Process for preparing alkanediol and dialkyl carbonate
View Patent ↗The invention relates to a process for the preparation of an alkanediol and a dialkyl carbonate comprising: reacting an alkylene carbonate and an alkanol in the presence of a transesterification catalyst to obtain a reaction mixture comprising dialkyl carbonate, unconverted alkanol, alkanediol and unconverted alkylene carbonate; and then subjecting the mixture to separation in three distillation columns.
1. A process for the preparation of an alkanediol and a dialkyl carbonate comprising:
(a) reacting an alkylene carbonate and an alkanol in the presence of a transesterification catalyst to obtain a reaction mixture comprising dialkyl carbonate, unconverted alkanol, alkanediol and unconverted alkylene carbonate;
(b) subjecting the reaction mixture to distillation in a first distillation column to obtain a top stream comprising dialkyl carbonate and alkanol and a bottom stream comprising dialkyl carbonate, alkanol, alkanediol and alkylene carbonate;
(c) subjecting the bottom stream from the first distillation column to distillation in a second distillation column to obtain a top stream comprising dialkyl carbonate and alkanol and a bottom stream comprising alkanediol and alkylene carbonate;
(d) recovering alkanediol from the bottom stream from the second distillation column; and
(e) subjecting the top streams from the first and second distillation columns to distillation in a third distillation column to obtain a top stream comprising alkanol and a bottom stream comprising dialkyl carbonate.
2. A process according to claim 1 , wherein a pressure at the top of the first distillation column is of from 0.5 to 10 bar.
3. A process according to claim 1 , wherein a pressure at the top of the second distillation column is of from 10 mbar to 3 bar.
4. A process according to claim 3 , wherein the pressure at the top of the second distillation column is lower than the pressure at the top of the first distillation column, and is of from 50 to 500 mbar.
5. A process according to claim 1 , wherein a pressure at the top of the third distillation column is lower than the pressure at the top of the first distillation column.
6. A process according to claim 5 , wherein the pressure at the top of the third distillation column is of from 0.1 to 5 bar.
7. A process according to claim 1 , wherein a temperature at the bottom of the first, second and third distillation columns is of from 100 to 200 ° C.
8. A process according to claim 1 , which is carried out continuously.
9. A process according to claim 1 , wherein the transesterification catalyst is a heterogeneous catalyst.
10. A process according to claim 1 , wherein the alkylene carbonate is ethylene carbonate or propylene carbonate and the alkanol is ethanol.