Intaglio printing ink
View Patent ↗There is provided an intaglio printing ink that causes little set-off, exhibits improved chalking resistance, and attains improved print quality, and which permits low-cost prevention of blocking by low-dose irradiation with ultraviolet light. The intaglio printing ink comprises at least an ultraviolet curable composition, an oxidation polymerizable composition, a photopolymerization initiator, an oxidation polymerization catalyst, and a pigment. An acid-modified epoxy-acrylate prepared by reacting a polybasic acid anhydride with an epoxy-acrylate obtained by reacting an acrylate, having two or more acryloyl groups and one carboxyl group in one molecule, with an epoxy compound, having two or more epoxy rings in one molecule, is used as the ultraviolet curable composition.
1. An intaglio printing ink comprising:
at least an ultraviolet curable composition;
an oxidation polymerizable composition;
a photopolymerization initiator;
an oxidation polymerization catalyst; and
a pigment;
wherein the ultraviolet curable composition comprises an acid-modified epoxy-acrylate prepared by reacting a polybasic acid anhydride with an epoxy-acrylate obtained by reacting only an acrylate, having two or more acryloyl groups and one carboxyl group in one molecule, with an epoxy compound having two or more epoxy rings in one molecule,
wherein the acrylate having two or more acryloyl groups and one carboxyl group in one molecule is an acrylate obtained by reacting pentaerythritol acrylate or dipentaerythritol pentaacrylate with succinic anhydride or maleic anhydride,
wherein the polybasic acid anhydride is succinic anhydride or maleic anhydride,
wherein the acid-modified epoxy-acrylate is obtained without removing (meth) acrylic acid residue after reacting the polybasic acid anhydride with the epoxy-acrylate, and
wherein the acid-modified epoxy-acrylate is obtained by reacting the polybasic acid anhydride with the epoxy-acrylate in a ratio of substantially 1 molar of the polybasic acid anhydride to 1 molar of a hydroxyl group of the epoxy-acrylate.
2. A process for producing a printed matter by using the intaglio printing ink according to claim 1 , comprising the steps of casting the intaglio printing ink on a printing plate and transferring the ink on a paper from the printing plate.
3. A printed matter obtained by the process according to claim 2 .