Methods for use of aniline copolymers
View Patent ↗Aniline copolymers and methods of making these copolymers are disclosed herein. The copolymers can, for example, be used for removing metal ions from a sample.
1. A method for removing a metal ion from a sample, the method comprising:
(a) providing an untreated sample suspected of containing the metal ion; and
(b) contacting the untreated sample and a composition to form a treated sample, wherein the composition comprises a copolymer comprising at least one optionally substituted 2-hydroxy-5-sulfonic aniline as a first monomer unit and at least one aniline as a second monomer unit.
2. The method of claim 1 , wherein, the first monomer unit is represented by Formula I:
wherein R 1 is hydrogen or an electron-donating group, and R 2 is hydrogen or an electron-donating group.
3. The method of claim 1 , wherein the metal ion is a heavy metal ion.
4. The method of claim 1 , wherein the metal ion is Pb(II) or Hg(II).
5. The method of claim 1 , wherein the metal ion is a noble metal ion.
6. The method of claim 1 , wherein the metal ion is Ag(I).
7. The method of claim 1 , wherein the metal ion is selected from the group consisting of Cd(II), Cu(II), Zn(II), Pb(II), Hg(II), and Fe(III).
8. The method of claim 1 , wherein the untreated sample is wastewater.
9. The method of claim 1 , wherein the concentration of the metal ion in the untreated sample is no more than about 200 g/L.
10. The method of claim 9 , wherein the concentration of the metal ion in the untreated sample is from about 1 ng/L to about 200 mg/L.
11. The method of claim 1 , wherein the concentration of the metal ion in the untreated sample is higher than the concentration of the metal ion in the treated sample.
12. The method of claim 11 , wherein the concentration of the metal ion in the untreated sample is at least about 5 times higher than the concentration of the metal ion in the treated sample.
13. The method of claim 12 , wherein the concentration of the metal ion in the untreated sample is at least about 10 times higher than the concentration of the metal ion in the treated sample.
14. The method of claim 13 , wherein the concentration of the metal ion in the untreated sample is at least about 20 times higher than the concentration of the metal ion in the treated sample.
15. The method of claim 1 , wherein the concentration of the metal ion in the treated sample is less than about 30% of the concentration of the metal ion in the untreated sample.
16. The method of claim 15 , wherein the concentration of the metal ion in the treated sample is less than about 15% of the concentration of the metal ion in the untreated sample.
17. The method of claim 16 , wherein the concentration of the metal ion in the treated sample is less than about 1% of the concentration of the metal ion in the untreated sample.
18. The method of claim 1 , further comprising separating the copolymer from the treated sample.
19. The method of claim 18 , further comprising contacting the separated copolymer with a chelating agent to form a regenerated copolymer, wherein the amount of metal ions in the regenerated copolymer is less than the amount of metal ions in the separated copolymer.
20. The method of claim 19 , further comprising contacting a second untreated sample suspected of containing metal ions with the regenerated copolymer.
21. The method of claim 19 , wherein the chelating agent is a polyamino carboxylic acid.
22. The method of claim 19 , wherein the chelating agent is selected from ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), N-(2-hydroxyethyl)ethylenediamine-N,N′,N′-triacetic acid (HEDTA), glycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid (EGTA), ethylenediamine-N,N′-bis((2-hydroxyphenyl)acetic acid) (EDDHA), and mixtures thereof.