Method and system for reducing emissions from evaporative emissions

1. A method of reducing fuel vapor emissions in an automotive evaporative emissions control system for a vehicle comprising steps of:

(a) contacting a vented fuel vapor stream from a fuel tank with a first passive purge canister bed, the passive purge canister bed comprising a vapor adsorbent material and including a passive purge vapor inlet and a passive purge vapor outlet for vapor stream flow;

(b) contacting the vapor stream from the passive purge vapor outlet with an active purge canister bed, the active purge canister bed comprising a vapor adsorbent material;

(c) contacting the active purge canister bed with mechanically convected purge air, wherein the mechanically convected purge air is prevented from flowing through the passive purge canister bed; and

(d) contacting the passive purge canister bed with fresh purge air drawn passively by the fuel tank through the passive purge vapor outlet without first contacting the active purge canister bed;

wherein the vented fuel vapor stream is prevented from being vented to an atmosphere without contacting both the passive purge canister bed and the active purge canister bed.

2. The method of claim 1 further comprising a step of providing a buffer bed section locating between the passive purge canister bed and the active purge canister bed.

3. The method of claim 1 wherein the vapor adsorbent material in the active canister bed, or the passive canister bed, or both the active canister and the passive canister beds includes activated carbon derived from materials selected from the group consisting of wood, peat, coal, coconut, lignite, petroleum pitch, petroleum coke, coal tar pitch, fruit pits, nut shells, sawdust, wood flour, synthetic polymer, and natural polymer having been activated by a process selected from the group consisting of chemical, thermal, and combined chemical/thermal activation processes.

4. The method of claim 1 wherein the vapor adsorbent material in the active canister bed, or the passive canister bed, or both the active canister and the passive canister beds includes inorganic materials selected from the group consisting of zeolites, porous silica, porous alumina, pillared clays, and molecular sieves.

5. The method of claim 1 wherein vapor adsorbent material in the active canister bed, or the passive canister bed, or both the active canister and the passive canister beds includes porous polymers.

6. The method of claim 1 wherein the vapor adsorbent material in the active canister bed, or the passive canister bed, or both the active canister and the passive canister beds are in a form of a honeycomb or monolith shape.

7. The method of claim 6 wherein the active canister bed is heated while the vehicle's engine is in operation.