Use of tin catalysts for the production of polyurethane coatings

1. A polyisocyanate polyaddition product obtained from

a) at least one aliphatic, cycloaliphatic, araliphatic and/or aromatic polyisocyanate,

b) at least one NCO-reactive compound,

c) at least one thermolatent inorganic tin-containing catalyst,

d) optionally further catalysts and/or activators other than c),

e) optionally fillers, pigments, additives, thickeners, antifoams and/or other auxiliary substances and additives,

wherein the ratio of the weight of the tin from component c) and the weight of component a) is less than 3000 ppm when component a) is an aliphatic polyisocyanate and less than 95 ppm when component a) is an aromatic polyisocyanate,

wherein the thermolatent inorganic tin-containing catalyst comprises compounds of formula I, II or III:

where n>1,

where n>1,

wherein:

D represents —O—, —S— or —N(R1)-

wherein R1 represents a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or an aromatic or araliphatic radical having up to 20 carbon atoms, which can optionally contain heteroatoms from the group oxygen, sulfur, nitrogen, or represents hydrogen or the radical

or R1 and L3 together represent —Z-L5-;

D* represents —O— or —S—;

X, Y and Z represent identical or different radicals selected from alkylene radicals of the formulae —C(R2)(R3)-, —C(R2)(R3)-C(R4)(R5)- or —C(R2)(R3)-C(R4)(R5)-C(R6)(R7)- or ortho-arylene radicals of the formulae

wherein R2 to R11 independently of one another represent saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or aromatic or araliphatic radicals having up to 20 carbon atoms, which can optionally contain heteroatoms from the group oxygen, sulfur, nitrogen, or represent hydrogen;

L1, L2 and L5 independently of one another represent —O—, —S—, —OC(═O)—, —OC(═S)—, —SC(═O)—, —SC(═S)—, —OS(═O) 2 O—, —OS(═O) 2 — or —N(R12)-,

wherein R12 represents a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or an aromatic or araliphatic radical having up to 20 carbon atoms, which can optionally contain heteroatoms from the group oxygen, sulfur, nitrogen, or represents hydrogen;

L3 and L4 independently of one another represent —OH, —SH, —OR13, -Hal, —OC(═O)R14, —SR15, —OC(═S)R16, —OS(═O) 2 OR17, —OS(═O) 2 R18 or —NR19R20, or L3 and L4 together represent -L1-X-D-Y-L2-,

wherein R13 to R20 independently of one another represent saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or aromatic or araliphatic radicals having up to 20 carbon atoms, which can optionally contain heteroatoms from the group oxygen, sulfur, nitrogen, or represent hydrogen.

2. The polyisocyanate polyaddition product according to claim 1 , wherein D is —N(R1)- and R1 is hydrogen or an alkyl, aralkyl, alkaryl or aryl radical having up to 20 carbon atoms or is the radical

3. The polyisocyanate polyaddition product according to claim 2 , wherein R1 is hydrogen or a methyl, ethyl, propyl, butyl, hexyl, octyl, Ph or CH 3 Ph radical or is the radical

and wherein propyl, butyl, hexyl and octyl represent all isomeric propyl, butyl, hexyl and octyl radicals.

4. The polyisocyanate polyaddition product according to claim 1 , wherein D* is —O—.

5. The polyisocyanate polyaddition product according to claim 1 , wherein X, Y and Z independently of one another are alkylene radicals of the formula —C(R2)(R3)- or —C(R2)(R3)-C(R4)(R5)- or ortho-arylene radicals of the formula

and R2 to R5 independently of one another are hydrogen, alkyl, aralkyl, alkaryl or aryl radicals having up to 20 carbon atoms and R8 to R11 independently of one another are hydrogen or alkyl radicals having up to 8 carbon atoms.

6. The polyisocyanate polyaddition product according to claim 5 , wherein the radicals R2 to R5 independently of one another are hydrogen or alkyl radicals having up to 8 carbon atoms and R8 to R11 independently of one another are hydrogen or methyl.

7. The polyisocyanate polyaddition product according to claim 1 , wherein L1, L2 and L5 independently of one another are —N(R12)-, —S—, —SC(═S)—, —SC(═O)—, —OC(═S)—, —O— or —OC(═O)— and R12 is hydrogen or an alkyl, aralkyl, alkaryl or aryl radical having up to 20 carbon atoms.

8. The polyisocyanate polyaddition product according to claim 7 , wherein L1, L2 and L5 independently of one another are —N(H)—, —N(CH3)-, —N(C2H5)-, —N(C4H9)-, —N(C8H17)-, —N(C6H5)-, —S—, —SC(═S)—, —SC(═O)—, —OC(═S)—, —O— or —OC(═O)—.

9. The polyisocyanate polyaddition product according to claim 1 , wherein L3 and L4 independently of one another are —OH, —SH, —OR13, -Hal or —OC(═O)R14 and the radicals R13 and R14 contain up to 20 carbon atoms.

10. The polyisocyanate polyaddition product according to claim 9 , wherein L3 and L4 independently of one another are Cl—, MeO—, EtO—, PrO—, BuO—, HexO—, OctO—, PhO—, formate, acetate, propanoate, butanoate, pentanoate, hexanoate, octanoate, laurate, lactate or benzoate, wherein Pr, Bu, Hex and Oct represent all isomeric propyl, butyl, hexyl and octyl radicals.

11. A process for the production of the polyisocyanate polyaddition products according to claim 1 , wherein the process comprises

a) reacting at least one aliphatic, cycloaliphatic, araliphatic and/or aromatic polyisocyanate with

b) at least one NCO-reactive compound in the presence of

c) at least one thermolatent inorganic tin-containing catalyst,

d) optionally further catalysts and/or activators other than c) and

e) optionally fillers, pigments, additives, thickeners, antifoams and/or other auxiliary substances and additives,

wherein the ratio of the weight of the tin from component c) and the weight of component a) is less than 3000 ppm when component a) is an aliphatic polyisocyanate and less than 95 ppm when component a) is an aromatic polyisocyanate,

wherein the thermolatent inorganic tin-containing catalyst comprises compounds of formula I, II or III:

where n>1,

where n>1,

wherein:

D represents —O—, —S— or —N(R1)-

wherein R1 represents a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or an aromatic or araliphatic radical having up to 20 carbon atoms, which can optionally contain heteroatoms from the group oxygen, sulfur, nitrogen, or represents hydrogen or the radical

or R1 and L3 together represent —Z-L5-;

D* represents —O— or —S—;

X, Y and Z represent identical or different radicals selected from alkylene radicals of the formulae —C(R2)(R3)-, —C(R2)(R3)-C(R4)(R5)- or —C(R2)(R3)-C(R4)(R5)-C(R6)(R7)- or ortho-arylene radicals of the formulae

wherein R2 to R11 independently of one another represent saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or aromatic or araliphatic radicals having up to 20 carbon atoms, which can optionally contain heteroatoms from the group oxygen, sulfur, nitrogen, or represent hydrogen;

L1, L2 and L5 independently of one another represent —O—, —S—, —OC(═O)—, —OC(═S)—, —SC(═O)—, —SC(═S)—, —OS(═O) 2 O—, —OS(═O) 2 — or —N(R12)-,

wherein R12 represents a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or an aromatic or araliphatic radical having up to 20 carbon atoms, which can optionally contain heteroatoms from the group oxygen, sulfur, nitrogen, or represents hydrogen;

L3 and L4 independently of one another represent —OH, —SH, —OR13, -Hal, —OC(═O)R14, —SR15, —OC(═S)R16, —OS(═O) 2 OR17, —OS(═O) 2 R18 or —NR19R20, or L3 and L4 together represent -L1-X-D-Y-L2-,

wherein R13 to R20 independently of one another represent saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or aromatic or araliphatic radicals having up to 20 carbon atoms, which can optionally contain heteroatoms from the group oxygen, sulfur, nitrogen, or represent hydrogen.

12. A coating composition comprising the polyisocyanate polyaddition product according to claim 1 .

13. A coating obtained from the coating composition according to claim 12 .

14. A substrate coated with coating according to claim 13 .