Mixed cathode active material having improved power characteristics and lithium secondary battery including the same
View Patent ↗Provided are a mixed cathode active material including layered structure lithium manganese oxide expressed as Chemical Formula 1 and a second cathode active material having a plateau voltage profile in a range of 2.5 V to 3.3 V, and a lithium secondary battery including the mixed cathode active material. The mixed cathode active material and the lithium secondary battery including the same may have improved safety and simultaneously, may be used in an operating device requiring the foregoing battery by widening a state of charge (SOC) range able to maintain power more than a required value by allowing the second cathode active material to complement low power in a low SOC range.
1. A mixed cathode active material comprising:
a first cathode active material, comprising a lithium manganese oxide expressed as Chemical Formula 1 and
a second cathode active material comprising a material expressed as Chemical Formula 2 having a plateau voltage profile in a range of about 2.5 V to about 3.3 V:
a Li 2 MnO 3 .(1− a )Li x MO 2 [Chemical Formula 1]
where 0<a<1, 0.9≦x≦1.2, and M is any one element or two or more elements selected from the group consisting of Al (aluminum), Mg (magnesium), Mn (manganese), Ni (nickel), Co (cobalt), Cr (chromium), V (vanadium), and Fe (iron)
y MnO 2 .(1− y )Li 2 MnO 3 [Chemical Formula 2]
where 0≦y≦1,
wherein the mixed cathode active material is suitable for use in a lithium secondary battery,
wherein the lithium secondary battery is suitable for a series-type plug-in hybrid electric vehicle (PHEV) or electric vehicle (EV), and
wherein a power of the lithium secondary battery in a state of charge (SOC) range of about 10% to about 40% is about 20% or more of power at about 50% SOC.
2. The mixed cathode active material of claim 1 , wherein the second cathode active material is included in an amount range of about 5 to about 50 parts by weight based on 100 parts by weight of the mixed cathode active material.
3. The mixed cathode active material of claim 1 , wherein the mixed cathode active material further comprises a conductive material.
4. The mixed cathode active material of claim 3 , wherein the conductive material comprises graphite and conductive carbon.
5. The mixed cathode active material of claim 3 , wherein the conductive material is included in an amount range of about 0.5 to about 15 parts by weight based on 100 parts by weight of the mixed cathode active material.
6. The mixed cathode active material of claim 4 , wherein the conductive carbon is a mixture of one or more selected from the group consisting of carbon black including carbon black, acetylene black, Ketjen black, channel black, furnace black, lamp black, or thermal black, or a material having a crystal structure of graphene or graphite.
7. The mixed cathode active material of claim 1 , wherein the mixed cathode active material further comprises at least a third cathode active material comprising one or more lithium-containing metal oxides selected from the group consisting of lithium cobalt oxide, lithium nickel oxide, lithium manganese oxide, lithium cobalt-nickel oxide, lithium cobalt-manganese oxide, lithium manganese-nickel oxide, lithium cobalt-nickel-manganese oxide, and oxides having other elements substituted or doped therein.
8. The mixed cathode active material of claim 7 , wherein the other elements are one or more selected from the group consisting of Al (aluminum), Mg (magnesium), Ni (nickel), Co (cobalt), Fe (iron), Cr (chromium), V (vanadium), Ti (titanium), Cu (copper), B (boron), Ca (calcium), Zn (zinc), Zr (zirconium), Nb (niobium), Mo (molybdenum), Sr (strontium), Sb (antimony), W (tungsten), and Bi (bismuth).
9. The mixed cathode active material of claim 7 , wherein the at least a third cathode active material is included in an amount of about 50 parts by weight or less based on 100 parts by weight of the mixed cathode active material.
10. A cathode comprising a current collector coated with the mixed cathode active material of claim 1 .
11. A lithium secondary battery comprising the cathode of claim 10 .
12. The mixed cathode active material of claim 1 , wherein the first cathode active material is in amount of 85 wt %, and wherein the second cathode active material is present in an amount of 15 wt %.