Method For Colouring Anodically Oxidised Aluminum Surfaces
The invention relates to a process for adsorptive coloration of anodically oxidized surfaces of aluminum and/or aluminum alloys, characterized in that a) an aqueous dyebath is provided, said aqueous dyebath containing an organic dye that fluoresces on irradiation with UV light of a wavelength between 300 and 400 nm, containing not more than 0.4 g/liter of alkaline earth metal ions and having a pH between 4.0 and 10, b) said anodically formed surface is colored by immersion in and/or spraying with said dyebath (a) at a temperature between 10 and 50° C., and c) the colored surface is sealed.
1 . A process for adsorptive coloration of anodically oxidized surfaces of aluminum and/or aluminum alloys, comprising the steps of
a) providing an aqueous dyebath, said aqueous dyebath containing an organic dye that fluoresces on irradiation with UV light of a wavelength between 300 and 400 nm, containing not more than 0.4 g/liter of alkaline earth metal ions and having a pH between 4.0 and 10,
b) coloring said anodically formed surface by immersion in spraying with said dyebath (a), or both at a temperature between 10 and 50° C., and
c) sealing the colored surface.
2 . The process as claimed in claim 1 , wherein the organic dye is selected from the group consisting of xanthenes, pyrenes, methines, stilbenes, coumarins, cyanines, oxazines, uranines and C.I. Acid Yellow 245.
3 . The process as claimed in claim 1 , wherein the dyebath pH is between 5.2 and 7.0.
4 . The process as claimed in claim 1 , wherein the dyebath contains not more than 60 mg of acetate ions per liter of dyebath.
5 . The process as claimed in claim 1 , wherein the dyebath contains at least one anionic or nonionic surfactants.
6 . The process as claimed in claim 1 , wherein the dyebath contains a nonionic surfactant selected from the group of polyether-modified polydimethylsiloxanes.
7 . The process as claimed in claim 1 , wherein the colored surface is sealed by treatment with hot water or with water vapor.
8 . An article comprising an anodically formed aluminum oxide layer dyed with a hue in the visible wavelength region of light by adsorptive coloration and fluorescent in UV light of a wavelength between 300 and 400 nm.
9 . The article as claimed in claim 8 , wherein the hue in the visible light is yellow, orange, red, blue, green or golden.
10 . The article as claimed in claim 8 wherein the article is in the form of casings of cell-phones, cosmetic articles, cameras, toy articles, flashlights, jewelry, buttons, belt buckles, disco club facilities, casings of music systems, picture frames, wall decorations, gift articles, beverage cans, coatings for protection against forgeries in signage, distinguishing marks, license plates or labels.