Mixed cathode active material having improved power characteristics and lithium secondary battery including the same
View Patent ↗Provided are a mixed cathode active material including lithium manganese oxide expressed as Chemical Formula 1 and a stoichiometric spinel structure Li 4 Mn 5 O 12 having a plateau voltage profile in a range of 2.5 V to 3.3 V, and a lithium secondary battery including the mixed cathode active material. The mixed cathode material and the lithium secondary battery including the same may have improved safety and simultaneously, power may be maintained more than a required value by allowing Li 4 Mn 5 O 12 to complement low power in a low state of charge (SOC) range. Therefore, a mixed cathode active material able to widen an available SOC range and a lithium secondary battery including the mixed cathode active material may be provided and properly used in a plug-in hybrid electric vehicle (PHEV) or electric vehicle (EV).
1. A mixed cathode active material comprising:
lithium manganese oxide expressed as Chemical Formula 1; and
a second cathode active material expressed as Chemical Formula 2 having a plateau voltage profile in a range of about 2.5 V to about 3.3 V:
xLi 2 MnO 3 .(1-x)LiMO 2 [Chemical Formula 1]
where 0<x<1 and M is any one element or two or more elements selected from the group consisting of Al (aluminum), Mg (magnesium), Mn (manganese), Ni (nickel), Co (cobalt), Cr (chromium), V (vanadium), and Fe (iron)
Li 4 Mn 5 O 12 . [Chemical Formula 2]
2. The mixed cathode active material of claim 1 , wherein the second cathode active material is included in an amount range of about 10 to about 30 parts by weight based on 100 parts by weight of the mixed cathode active material.
3. The mixed cathode active material of claim 1 , wherein the mixed cathode active material further comprises a conductive material in addition to the lithium manganese oxide and the second cathode active material.
4. The mixed cathode active material of claim 3 , wherein the conductive material is formed of graphite and conductive carbon.
5. The mixed cathode active material of claim 4 , wherein the conductive carbon is a mixture of one or more selected from the group consisting of carbon black, acetylene black, Ketien black, channel black, furnace black, lamp black, or thermal black, and a material having a crystal structure of graphene or graphite.
6. The mixed cathode active material of claim 3 , wherein the conductive material is included in an amount range of about 0.5 to about 15 parts by weight based on 100 parts by weight of the mixed cathode active material.
7. The mixed cathode active material of claim 1 , wherein the mixed cathode active material further comprises one or more lithium-containing metal oxides selected from the group consisting of lithium cobalt oxide, lithium nickel oxide, lithium manganese oxide, lithium cobalt-nickel oxide, lithium cobalt-manganese oxide, lithium manganese-nickel oxide, lithium cobalt-nickel-manganese oxide, and oxides having other elements substituted or doped therein.
8. The mixed cathode active material of claim 7 , wherein the other elements are one or more selected from the group consisting of Al (aluminum), Mg (magnesium), Ni (nickel), Co (cobalt), Fe (iron), Cr (chromium), V (vanadium), Ti (titanium), Cu (copper), B (boron), Ca (calcium), Zn (zinc), Zr (zirconium), Nb (niobium), Mo (molybdenum), Sr (strontium), Sb (antimony), W (tungsten), and Bi (bismuth).
9. The mixed cathode active material of claim 7 , wherein the lithium-containing metal oxide further added to the mixed cathode active material comprising the compounds of chemical formulas 1 and 2 is included in an amount of about 50 parts by weight or less based on 100 parts by weight of the mixed cathode active material.
10. A cathode comprising the mixed cathode active material of claim 1 .
11. A lithium secondary battery comprising the cathode of claim 10 .
12. The lithium secondary battery of claim 11 , wherein power of the lithium secondary battery in a SOC (state of charge) range of about 20% to about 40% is about 20% or more of power at about 50% SOC.
13. The lithium secondary battery of claim 11 , wherein the lithium secondary battery is suitable for use in a series-type PHEV (plug-in hybrid electric vehicle).
14. The lithium secondary battery of claim 11 , wherein the lithium secondary battery is suitable for use in an EV (electric vehicle).