Preparing and dispersing surface-modified colour pigments
A method of preparing a pigment includes, in order, the steps of: a) providing a pigment containing a nucleophile group under basic conditions; b) reacting the pigment with a compound according to Formula (I): wherein, X is a halogen atom or a tosylate group, and R1 and R2 independently represent an alkyl group; and c) hydrolyzing the R1-O bond and/or the R2-O bond. The obtained pigments can be used in non-aqueous pigment dispersions.
1. A method of preparing a pigment comprising, in order, the steps of:
providing a pigment containing a nucleophile group under basic conditions;
reacting a surface of the pigment with a compound according to Formula (I):
wherein,
X is a halogen atom or a tosylate group; and
R1 and R2 independently represent an alkyl group; and
hydrolyzing the R1-O bond and/or the R2-O bond; wherein
the nucleophile group is selected from the group consisting of an amine group, an amide group, and a vinylogous amide group.
2. The method according to claim 1 , wherein the halogen atom is chlorine.
3. The method according to claim 1 , wherein each of R1 and R2 is independently selected from the group consisting of a methyl group and an ethyl group.
4. The method according to claim 2 , wherein each of R1 and R2 is independently selected from the group consisting of a methyl group and an ethyl group.
5. The method according to claim 1 , wherein both R1 and R2 are a methyl group.
6. The method according to claim 2 , wherein the pigment is a quinacridone pigment.
7. The method according to claim 6 , wherein the quinacridone pigment is selected of the group consisting of C.I. Pigment Violet 19, C.I. Pigment Red 122, C.I. Pigment Red 192, C.I. Pigment Red 202, C.I. Pigment Red 207, and C.I. Pigment Red 209.
8. The method according to claim 6 , wherein the quinacridone pigment is a mixed crystal of two or more quinacridones.
9. The method according to claim 7 , wherein the quinacridone pigment is a mixed crystal containing C.I. Pigment Violet 19 and C.I. Pigment Red 202.
10. The method according to claim 1 , wherein the pigment is a diketopyrrolo-pyrrole pigment.
11. The method according to claim 10 , wherein the diketopyrrolo-pyrrole pigment is selected from the group consisting of C.I. Pigment Orange 71, C.I. Pigment Orange 73, C.I. Pigment Orange 81, C.I. Pigment Red 254, C.I. Pigment Red 255, C.I. Pigment Red 264, C.I. Pigment Red 270, C.I. Pigment Red 272, and mixed crystals thereof.
12. The method according to claim 1 , wherein the method includes the step of mixing the pigment with aceto nitrile before the step of reacting the surface of the pigment with the compound according to Formula (I).
13. The method according to claim 1 , wherein the step of reacting the surface of the pigment with the compound according to Formula (I) does not include dissolving the pigment.
14. The method according to claim 1 , wherein the step of reacting the surface of the pigment with the compound according to Formula (I) includes mixing, but not dissolving, the pigment in a solution.
15. The method according to claim 1 , wherein the surface of the pigment comprises a plurality of pigment molecules.
16. A pigment obtained by the method according to claim 1 .
17. A non-aqueous pigment dispersion including:
the pigment as defined by claim 16 .
18. The non-aqueous pigment dispersion according to claim 17 , further comprising a component that is curable by UV radiation or e-beams.
19. The non-aqueous pigment dispersion according to claim 17 , wherein the non-aqueous pigment dispersion is an inkjet ink.
20. The non-aqueous pigment dispersion according to claim 18 , wherein the non-aqueous pigment dispersion is an inkjet ink.