Viscous alcohol-containing sunscreen compositions
View Patent ↗The present disclosure provides a composition that maintains a high and desirable viscosity while having a high amount of alcohol. Suitable thickeners and gelling agents are mixed with the alcohol to achieve this effect. An emulsion stabilizer can also be added. These components can also be combined with a sunscreen. The resulting composition provides benefits such as cooling and desirable skin feel, but is still easily spreadable and viscous enough to function effectively as a sunscreen.
1. A sunscreen composition, comprising:
0.1 to 10 percent, based on the weight of the total composition, of a rheology modifying agent selected from the group consisting of a copolymer of acryloyldimethyltaurine and vinylpyrrolidone, a copolymer of acrylic acid and vinylpyrrolidone, acrylic-based anionic polymers, carbomers, and any combinations thereof;
0.01 to 5 percent, based on the total weight of the composition, of a gelling agent selected from the group consisting of polysaccharides, polysaccharide gums, and a combination thereof; and
10 to 40 percent, based on the total weight of the composition, of an aliphatic alcohol having 1 to 4 carbon atoms or a mixture thereof;
5 to 30 percent, based on the total weight of the composition, of a sunscreen active; and
0.01 to 5 percent, based on a total weight of the composition, of an emulsion stabilizer comprising natural fibers,
wherein said composition provides a cooling sensation when rubbed on a user's skin.
2. The sunscreen composition of claim 1 , wherein the natural fibers are from leaves, flowers, wood, fruits, or combinations thereof.
3. The sunscreen composition of claim 1 , wherein said gelling agent is selected from the group consisting of starch, modified starch, cellulose, cellulose gum, pectin, gelatin, agar, alginate, gellan gum, and any combinations thereof.
4. The sunscreen composition of claim 1 , wherein said alcohol is ethanol.
5. The sunscreen composition of claim 1 , wherein said composition comprises 10 to 40 percent, based on the total weight of the composition, of said alcohol.
6. The sunscreen composition of claim 1 , wherein said composition comprises 20 to 30 percent, based on the total weight of the composition, of said alcohol.
7. The sunscreen composition of claim 1 , further comprising 1 to 8 percent, based on the total weight of the composition, of a skin conditioner.
8. The sunscreen composition of claim 7 , wherein said skin conditioner is selected from the group consisting of glycols, silicones, aloe, vitamin C, derivatives of vitamin C, vitamin B, derivatives of vitamin B, and a combination thereof.
9. The sunscreen composition of claim 1 , further comprising 0.01 to 1 percent, based on the total weight of the composition, of a cooling enhancer.
10. The sunscreen composition of claim 9 , wherein said cooling enhancer is selected from the group consisting of menthol, menthol derivatives, menthyl lactate, menthyl PCA (pyrrolidone carboxylic acid), isopulegol, 3-(menthoxy)propane-1,2-diol, p-menthane-3,8-diol, vanillyl butyl ether, ethyl methane carboxamide, and any combinations thereof.
11. A sunscreen composition, comprising:
0.1 to 10 percent, based on the weight of the total composition, of a rheology modifying agent selected from the group consisting of a copolymer of acryloyldimethyltaurine and vinylpyrrolidone, a copolymer of acrylic acid and vinylpyrrolidone, acrylic-based anionic polymers, carbomers, and any combinations thereof;
0.01 to 5 percent, based on the total weight of the composition, of a gelling agent selected from the group consisting of starch, modified starch, cellulose, cellulose gum, pectin, gelatin, agar, alginate, gellan gum, and any combinations thereof;
20 to 30 percent, based on the total weight of the composition, of an alcohol selected from the group consisting of aliphatic alcohols having one to four carbons;
11 to 19.5 percent, based on the total weight of the composition, of a sunscreen active; and
0.01 to 5 percent, based on the total weight of the composition, of an emulsion stabilizer comprising natural fibers,
wherein said composition provides a cooling sensation when rubbed on a user's skin.
12. The sunscreen composition of claim 11 , wherein the natural fruit fibers are from leaves, flowers, wood, fruits, or combinations thereof.
13. The sunscreen composition of claim 11 , further comprising:
1 to 8 percent, based on the total weight of the composition, of a skin conditioner selected from the group consisting of glycols, silicones, or a combination thereof; and
0.01 to 1 percent, based on the total weight of the composition, of a cooling enhancer selected from the group consisting of menthol, menthol derivatives, menthyl lactate, menthyl pyrrolidone carboxylic acid, isopulegol, 3-(menthoxy)propane-1,2-diol, p-menthane-3,8-diol, vanillyl butyl ether, ethyl methane carboxamide, and any combinations thereof.
14. The sunscreen composition of claim 1 , wherein the composition has a viscosity of from 10,000 to 90,000 centipoise.
15. The sunscreen composition of claim 1 , wherein the composition has a viscosity of from 40,000 to 60,000 centipoise.
16. The sunscreen composition of claim 1 , wherein the composition has:
a ratio of a loss modulus to a storage modulus less than 0.19; or
a flow point range from 20 Pa to 200 Pa.
17. The sunscreen composition of claim 1 , wherein said sunscreen active is a physical blocking sunscreen active selected from the group consisting of titanium dioxide, zinc oxide, and a combination thereof.
18. The sunscreen composition of claim 1 , wherein said sunscreen active is a chemical absorbing sunscreen.
19. The sunscreen composition of claim 18 , wherein said chemical absorbing sunscreen is selected from the group consisting of anthranilate, benzophenone, dibenzoyl methane, p-aminobenzoic acid derivative, camphor derivative, cinnamate, salicylate, amyldimethyl PABA, digalloyl trioleate, dioxybenzone, ethyl 4-bis(hydroxypropyl)aminobenzoate, 2-ethylhexyl-2-cyano-3,3-diphenylacrylate, glyceryl aminobenzoate, 3-imidazol-4-ylacrylic acid and ethyl ester, methyl anthranilate, octyldimethyl PABA, 2-phenylbenzimidazole-5-sulfonic acid and salt, sulisobenzone, N,N,N-trimethyl-4-(2-oxobom-3-ylidene methyl)anillinium methyl sulfate, and any combinations thereof.