Secondary electrochemical cells with separator and electrolyte combination
A secondary electrochemical cell comprises an anode, a cathode including electrochemically active cathode material, a separator between the anode and the cathode, and an electrolyte. The electrolyte comprises at least one salt dissolved in at least one organic solvent. The separator in combination with the electrolyte has an area-specific resistance of less than about 2 ohm-cm 2 .
1. A secondary electrochemical cell comprising an anode;
a cathode comprising electrochemically active cathode material, said electrochemically active cathode material is selected from the group consisting of lithium-transition-metal phosphate, sodium-transition-metal phosphate, lithium-metal oxide, and any mixture thereof; a cast separator consisting of a material selected from the group consisting of polypropylene, polyethylene, polyvinylidene, poly(vinylidene fluoride), and any mixture thereof between said anode and said cathode; and an electrolyte said electrolyte comprising at least one salt dissolved in at least one organic solvent, wherein said separator in combination with said electrolyte has an area-specific resistance of less than about 2 ohm-cm 2 and wherein said lithium-metal oxide is selected from the group consisting of LiCoO 2 , LiNi x Mn 2 O 4 , Li(Ni x Co y Al z )O 2 , Li(Ni x Mn y Co z )O 2 , aLi 2 MnO 3 ·(1−a)Li(Ni x Mn y Co z )O 2 , and any mixture thereof wherein 0<a<1, 0≤x≤1, 0≤y≤1, and 0≤z≤1.
2. The electrochemical cell of claim 1 wherein the lithium-transition-metal phosphate comprises LiMPO 4 wherein M is selected from the group consisting of vanadium, chromium, manganese, iron, cobalt, tin, niobium, molybdenum, zirconium, zinc, nickel, and any mixture thereof.
3. The electrochemical cell of claim 1 wherein the sodium-transition-metal phosphate comprises NaMPO 4 wherein M is selected from the group consisting of vanadium, chromium, manganese, iron, cobalt, tin, niobium, molybdenum, zirconium, zinc, nickel, and any mixture thereof.
4. The electrochemical cell of claim 1 wherein the separator porosity is between about 30% and about 70%.
5. The electrochemical cell of claim 1 wherein the at least one salt is selected from the group consisting of lithium perchlorate (LiCIO 4 ), lithium hexafluorophosphate (LiPF 6 ), lithium tetrafluorooxalatophosphate (LiPF 4 (C 2 O 4 )), lithium tetrafluoroborate (LiBF 4 ), lithium trifluorosulfonate (LiSO 3 CF 3 ), lithium trifluorosulfonimide (LiN(SO 2 CF 3 ) 2 ), lithium bis(pentafluoroethanesulfonyl)imide (LiN(SO 2 CF 2 CF 3 ) 2 )(LiBETi), lithium bis(oxalato)borate (LiBOB), lithium hexafluoroarsenate (LiAsF 6 ), lithium fluorosulfonimide (LiFSI), sodium perchlorate (NaCIO 4 ), sodium trifluorosulfonimide (NaTFSI), sodium trifluorosulfonate (NaTFS), and any mixture thereof.
6. The electrochemical cell of claim 1 wherein the at least one salt is at a concentration within the electrolyte from about 0.5 M to about 1.8 M.
7. The electrochemical cell of claim 1 wherein the electrolyte comprises at least one electrolyte additive selected from the group consisting of propane sultone (PS), vinylene carbonate (VC), succinonitrile (SN), cyclohexylbenzene (CHB), tetra ethyl orthosilicate (TEOS), lithium bis(oxalato)borate (LiBOB), tetramethoxy titanium (TMTi), dimethyl acetamide (DMAc), lithium perchlorate (LiCIO 4 ), propargyl methane sulfonate (PMS), and any mixture thereof.
8. The electrochemical cell of claim 1 wherein the electrolyte comprises at least one electrolyte additive at a concentration from about 0.05 to about 5 weight percent of the electrolyte solution.
9. The electrochemical cell of claim 1 wherein the organic solvent is selected from the group consisting of ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), dimethyl carbonate (DMC), ethyl methyl dicarbonate (EMC), diethyl carbonate (DEC), dipropyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, dibutyl carbonate, butylmethyl carbonate, butylethyl carbonate, butylpropyl carbonate, and any mixture thereof.
10. The electrochemical cell of claim 1 wherein the organic solvent is at a concentration from about 0.5 weight percent to about 95 weight percent of the electrolyte solution.
11. The electrochemical cell of claim 1 wherein the anode comprises electrochemically active anode material selected from the group consisting of graphite, spheroidal natural graphite, mesocarbon mircrobead, coke, mesophase carbon fibers, fullerene, graphene, carbon nanotube, single-walled carbon nanotube (SWCNT), multi-wall carbon nanotube (MWCNT), vapor-phase grown carbon fiber (VGCF), silicon, silicon alloy, tin, tin alloy, lithium titanate, and any mixture thereof.
12. The electrochemical cell of claim 1 wherein the anode comprises conductive additive selected from the group consisting of graphite, carbon black, acetylene black, vapor-phase grown carbon fiber (VGCF), carbon nanotube, fullerenic carbon nanotube, vitreous carbon, carbon fiber, graphene, and any mixture thereof.
13. The electrochemical cell of claim 1 wherein the separator has a thickness from about 8 to about 30 micrometers.
14. The electrochemical cell of claim 1 wherein the area-specific resistance is from about 1.0 to about 1.9.
15. The electrochemical cell of claim 1 wherein the cathode comprises conductor material selected from the group consisting of carbon black, graphite, fullerenes, graphenes, carbon nanotube, single-walled carbon nanotube (SWCNT), multi-wall carbon nanotube (MWCNT), vapor-phase grown carbon fibers (VGCF), and any mixture thereof.
16. The electrochemical cell of claim 1 wherein said electrochemical cell has a total anode-to-cathode (A/C) ratio of less than about 1.5.
17. The electrochemical cell of claim 16 wherein the total anode-to-cathode (A/C) ratio is from about 1.0 to about 1.35.
18. The electrochemical cell of claim 1 wherein the cast separator consists of a material selected from the group consisting of polypropylene, polyethylene, polyvinylidene, and any mixture thereof.