Austenitic stainless steel pipe excellent in steam oxidation resistance and manufacturing method therefor
View Patent ↗There is provided an austenitic stainless steel pipe excellent in steam oxidation resistance. The austenitic stainless steel pipe excellent in steam oxidation resistance contains, by mass percent, 14 to 28% of Cr and 6 to 30% of Ni, and is configured so that a region satisfying the following Formula exists in a metal structure at a depth of 5 to 20 μm from the inner surface of the steel pipe: (α/β)×δ/ε×100≧0.3 where the meanings of symbols in the above Formula are as follows: α: sum total of the number of pixels of digital image in region in which orientation difference of adjacent crystals detected by electron backscattering pattern is 5 to 50 degrees β: the number of total pixels of digital image in region of measurement using electron backscattering pattern ε: analysis pitch width of electron backscattering pattern (μm) δ: grain boundary width (μm).
1. An austenitic stainless steel pipe having steam oxidation resistance which contains, by mass percent, 14 to 28% of Cr and 6 to 30% of Ni, wherein a region satisfying Formula (1) exists in a metal structure at least in one location of 10 to 15 μm in a depth range from an inner surface of the steel pipe and the region is formed by blasting shots or sands:
g≧ 0.3 (1)
where g in Formula (1) is a value calculated from Formula (2),
g =(α/β)×δ/ε×100 (2)
where the meanings of symbols in Formula (2) are as follows;
g: volume ratio (%)
α: sum total of the number of pixels of digital image in region in which orientation difference of adjacent crystals detected by electron backscattering pattern is 5 to 50 degrees
β: the number of total pixels of digital image in region of measurement using electron backscattering pattern
ε: analysis pitch width of electron backscattering pattern (μm)
δ: grain boundary width (μm).
2. The austenitic stainless steel pipe having steam oxidation resistance according to claim 1 , wherein a crystal grain size of the steel pipe is 50 μm or smaller.
3. A manufacturing method for an austenitic stainless steel pipe having steam oxidation resistance containing, by mass percent, 14 to 28% of Cr and 6 to 30% of Ni, wherein a region satisfying Formula (1) is formed in a metal structure at least in one location of 10 to 15 μm in a depth range from an inner surface of the steel pipe, the method being carried out by blasting shots or sands onto the inner surface of the austenitic stainless steel pipe with an injection amount of 3 kg/cm 2 /min or larger;
g≧ 0.3 (1)
where g in Formula (1) is a value calculated from Formula (2),
g =(α/β)×δ/ε×100 (2)
where the meanings of symbols in Formula (2) are as follows;
g: volume ratio (%)
α: sum total of the number of pixels of digital image in region in which orientation difference of adjacent crystals detected by electron backscattering pattern is 5 to 50 degrees
β: the number of total pixels of digital image in region of measurement using electron backscattering pattern
ε: analysis pitch width of electron backscattering pattern (μm)
δ: grain boundary width (μm).
4. The manufacturing method for an austenitic stainless steel pipe having steam oxidation resistance according to claim 3 , wherein the method is carried out by blasting shots or sands having an average particle size of 0.5 mm or smaller.