10% of ZnO, from 0.1 to 15% of Na 2 O, from 0 to 10% of K 2 O, and from 0 to 16% of MgO+CaO.
3. The process for producing a glass substrate according to claim 1 , wherein the surface compressive stress layer on the glass substrate surface has a depth of at least 3 μm and a surface compressive stress of at least 250 MPa.
4. The process for producing a glass substrate according to claim 1 , wherein the heat treatment occurs at a temperature of from 300 to 475° C.
5. The process for producing a glass substrate according to claim 1 , wherein said process further comprises plate-forming said glass substrate prior to chemically tempering said glass substrate.
6. The process for producing a glass substrate according to claim 5 , wherein said plate-forming is carried out by a float process.
7. The process for producing a glass substrate according to claim 1 , wherein said glass substrate is a plate-formed glass substrate.
8. The process for producing a glass substrate according to claim 1 , wherein the silver film does not contain potassium ions.