Heat treatment of martensitic stainless steel after remelting under a layer of slag
A method fabricating a stainless martensitic steel, including electroslag remelting then cooling an ingot of the steel, then at least one austenitic thermal cycle heating the ingot above its austenitic temperature followed by a cooling. During each cooling: if the cooling is not followed by an austenitic thermal cycle, holding the ingot at a holding temperature included in the ferritic-pearlitic transformation nose for a hold time longer than sufficient for transforming the austenite into a ferritic-pearlitic structure in the ingot as completely as possible at the holding temperature; if the cooling is followed by an austenitic thermal cycle, before its minimum temperature falls below the martensitic transformation start temperature, the ingot is either held throughout the period between the two austenitic thermal cycles at a temperature above the austenitic transformation completion temperature on heating, or held at the holding temperature included in the ferritic-pearlitic transformation nose.
1. A method of fabricating a stainless martensitic steel, comprising:
an electroslag remelting of an ingot of steel;
a first cooling of the ingot, wherein before a minimum temperature of the ingot falls below a martensitic transformation start temperature, either
interrupting the first cooling by holding the ingot at a temperature above an austenitic transformation completion temperature on heating until commencement of a subsequent austenitic thermal cycle, or
holding the ingot at a holding temperature included in a ferritic-pearlitic transformation nose for a hold time that is longer than a transformation period sufficient for transforming austenite into a ferritic-pearlitic structure in the ingot as completely as possible at the holding temperature;
subjecting the ingot to at least one austenitic thermal cycle comprising heating the ingot above an austenitic temperature of the ingot and a second cooling step of cooling the ingot,
wherein for the second cooling step:
when the second cooling step is not followed by another austenitic thermal cycle, the method further comprises a second holding wherein the ingot is held at the holding temperature included for the hold time, the second holding being carried out as soon as the temperature of the coolest point of the ingot has reached the holding temperature;
when the second cooling step is followed by another austenitic thermal cycle, before a minimum temperature of the ingot falls below the martensitic transformation start temperature, the method further comprises
either interrupting the second cooling by holding the ingot at a temperature above an austenitic transformation completion temperature on heating until commencement of a subsequent austenitic thermal cycle, or
holding the ingot at the holding temperature for the hold time.
2. The method of fabricating a stainless martensitic steel according to claim 1 , wherein the method is carried out on the steel in one of the following circumstances:
the maximum dimension of the ingot before the first or second cooling is less than approximately 910 mm or the minimum dimension is more than 1500 mm, and the H content of the ingot before electroslag remelting is more than 10 ppm; and
the maximum dimension of the ingot before the first or second cooling is more than approximately 910 mm and the minimum dimension of the ingot is less than approximately 1500 mm, and the H content of the ingot before electroslag remelting is more than 3 ppm.
3. The method of fabricating a stainless martensitic steel according to claim 1 , wherein the slag used in the remelting step has been dehydrated in advance.
4. The method of fabricating a stainless martensitic steel according to claim 1 , wherein carbon content of the steel is less than carbon content below which the steel is hypoeutectoid.
5. The method of fabricating a stainless martensitic steel according to claim 1 , wherein the ingot is held at temperature by placing the ingot in a furnace.
6. The method of fabricating a stainless martensitic steel according to claim 5 , wherein the ingot is placed in the furnace before the temperature of a skin of the ingot falls below the ferritic-pearlitic completion temperature on cooling.
7. A method of fabricating a stainless martensitic steel, comprising:
an electroslag remelting of an ingot of steel; and
a cooling of the ingot,
wherein, for the cooling step, the ingot is held at a holding temperature included in a ferritic-pearlitic transformation nose for a hold time that is longer than a period necessary to transform austenite into a ferritic-pearlitic structure in the ingot at the holding temperature as completely as possible, the holding step being carried out as soon as a temperature of a coolest point of the ingot has reached the holding temperature, the ingot not undergoing an austenitic thermal cycle after the electroslag remelting.
8. The method of fabricating a stainless martensitic steel according to claim 1 , comprising the electroslag remelting, then the first cooling, then the at least one austenitic thermal cycle comprising the heating and the second cooling.