Phosphor composition and method for producing the same, and light-emitting device using the same
View Patent ↗A light-emitting device is produced using a phosphor composition containing a phosphor host having as a main component a composition represented by a composition formula: aM 3 N 2 .bAlN.cSi 3 N 4 , where “M” is at least one element selected from the group consisting of Mg, Ca, Sr, Ba, and Zn, and “a”, “b”, and “c” are numerical values satisfying 0.2≦a/(a+b)≦0.95, 0.05≦b/(b+c)≦0.8, and 0.4≦c/(c+a)≦0.95. This enables a light-emitting device emitting white light and satisfying both a high color rendering property and a high luminous flux to be provided.
1. A light-emitting device comprising a light-emitting element and a phosphor layer,
the light-emitting element being a blue light-emitting element that emits light having an emission peak in a wavelength range of 440 nm to less than 500 nm,
the phosphor layer containing a green phosphor having an emission peak in a wavelength range of 500 nm to less than 560 nm and a red phosphor having an emission peak in a wavelength range of 600 nm to less than 660 nm, the red phosphor being a nitride or oxynitride containing Eu 2+ as a luminescent center ion,
the green phosphor and the red phosphor being excited with light emitted by the blue light-emitting element, and
output light of the light-emitting device containing light-emitting components emitted by the green phosphor, the red phosphor, and the blue light-emitting element,
wherein the phosphor layer substantially contains no phosphor other than those activated with Eu 2+ or Ce 3+ ,
the green phosphor has an excitation peak on a shorter wavelength side than an excitation wavelength as a peak of the light emitted by the blue light-emitting element.
2. The light-emitting device according to claim 1 , wherein the red phosphor is a nitridoaluminosilicate-based red phosphor.
3. The light-emitting device according to claim 1 , wherein the red phosphor is a phosphor represented by the composition formula (M 1-x Eu x )AlSiN 3 , where M is at least one element selected from Mg, Ca, Sr, Ba, and Zn, and x is a numerical value satisfying 0.005≦x≦0.3.
4. The light-emitting device according to claim 1 , wherein the red phosphor is a phosphor represented by the composition formula (M 1-x Eu x ) 2 Si 4 AlON 7 , where M is at least one element selected from Mg, Ca, Sr, Ba, and Zn, and x is a numerical value satisfying 0.005≦x≦0.3.
5. The light-emitting device according to claim 1 , wherein an excitation peak of the excitation spectrum of the green phosphor on a longest wavelength side is in a wavelength range of less than 420 nm.
6. The light-emitting device according to claim 1 , wherein the phosphor layer further contains a yellow phosphor having an emission peak in a wavelength range of 560 nm to less than 600 nm.
7. The light-emitting device according to claim 1 , wherein the phosphor layer substantially contains no nitride or oxynitride phosphor other than the red phosphor.
8. The light-emitting device according to claim 1 , wherein the green phosphor is at least one green phosphor selected from the group consisting of a nitride phosphor or oxynitride phosphor activated with Eu 2+ , an alkaline-earth metal orthosilicate phosphor activated with Eu 2+ , an aluminate phosphor activated with Eu 2+ , a nitride phosphor or oxynitride phosphor activated with Ce 3+ , and a phosphor with a garnet structure activated with Ce 3+ .
9. The light-emitting device according to claim 1 , wherein the green phosphor is one selected from the group consisting of Sr 1.5 Al 3 Si 9 N 16 :Eu 2+ , Ca 1.5 Al 3 Si 9 N 16 :Eu 2+ , CaSiAl 2 O 3 N 2 :Eu 2+ , SrSiAl 2 O 3 N 2 :Eu 2+ , CaSi 2 O 2 N 2 :Eu 2+ , SrSi 2 O 2 N 2 :Eu 2+ , BaSi 2 O 2 N 2 :Eu 2+ , (Ba,Sr) 2 SiO 4 :Eu 2+, (Ba,Ca) 2 SiO 4 :Eu 2+ , SrAl 2 O 4 :Eu 2+ , Sr 2 Si 5 N 8 :Ce 3+ , Ca 1.5 Al 3 Si 9 N 16 :Ce 3+ , Ca 2 Si 5 N 8 :Ce 3+ , Y 3 (Al,Ga) 5 O 12 :Ce 3+ , BaY 2 SiAl 4 O 12 :Ce 3+ and Ca 3 Sc 2 Si 3 O 12 :Ce 3+ .
10. The light-emitting device according to claim 1 , wherein the blue light-emitting element has an emission peak wavelength in a range of 450 nm to 480 nm.
11. The light-emitting device according to claim 1 , wherein the green phosphor has an emission peak wavelength in a range of 510 nm to 550 nm.
12. The light-emitting device according to claim 1 , wherein the green phosphor has an emission peak wavelength in a range of 525 nm to less than 560 nm.
13. The light-emitting device according to claim 1 , wherein an excitation peak of the excitation spectrum of the green phosphor on a longest wavelength side is outside a wavelength range of the emission peak of the blue light-emitting element.