Organic light emitting diodes and methods of manufacturing the same
The inventive concept provides organic light emitting diodes and methods of manufacturing an organic light emitting diode. The organic light emitting diode includes a substrate, a first electrode layer and a second electrode layer formed on the substrate, an organic light emitting layer disposed between the first electrode layer and the second electrode layer and generating light, and a scattering layer between the first electrode layer and the substrate or between the first electrode layer and the organic light emitting layer. The scattering layer scatters the light.
1. A method of manufacturing an organic light emitting diode, comprising:
preparing a substrate;
forming a scattering layer on the substrate, wherein forming the scattering layer comprises:
forming fine patterns on the substrate, wherein forming the fine patterns comprises:
forming a polymer layer on the substrate;
rearranging the polymer layer into first polymer blocks and second polymer blocks by a phase separation method; and
removing the first polymer blocks or the second polymer blocks;
and
forming a planarization layer covering the fine patterns;
forming a first electrode layer on the scattering layer;
forming an organic light emitting layer on the first electrode layer; and
forming a second electrode layer on the organic light emitting layer.
2. The method of claim 1 , wherein the polymer layer includes block copolymer formed by a spin coating method.
3. The method of claim 2 , wherein the block copolymer includes at least one of polystyrene-polymethylmethacrylate copolymer, polybutadiene-polybutylmethacrylate copolymer, polybutadiene-polydimethylsiloxane copolymer, polybutadiene-polymethylmethacrylate copolymer, polybutadiene-polyvinylpyridine copolymer, polybutylacrylate-polymethylmethacrylate, polybutylacrylate-polyvinylpyridine, polyisoprene-polyvinylpyridine, polyisoprene-polymethylmethacrylate, polyhexylacrylate-polyvinylpyridine, polyisobutylene-polybutylmethacrylate, polyisobutylene-polymethylmethacrylate, polyisobutylene-polybutylmethacrylate, polyisobutylene-polydimethylsiloxane, polybutylmethacrylate-polybutylacrylate, polyethylethylene-polymethylmethacrylate, polystyrene-polybutylmethacrylate, polystyrene-polybutadiene, polystyrene-polyisoprene, polystyrene-polydimethylsiloxane, polystyrene-polyvinylpyridine, polyethylethylene-polyvinylpyridine, polyethylene-polyvinylpyridine, polyvinylpyridine-polymethylmethacrylate, polyethyleneoxide-polyisoprene, polyethyleneoxide-polybutadiene, polyethyleneoxide-polystyrene, polyethyleneoxide-polymethylmethacrylate, polyethyleneoxide-polydimethylsiloxane, and polystyrene-polyethyleneoxide.
4. The method of claim 2 , wherein the block copolymer is rearranged into the first polymer blocks and the second polymer blocks by a thermal treatment; and
wherein the phase separation method includes the thermal treatment.
5. The method of claim 1 , wherein the first polymer blocks or the second polymer blocks are removed by a cleaning solution after the first and second polymer blocks are exposed by ultraviolet rays.
6. The method of claim 1 , wherein forming the fine patterns comprises:
etching the substrate exposed from the first polymer blocks or the second polymer blocks which remain on the substrate.
7. The method of claim 1 , wherein the planarization layer includes at least one of inorganic materials of TiO 2 , ZrO 2 , ZnS, TiO 2 —SiO 2 , SnO 2 , and In 2 O 3 , polymers of polyvinyl phenolic resin, epoxy resin, polyimide resin, polystyrene resin, polycarbonate resin, polyethylene resin, polymethylmethacrylate (PMMA) resin, and polypropylene resin, and any combination thereof.
8. The method of claim 1 , wherein preparing the substrate comprises:
forming recesses at a top surface of the substrate.