Gas storage and release using piezoelectric materials

1. A method for storing and releasing a gas, the method comprising:

providing a piezoelectric metal-organic framework material;

adsorbing at least a portion of the gas into the piezoelectric metal-organic framework material; and

applying an electric field to the piezoelectric metal-organic framework material to release a portion of the gas.

2. The method of claim 1 , wherein the piezoelectric metal-organic framework material comprises one or more of MOF-177, MOF-74, an MOF-74 framework structure with open Zn2+ sites, a 2D laminar homochiral metal-organic framework, and/or a piezoelectric metal-organic framework material having the chemical formula (Lig)2Tb(H2O)2(ClO4), wherein Lig corresponds to a ligand comprising one or more of oxalic acid, malonic acid, succinic acid, glutaric acid, phthalic acid, isophthalic acid, terephthalic acid, citric acid, trimesic acid, 1,2,3-triazole, pyrrodiazole and/or squaric acid.

3. The method of claim 1 , wherein the gas comprises one or more of hydrogen, carbon dioxide, ammonia, boron trifluoride, and/or aluminum trifluoride.

4. The method of claim 1 , further comprising varying a magnitude of the applied electric field to vary an amount of gas released from the piezoelectric metal-organic framework material.

5. A method for storing and releasing a gas comprising:

providing a piezoelectric metal-organic framework material;

applying an electric field to the piezoelectric metal-organic framework material;

adsorbing at least a portion of the gas into the metal-organic framework material during application of the electric field; and

reducing an electric field strength of the electric field to release at least a portion of the gas.

6. The method of claim 5 , wherein the piezoelectric metal-organic framework material comprises one or more of MOF-177, MOF-74, an MOF-74 framework structure with open Zn2+ sites, a 2D laminar homochiral metal-organic framework, and/or a piezoelectric metal-organic framework material having the chemical formula (Lig)2Tb(H2O)2(ClO4), wherein Lig corresponds to a ligand comprising one or more of oxalic acid, malonic acid, succinic acid, glutaric acid, phthalic acid, isophthalic acid, terephthalic acid, citric acid, trimesic acid, 1,2,3-triazole, pyrrodiazole and/or squaric acid.

7. The method of claim 5 , wherein the gas comprises one or more of hydrogen, carbon dioxide, ammonia, boron trifluoride, and/or aluminum trifluoride.

8. The method of claim 5 , further comprising:

applying a second electric field to the piezoelectric metal-organic framework material, wherein the second electric field has a different magnitude than the first electric field; and

adsorbing at least a portion of a second gas into the piezoelectric metal-organic framework material during application of the second electric field, wherein the second gas is different than the gas.

9. An apparatus that is arranged to store a gas and release the gas responsive to the application of an electric field, the apparatus comprising:

a piezoelectric metal-organic framework material, the piezoelectric metal-organic framework material configured to adsorb at least a portion of the gas in response to the application of an electric field;

a power supply;

a controller coupled to the power supply, wherein the controller is arranged to control the application of the electric field with the power supply;

a vessel, wherein the piezoelectric metal-organic framework material is in the vessel; and

a gas port in the vessel, wherein the gas port is arranged to convey the gas when gas is either released or stored by the apparatus.

10. The apparatus of claim 9 , wherein the piezoelectric metal-organic framework material comprises a non-centrosymmetric piezoelectric metal-organic framework material.

11. The apparatus of claim 9 , wherein the piezoelectric metal-organic framework material comprises one or more of MOF-177, MOF-74, and/or an MOF-74 framework structure with open Zn2+ sites.

12. The apparatus of claim 9 , wherein the piezoelectric metal-organic framework material comprises a 2D laminar homochiral metal-organic framework.

13. The apparatus of claim 9 , wherein the piezoelectric metal-organic framework material comprises a piezoelectric metal-organic framework material having the chemical formula (Lig)2Tb(H2O)2(ClO4), wherein Lig corresponds to a ligand comprising one or more of oxalic acid, malonic acid, succinic acid, glutaric acid, phthalic acid, isophthalic acid, terephthalic acid, citric acid, trimesic acid, 1,2,3-triazole, pyrrodiazole and/or squaric acid.

14. The apparatus of claim 9 , further comprising:

a second piezoelectric metal-organic framework material.

15. A method of storing and releasing a gas responsive to the application of an electric field, the method comprising:

providing a piezoelectric metal-organic framework material, the piezoelectric metal-organic framework material configured to adsorb at least a portion of the gas in response to the application of an electric field;

adsorbing at least a portion of the gas into the piezoelectric metal-organic framework material; and

applying an electric field to the piezoelectric metal-organic framework material to release a portion of the gas.