Heterophasic polypropylene with improved balance between stiffness and transparency
View Patent ↗The present invention relates to a heterophasic polypropylene composition with rather high melt flow rate, high stiffness, acceptable impact properties and an advantageous balance between stiffness and transparency. Still further, the present invention is also directed to a process for producing the inventive polypropylene composition, to an article made of the inventive polypropylene composition and to the use of the inventive polypropylene composition for the production of films and molded articles, such as thin-walled plastic containers for packaging. The inventive heterophasic polypropylene composition comprises at least a propylene homopolymer fraction, a propylene random copolymer fraction, two different ethylene-propylene rubber fractions and an ethylene homo- or copolymer fraction.
1. A heterophasic polypropylene composition comprising
(A) 40-70 wt % of a propylene homopolymer fraction,
(B) 10-50 wt % of a propylene random copolymer fraction,
(C) 1-20 wt % of a first elastomeric ethylene-propylene copolymer fraction,
(D) 1-20 wt % of a second elastomeric ethylene-propylene copolymer fraction, and
(E) 5-25 wt % of an ethylene homo- or copolymer fraction having a density between 905 and 925 kg/m 3 ,
wherein
the ratio of intrinsic viscosity of fraction (A) to the intrinsic viscosity of combined fractions (A) and (B) is smaller than 0.9,
the comonomer content of the propylene random copolymer fraction (B) is up to 5 wt %,
the first elastomeric ethylene-propylene copolymer fraction (C) has a different ethylene content than the second elastomeric ethylene-propylene copolymer fraction (D), and
the MFR 2 of the heterophasic polypropylene composition is at least 20 g/10 min, the values of MFR 2 being measured according to ISO 1133 (230° C., 2.16 kg load).
2. The heterophasic polypropylene composition according to claim 1 , comprising between 45 and 65 wt % of crystal lamellae having a thickness of at least 14.0 nm as measured by stepwise isothermal segregation.
3. The heterophasic polypropylene composition according to claim 1 , wherein the tensile modulus of the heterophasic polypropylene composition is at least 900 MPa.
4. The heterophasic polypropylene composition according to claim 1 , wherein the haze of the heterophasic polypropylene composition is lower than 50% measured on 1 mm injection molded plaque samples.
5. The heterophasic polypropylene composition according to claim 1 , wherein the haze of the heterophasic polypropylene composition is lower than 80% measured on 2 mm injection molded plaque samples.
6. The heterophasic polypropylene composition according to claim 1 , wherein the ratio between the tensile modulus and the haze of the heterophasic polypropylene composition is higher than 27.0, the haze measured on 1 mm injection molded plaque samples.
7. The heterophasic polypropylene composition according to claim 1 , wherein the ratio between the tensile modulus and the haze of the heterophasic polypropylene composition is 15 or higher, the haze measured on 2 mm injection molded plaque samples.
8. The heterophasic polypropylene composition according to claim 1 , wherein the ratio between the ethylene content of fraction (C) and fraction (D) is higher than 1.5.
9. The heterophasic polypropylene composition according to claim 1 , comprising 0.0001-3 wt % of a nucleation agent.
10. A process for the preparation of a heterophasic polypropylene composition comprising the following steps in any sequence:
(i) preparation of 40-70 wt % of a propylene homopolymer fraction (A),
(ii) preparation of 10-50 wt % of a propylene random copolymer fraction (B),
(iii) preparation of 1-20 wt % of a first elastomeric ethylene-propylene copolymer fraction (C), and
(iv) preparation of 1-20 wt % of a second elastomeric ethylene-propylene copolymer fraction (D),
wherein
the ratio of intrinsic viscosity of fraction (A) to the intrinsic viscosity of combined fractions (A) and (B) is smaller than 0.9,
the comonomer content of the propylene random copolymer fraction (B) is up to 5 wt %,
the first elastomeric ethylene-propylene copolymer fraction (C) has a different ethylene content than the second elastomeric ethylene-propylene copolymer fraction (D), and
the MFR 2 of the heterophasic polypropylene composition is at least 20 g/10 min, the values of MFR 2 being measured according to ISO 1133 (230° C., 2.16 kg load),
wherein fractions (A), (B), (C) and (D) are produced in different reactors connected in series and each fraction is produced in the presence of the product produced in the preceding reactor(s) except for the first fraction, and
wherein the process further comprises adding 5-25 wt % of an ethylene homo- or copolymer fraction (E) having a density between 905 and 925 kg/m 3 in a step of compounding.
11. The process according to claim 10 , which further comprises adding 0.0001-3 wt % of a nucleation agent in a step of compounding.
12. An article comprising a heterophasic polypropylene composition according to claim 1 .
13. An article according to claim 12 , wherein the article has been produced by injection moulding.
14. An article according to claim 12 , wherein the article has been produced by injection stretch blow moulding.