Granted Patent B2

US 9,550,675 · App. 13/502,265 · Granted Jan 24, 2017

Abstract

Claims (23)

1. A method for removing a particulate contaminant material from a particulate mixed lithium metal phosphate material, comprising the steps of:

a) providing a particulate mixed lithium metal phosphate material, including a particulate contaminant material and a fine particulate mixed lithium metal phosphate, having a mass,

b) feeding the particulate mixed lithium metal phosphate material into a fluidizing stage and fluidizing it in the fluidizing stage, wherein the fluidized material in the fluidized stage has an average mass,

c) feeding the fluidized particulate mixed lithium metal phosphate material to a sifting stage and passing it through the sifting stage,

d) discontinuing the feed of the particulate mixed lithium metal phosphate material into the fluidizing stage after 10 to 100 times of mass m have been fed into the fluidizing stage,

e) fluidizing and sifting the material present in the fluidizing stage after discontinuing the feed, until the mass of the material present in the fluidizing stage becomes 10% to 100% of the mass m, and

f) removing the remaining material from the fluidizing stage, wherein

the mass of the particulate mixed lithium metal phosphate material provided in step a) is equal to x·m, in which x>100 and

the sequence of steps b) to f) is repeated until the total mass x·m has been processed.

2. The method according to claim 1 , wherein the feed of the particulate mixed lithium metal phosphate material into the fluidizing stage is discontinued after 30 to 70 times of the mass m have been fed into the fluidizing stage.

3. The method according to claim 1 , wherein the material present in the fluidizing stage is fluidized and sifted after discontinuing the feed, until the mass of the material present in the fluidizing stage becomes 20% to 80% of the mass m.

4. The method according to claim 1 , wherein the mixed lithium metal phosphate is represented by the formula LiMPO 4 , wherein M is selected from at least one metal selected from the group consisting of Fe, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Be, Mg, Ca, Sr, Ba, Al, Zr, La, and rare earth metals.

5. The method according to claim 4 , wherein M is selected from the group consisting of Fe, Mn, Co and Ni and mixtures thereof.

6. The method according to claim 5 , wherein M is Fe.

7. The method according to claim 1 , wherein the fine particulate mixed lithium metal phosphate consists of particles having a D 90 value of at most 25 μm.

8. The method according to claim 7 , wherein the fine particulate mixed lithium metal phosphate particles have a D 90 value of less than 0.8 μm.

9. The method according to claim 1 , wherein the particulate contaminant material is a metallic and/or oxide material.

10. The method according to claim 1 , wherein the fluidizing stage is a fluidized bed chamber.

11. The method according to claim 1 , wherein the method additionally comprises a step b1) of milling the particulate mixed lithium metal phosphate material in a milling step between the steps a) and b) or between b) and c).

12. The method according to claim 11 , wherein the milling step is carried out with a jet mill.

13. The method according to claim 11 , wherein the milling step is carried out in a milling stage and the fluidizing stage, the sifting stage and the milling stage are separate stages.

14. The method according to claim 13 , wherein the fluidizing stage, the sifting stage and the milling stage are integrated in one device.

15. The method according to claim 1 , wherein the fluidizing stage includes an automatic eject valve for removing the content of the fluidizing stage in step f).

Assignments (7)