Nano sensing of temperature using equal intensity double plasmon resonance (EIDPR)
View Patent ↗Technologies are generally described for providing and using a material including: a template molecule; a first cluster of one or more nanoparticles located at a first site on the template molecule; and a second cluster of one or more nanoparticles located at a second site on the template molecule and spaced apart from the first cluster. In some embodiments, the first and second clusters of nanoparticles exhibit a plasmon resonance having a first resonant peak and a second resonant peak.
1. A method of detecting a temperature of an environment, the method comprising:
introducing a material to the environment, the material comprising:
a template molecule;
wherein the template molecule is tryptophan, tryptophan alkyl ester, or methionine;
a first cluster of two or more silver nanoparticles located at a first affinity site on the template molecule, wherein the first affinity site includes at least one of: a nitrogen atom or a sulfur atom; and
a second cluster of two or more silver nanoparticles located at a second affinity site on the template molecule and spaced apart from the first cluster, wherein the second affinity site includes at least one of: a nitrogen atom or a sulfur atom;
wherein the template molecule, the first cluster of two or more silver nanoparticles, and second cluster of two or more silver nanoparticles form a molecular sandwich structure;
irradiating the material so as to cause the first cluster of silver nanoparticles to exhibit a plasmon resonance having a first resonant peak, and the second cluster of silver nanoparticles to exhibit a plasmon resonance having a second resonant peak;
wherein the first resonance peak has a first absorbance value, the second resonance peak has a second absorbance value, and the first and second absorbance values differ by less than 25%;
detecting at least one characteristic of the plasmon resonance of the material; and
determining information indicative of the temperature of the environment based on the at least one detected characteristic of the plasmon resonance of the material;
wherein the temperature is from about 0° C. to about 100° C.
2. The method of claim 1 , wherein the at least one characteristic of the plasmon resonance of the material is selected from the group consisting of: a wavelength of the first resonant peak; a wavelength of the second resonant peak; an extinction coefficient associated with the first resonant peak; and an extinction coefficient associated with the second resonant peak.
3. The method of claim 1 , wherein the at least one characteristic of the plasmon resonance of the material comprises at least two different characteristics selected from the list consisting of: a wavelength of the first resonant peak; a wavelength of the second resonant peak; an extinction coefficient associated with the first resonant peak; and an extinction coefficient associated with the second resonant peak.
4. The method of claim 1 , wherein the at least one characteristic of the plasmon resonance of the material comprises at least three different characteristics selected from the list consisting of: a wavelength of the first resonant peak; a wavelength of the second resonant peak; an extinction coefficient associated with the first resonant peak; and an extinction coefficient associated with the second resonant peak.
5. The method of claim 1 , wherein the at least one characteristic of the plasmon resonance of the material comprises a wavelength of the first resonant peak; a wavelength of the second resonant peak; an extinction coefficient associated with the first resonant peak; and an extinction coefficient associated with the second resonant peak.
6. The method of claim 1 , wherein detecting at least one characteristic of the plasmon resonance of the material comprises detecting an absorbance spectrum of the material.
7. The method of claim 1 , wherein the silver nanoparticles are spherical.