IP Library Granted Patent US 9,302,245
Granted Patent B2
US 9,302,245 · App. 13/497,394 · Granted Apr 5, 2016

Apparatus for continuously carrying out heterogeneously catalyzed chemical reactions at elevated temperatures

Inventors: Matthias Krull (Harxheim, DE); Roman Morschhaeuser (Mainz, DE); Hans-Juergen Scholz (Alzenau, DE)
Assignee: Clariant International Ltd.
B01J19/126B01J23/44B01J23/462B01J23/882B01J35/04C07C29/143C07C67/03C10G32/02H05B6/806B01J2219/00033B01J2219/0892B01J2219/1215B01J2219/1227C07C2101/14C10G2300/1055C10G2300/202C10G2400/04
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Quick Facts
Patent No.
US 9,302,245
App. No.
13/497,394
Granted
Apr 5, 2016
Kind
B2
Abstract

The invention relates to an apparatus for continuously carrying out heterogeneously catalyzed chemical reactions, comprising a microwave-transparent tube, the longitudinal axis of which extends in the direction of propagation of the microwaves of a single-mode microwave applicator and which is filled with an open-cell foam that carries or is made of catalytically active species.

Claims (23)

1. An apparatus for continuous performance of heterogeneously catalyzed chemical reactions, wherein the apparatus comprises

a monomode microwave applicator configured to propagate microwave radiation in a direction of propagation;

a substantially microwave-transparent reaction tube having a longitudinal axis in the direction of propagation of the monomode microwave applicator, and having an irradiation zone operatively coupled to the monomode microwave applicator; and

an open-cell solid foam essentially filling the reaction tube in the irradiation zone, wherein the open-cell solid foam comprises a plurality of cells and a plurality of cell walls, the cells and the cell walls forming two continuous networks that penetrate one another, and has a porosity of at least 20%.

2. The apparatus as claimed in claim 1 , wherein the monomode microwave applicator comprises a hollow conductor in which the microwave-transparent reaction tube is disposed, the hollow conductor being operatively connected to a microwave generator.

3. The apparatus as claimed in claim 1 , in which the monomode microwave applicator is configured as a cavity resonator.

4. The apparatus as claimed in claim 1 , in which the monomode microwave applicator is configured as a cavity resonator of the reflection type.

5. The apparatus as claimed in claim 2 , in which the hollow conductor has a central axis of symmetry, and wherein the reaction tube is aligned axially with the central axis of symmetry of the hollow conductor.

6. The apparatus as claimed in claim 3 , wherein the cavity resonator comprises a coaxial transition of the microwaves.

7. The apparatus as claimed in claim 3 , in which the cavity resonator is configured such that it can be operated in E 01n mode with respect to the microwave radiation where n is an integer from 1 to 200.

8. The apparatus as claimed in claim 3 , in which the cavity resonator is configured such that a standing wave with respect to the microwave radiation can form therein.

9. The apparatus as claimed in claim 1 , in which the open-cell solid foam consists of a ceramic material which is itself catalytically active.

10. The apparatus as claimed in claim 1 , in which the open-cell solid foam is a ceramic material which bears a different catalytically active species.

11. The apparatus as claimed in claim 1 , in which the open-cell solid foam consists of a catalytically active metal.

12. The apparatus as claimed in claim 1 , in which the pore count of the open-cell solid foam, determined on the basis of ASTM D3576, is between 1 and 150 ppi.

13. The apparatus as claimed in claim 1 , in which the porosity of the open-cell solid foam is 50% to 90%.

14. The apparatus as claimed in claim 1 , in which the pore size of the open-cell solid foam is between 0.01 mm and 1 cm.

15. The apparatus as claimed in claim 1 , in which the average strength of the open-cell solid foam, determinable by means of die indentation, is between 100 and 15 000 N.

16. The apparatus as claimed in claim 1 , in which the open-cell solid foam bears or consists of catalytically active species, and is configured such that a reaction mixture to be converted can flow through it.

17. The apparatus as claimed in claim 1 , wherein the open-cell solid foam is formed from a catalytically active material.

18. The apparatus as claimed in claim 1 , wherein the open-cell solid foam is formed from a material into which catalytically active species have been intercalated and/or which has been coated or impregnated with catalytically active species.

19. The apparatus as claimed in claim 1 , wherein the open-cell solid foam is formed from a ceramic material into which catalytically active species have been intercalated and/or which has been coated or impregnated with catalytically active species.

20. The apparatus as claimed in claim 1 , wherein the open-core solid foam is fixed in the reaction tube as a core.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 4, 2015
From: CLARIANT FINANCE (BVI) LIMITED
To: CLARIANT INTERNATIONAL LTD.
Reel/Frame 037212/0379 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 21, 2012
From: KRULL, MATTHIAS; MORSCHHAEUSER, ROMAN; SCHOLZ, HANS JUERGEN
To: CLARIANT FINANCE (BVI) LIMITED
Reel/Frame 027902/0739 →
Priority Claims (1)
DE 10 2009 042 523 · Sep 22, 2009 · national
Continuity (1)
Related Publication 20120178951A1 · Jul 12, 2012