Low molar, homogeneously substituted HEC for use in cement-based systems
View Patent ↗Hydroxyethylcellulose with a low molar substitution and which is uniformly substituted is useful in cement-based systems, including mortars. The cement-based system exhibits long pot life, as well as very high water retention capability at hot temperature, as well as better paste stability and optimized setting behavior for hot as well as cold temperature compared to typical, cement-based systems with commercial cellulose ether compounds. Less hydrophilic cellulose ethers such as methylhydroxyethylcellulose can be added as a second cellulose ether.
1. A cement-based system comprising:
cement,
filler/aggregate, and
a rheology control agent comprising a low molar, homogeneously substituted hydroxyethylcellulose which has no further substitution by a hydrocarbon radical,
wherein the molar substitution of the low molar, homogenously substituted hydroxyethylcellulose is in a range of from about 1.8 to about 2.2 and wherein the low molar, homogenously substituted hydroxyethylcellulose is characterized by a molar substitution/degree of substitution ratio of less than 1.60.
2. The cement-based system claimed in claim 1 , wherein the rheology control agent is present in an amount of about 0.1% to about 1% by weight, based on the weight of the cement-based system on a dry basis.
3. The cement-based system of claim 2 , wherein the rheology control agent comprises a blend of the low molar, homogeneously substituted hydroxyethylcellulose with a second cellulose ether comprising a hydrocarbon radical that is less hydrophilic than the low molar, homogenously substituted hydroxyethylcellulose.
4. The cement-based system of claim 3 , wherein the second cellulose ether is selected from the group consisting of methylhydroxyethylcellulose and methylhydroxypropylcellulose.
5. The cement-based system of claim 3 , wherein the second cellulose ether comprises methylhydroxyethylcellulose.
6. The cement-based system of claim 3 , wherein the blend has a ratio of the second cellulose ether to the low molar, homogenously substituted hydroxyethylcellulose of about 10:90 to about 90:10 by weight.
7. The cement-based system of claim 6 , wherein the blend has a ratio of the second cellulose ether to the low molar, homogenously substituted hydroxyethylcellulose of about 30:70 to about 70:30 by weight.
8. The cement-based system of claim 6 , wherein the blend has a ratio of the second cellulose ether to the low molar, homogenously substituted hydroxyethylcellulose of about 50:50 by weight.