Preparing and dispersing surface-modified colour pigments
View Patent ↗A method of preparing a pigment includes the steps of: a) providing a mixture including: a pigment selected from the group of pigments including at least 50 wt % of C.I. Pigment Violet 23, C.I. Pigment Red 146, C.I. Pigment Red 176, C.I. Pigment Red 177, C.I. Pigment Violet 19 and C.I. Pigment Orange 13 based on the total weight of the pigment; alkyl nitrile; and at least one acid selected from the group consisting of sulfuric acid and chlorosulfuric acid, with the acid present in the mixture in amount of more than 2 wt % based on the total weight of the pigment; b) heating the mixture for more than 2 hours to a temperature of at least 70° C.; and c) filtering the mixture and washing the filtrand with a washing liquid containing water until the filtrate has a pH between 4 and 7. Pigments obtainable by the method and non aqueous pigment dispersions are also disclosed.
1. A method of preparing a pigment comprising the steps of:
providing a mixture including:
a pigment, or a mixed crystal of a pigment comprising at least 50 wt % of a total weight of pigment in the mixture, selected from the group of pigments consisting of C.I. Pigment Violet 23, C.I. Pigment Red 146, C.I. Pigment Red 176, C.I. Pigment Red 177, C.I. Pigment Violet 19, and C.I. Pigment Orange 13;
an alkyl nitrile; and
at least one acid selected from the group consisting of sulfuric acid and chlorosulfuric acid, wherein the at least one acid is present in the mixture in an amount more than 2 wt % based on the total weight of the pigment in the mixture;
heating the mixture for more than 2 hours at a temperature of at least 70° C.; and
filtering the mixture and washing a filtrand obtained by the step of filtering with a washing liquid to remove residual acid.
2. The method according to claim 1 , wherein the washing liquid contains an alkyl nitrile selected from the group consisting of acetonitrile, propionitrile, and butyronitrile.
3. The method according to claim 2 , wherein the washing liquid contains water and the filtrand is washed until the filtrate has a pH between 4 and 7.
4. The method according to claim 1 , wherein the alkyl nitrile in the mixture and/or an alkyl nitrile in the washing liquid is selected from the group consisting of acetonitrile, propionitrile, and butyronitrile.
5. The method according to claim 1 , further comprising the step of:
drying the filtrand.
6. The method according to claim 1 , wherein the mixture is heated for at least 8 hours at a temperature of at least 75° C.
7. The method according to claim 6 , wherein the mixture is cooled to a temperature below 45° C. before the step of filtering.
8. The method according to claim 1 , wherein the washing liquid consists of alkyl nitrile or water.
9. The method according to claim 1 , wherein the at least one acid is sulfuric acid, and the sulfuric acid is present in the mixture in amount between 20 wt % and 40 wt % based on the total weight of the pigment.
10. A pigment obtained by the method according to claim 1 .
11. A non-aqueous pigment dispersion comprising:
a non-aqueous dispersion medium;
a polymeric dispersant; and
at least one pigment according to claim 10 .
12. The non-aqueous pigment dispersion according to claim 11 , further comprising a component that is capable of being cured by UV radiation or e-beams.
13. The non-aqueous pigment dispersion according to claim 11 , wherein the non-aqueous pigment dispersion is an inkjet ink.