Liquid crystal composition and liquid crystal display device
A liquid crystal composition satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large positive dielectric anisotropy, a large specific resistance, a large elastic constant, a high stability to ultraviolet light and heat, or is suitably balanced between at least two of the characteristics. An AM device has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth. The liquid crystal composition includes a specific two-ring compound having a high maximum temperature and a large elastic constant as a first component, a specific compound having a large dielectric anisotropy as a second component, and has a nematic phase. The liquid crystal display device contains this composition.
1. A liquid crystal composition having a nematic phase and including at least one compound selected from the group of compounds represented by formula (1) as a first component and at least one compound selected from the group of compounds represented by formula (2) as a second component, wherein the group of compounds represented by formula (2) at least comprises one compound selected from the group of compounds represented by formula (2-12) or formula (2-13), and the liquid crystal composition doesn't contain a cyano compound:
wherein R 1 is independently alkyl having 1 to 12 carbons; R 2 is independently alkyl having 1 to 12 carbons, or alkoxy having 1 to 12 carbons; R 3 is independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring A is independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene, 1,3-dioxane-2,5-diyl, or tetrahydropyran-2,5-diyl, at least one of rings A is 1,4-phenylene, 3-fluoro-1,4-phenylene, or 3,5-difluoro-1,4-phenylene; Z 1 is independently a single bond, ethylene, carbonyloxy, or difluoromethyleneoxy; X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , and X 7 are independently hydrogen or fluorine; Y 1 is independently fluorine, chlorine, or trifluoromethoxy; m is 1, 2, 3, or 4.
2. The liquid crystal composition according to claim 1 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1):
wherein R 1 and R 4 are independently alkyl having 1 to 12 carbons.
3. The liquid crystal composition according to claim 1 , the second component further comprising at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-11) and formula (2-14) to formula (2-19):
wherein R 3 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine, X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are independently hydrogen or fluorine; Y 1 is independently fluorine, chlorine or trifluoromethoxy.
4. The liquid crystal composition according to claim 1 , wherein the ratio of the first component is in the range of 5% by weight to 40% by weight, the ratio of the second component is in the range of 10% by weight to 95% by weight based on the total weight of the liquid crystal composition.
5. The liquid crystal composition according to claim 1 , further including at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 5 and R 6 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring B and ring C are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z 2 is independently a single bond, ethylene or carbonyloxy; and p is 1, 2 or 3, and R 5 is alkyl having 1 to 12 carbons when p is 1 and ring B is 1,4-cyclohexylene, R 6 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 4 carbons.
6. The liquid crystal composition according to claim 5 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1) to formula (3-15):
wherein R 5 and R 6 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine, R 7 is independently alkyl having 1 to 12 carbons; R 8 is independently alkyl having 1 to 12 carbons or alkoxy having 1 to 12 carbons; and R 9 is independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons and alkenyl having 2 to 4 carbons.
7. The liquid crystal composition according to claim 5 , wherein the ratio of the third component is in the range of 5% by weight to 70% by weight.
8. The liquid crystal composition according to claim 1 , further including at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 10 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring D is independently 1,4-cyclohexylene or 1,3-dioxane-2,5-diyl; Z 3 is independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are independently hydrogen or fluorine; Y 2 is fluorine, chlorine or trifluoromethoxy; and q is 1 or 2.
9. The liquid crystal composition according to claim 8 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-1) to formula (4-8):
wherein R 10 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
10. The liquid crystal composition according to claim 8 , wherein the ratio of the fourth component is in the range of 5% by weight to 40% by weight based on the total weight of the liquid crystal composition.
11. The liquid crystal composition according to claim 1 , wherein the maximum temperature of a nematic phase is 70° C. or higher, the optical anisotropy (25° C.) at a wavelength of 589 nanometers is 0.065 or more, and the dielectric anisotropy (25° C.) at a frequency of 1 kHz is 2 or more.
12. The liquid crystal composition according to claim 1 , wherein the elastic constant (K) at 25° C. is 12 pN or more.
13. A liquid crystal display device containing the liquid crystal composition according to claim 1 .
14. The liquid crystal display device according to claim 13 , wherein the operating mode of the liquid crystal display device is a TN mode, an OCB mode, an IPS mode, or the driving mode of the liquid crystal display device is an active matrix mode.
15. The liquid crystal composition according to claim 5 , further including at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 10 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring D is independently 1,4-cyclohexylene or 1,3-dioxane-2,5-diyl; Z 3 is independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are independently hydrogen or fluorine; Y 2 is fluorine, chlorine or trifluoromethoxy; and q is 1 or 2.
16. The liquid crystal composition according to claim 15 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-1) to formula (4-8):
wherein R 10 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
17. The liquid crystal composition according to claim 15 , wherein the ratio of the fourth component is in the range of 5% by weight to 40% by weight based on the total weight of the liquid crystal composition.