Phosphor and LED light emitting device using the same
An LED light emitting device is provided that has high color rendering properties and is excellent color uniformity and, at the same time, can realize even luminescence unattainable by conventional techniques. A phosphor having a composition represented by formula: (Sr 2-X-Y-Z-ω Ba X Mg Y Mn Z Eu ω )SiO 4 wherein x, y, z, and ω are respectively coefficients satisfying 0.1<x<1, 0<y<0.5, 0<z<0.1, y>z, and 0.01<ω<0.2 is provided. The phosphor is used in combination with ultraviolet and blue light emitting diodes having a luminescence peak wavelength of 360 to 470 nm to form an LED light emitting device.
1. A process for producing europium-manganese-activated alkaline earth magnesium silicate phosphor comprising the steps of:
mixing a strontium compound, a barium compound, magnesium oxide, a manganese compound, silicon oxide, europium oxide and a halide compound as a flux;
filling the mixture into a crucible;
firing the mixture at 1100 to 1300° C. for 4 to 6 hours in an atmosphere containing nitrogen and hydrogen to form a fired product;
grinding the fired product to form a powder of the fired product; and
firing again the powder in a reducing atmosphere.
2. The process according to claim 1 , wherein the strontium compound, the barium compound and the manganese compound are carbonate compounds.
3. The process according to claim 1 , wherein the crucible is an aluminum crucible.