Rubber composition, method for its formation, and automotive tire containing the composition
View Patent ↗A rubber composition with disperse phase particles containing poly(phenylene ether) can be formed by a method that includes melt blending an uncured rubber with a poly(phenylene ether) composition containing a poly(phenylene ether) and an oil to form an uncured rubber composition, then curing the uncured rubber composition. Before being blended with the rubber, the poly(phenylene ether) composition exhibits a glass transition temperature of about 40 to about 140° C., and during blending with the rubber, the oil component of poly(phenylene ether) composition migrates from the poly(phenylene ether) composition to the rubber, leaving a poly(phenylene ether)-containing disperse phase that gives rise to a second hysteresis peak temperature of about 160 to about 220° C. as measured by dynamic mechanical analysis of the cured rubber composition. Also described are the poly(phenylene ether) composition used in the method, a cured rubber composition formed by the method, and a tire containing the cured rubber composition.
1. A method of forming a rubber composition, comprising:
melt blending
a rubber comprising ethylenic unsaturation, and
a poly(phenylene ether) composition exhibiting a glass transition temperature of
40 to 140° C. and comprising a poly(phenylene ether) and an oil to form an uncured rubber composition comprising a continuous phase comprising the rubber containing ethylenic unsaturation and the oil, and a disperse phase comprising the poly(phenylene ether), the oil having migrated from the disperse phase comprising the poly(phenylene ether) to the continuous phase comprising the rubber; and
curing the uncured rubber composition to form a cured rubber composition exhibiting, by dynamic mechanical analysis, a second hysteresis peak temperature of 160 to 220° C.
2. The method of claim 1 , wherein the poly(phenylene ether) has a glass transition temperature of 170 to 220° C.
3. The method of claim 1 , wherein said melt blending comprises melt blending 5 to 40 parts by weight of the poly(phenylene ether) composition and 100 parts by weight of the rubber comprising ethylenic unsaturation.
4. The method of claim 1 , wherein said melt blending comprises blending at a temperature of 100 to 170° C.
5. The method of claim 1 , wherein the rubber comprising ethylenic unsaturation is selected from the group consisting of natural rubbers, synthetic rubbers, and combinations thereof.
6. The method of claim 1 , wherein the rubber comprising ethylenic unsaturation is selected from the group consisting of natural polyisoprenes, synthetic polyisoprenes, styrene-butadiene random copolymers, polybutadienes, ethylene-propylene random copolymers, ethylene-propylene-diene monomer random copolymers, isobutylene-isoprene random copolymers, chloroprene rubbers, acrylonitrile-butadiene random copolymers, and combinations thereof.
7. The method of claim 1 , wherein the oil is selected from the group consisting of rubber processing oils, extending oils for polyolefins, rubber processing waxes, organophosphate ester flame retardants that are liquids at one atmosphere and at least one temperature in the range of 25 to 120° C., and combinations thereof.
8. The method of claim 1 , wherein the oil is a rubber processing oil.
9. The method of claim 1 , wherein the oil is selected from the group consisting of mild extraction solvate (MES) oils, treated distillate aromatic extract (TDAE) oils, and combinations thereof.
10. The method of claim 1 , wherein the oil comprises a treated distillate aromatic extract (TDAE) oil.
11. The method of claim 1 , wherein the poly(phenylene ether) composition has an average particle size of 37 micrometers to 2 millimeters prior to said melt blending the rubber comprising ethylenic unsaturation and the poly(phenylene ether) composition.
12. The method of claim 1 , wherein the poly(phenylene ether) composition has a first average particle size, the disperse phase has a second average particle, and a ratio of the first average particle size to the second average particle size is at least 10.
13. The method of claim 1 , wherein the poly(phenylene ether) composition further comprises 5 to 50 weight percent, based the weight of the poly(phenylene ether) composition, of a styrenic polymer selected from the group consisting of poly(alkenyl aromatic)s, rubber-modified poly(alkenyl aromatic)s, unhydrogenated block copolymers of an alkenyl aromatic monomer and a conjugated diene, hydrogenated block copolymers of an alkenyl aromatic monomer and a conjugated diene, and combinations thereof.
14. A method of forming a rubber composition, comprising:
melt blending
100 parts by weight of a rubber comprising ethylenic unsaturation, and 5 to about 40 parts by weight of a poly(phenylene ether) composition exhibiting a glass transition temperature of 40 to 140° C. and comprising
a poly(phenylene ether) having a glass transition temperature of 170 to 220° C., and
an oil selected from the group consisting of mild extraction solvate (MES) oils, treated distillate aromatic extract (TDAE) oils, residual aromatic extract (RAE) oils, and combinations thereof
to form an uncured rubber composition comprising a continuous phase comprising the rubber containing ethylenic unsaturation and the oil, and a disperse phase comprising the poly(phenylene ether); and
curing the uncured rubber composition to form a cured rubber composition exhibiting, by dynamic mechanical analysis, a second hysteresis peak temperature of 160 to 220° C.
15. A cured rubber composition formed by the method of claim 1 .