IP Library Granted Patent US 9,265,268
Granted Patent B2
US 9,265,268 · App. 13/504,306 · Granted Feb 23, 2016

Method of handling bananas

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Quick Facts
Patent No.
US 9,265,268
App. No.
13/504,306
Granted
Feb 23, 2016
Kind
B2
Abstract

There is provided a method of storing bananas comprising the steps of (a) exposing said bananas to an atmosphere that contains one or more ethylene-active compound, and (b) after said step (a), exposing said bananas to an atmosphere that contains one or more cyclopropene compound while said bananas have color stage 2 to 6 on the seven-stage scale, wherein said bananas are kept in a modified-atmosphere package for a time period that includes at least a time interval that lasts for 1 hour, wherein said time interval begins between the conclusion of said step (b) and 72 hours from the conclusion of said step (b), and wherein said modified-atmosphere package is constructed so that the transmission rate of carbon dioxide for the entire package (PCT) is from 2,400 to 120,000 cubic centimeters per day per kilogram of bananas.

Claims (32)

1. A method of handling bananas, comprising:

(a) exposing said bananas to an atmosphere that contains one or more ethylene-active compounds selected from the group consisting of ethylene, ethylene release agents, and compounds with high ethylene activity;

(b) after said step (a), exposing said bananas to an atmosphere that contains one or more cyclopropene compounds while said bananas have a color stage of from 2 to 6 on the seven-stage scale;

wherein said bananas are kept in a modified-atmosphere package for a time period that includes at least a time interval that lasts for 1 hour, wherein said time interval begins between the conclusion of said step (b) and 72 hours from the conclusion of said step (b); and

wherein said modified-atmosphere package is formed from a polymeric film that is microperforated to include holes of 5 micrometers to 500 micrometers in diameter, and said modified-atmosphere package has a transmission rate of carbon dioxide for the entire package (PCT) of 2,400 to 120,000 cubic centimeters per day per kilogram of bananas.

2. The method of claim 1 , wherein said modified-atmosphere package is constructed so that the transmission rate of oxygen for the entire package (POT) is from 2,000 to 100,000 cubic centimeters per day per kilogram of bananas.

3. The method of claim 1 , wherein the ratio of said POT to said PCT is from 1:1.05 to 1:3.

4. The method of claim 1 , wherein 10% to 100% of the surface area of said modified-atmosphere package is polymeric film, and wherein the portion of the surface area of said modified-atmosphere package that is not said polymeric film effectively blocks diffusion of gas molecules.

5. The method of claim 1 , wherein said polymeric film has composition that, if it had thickness of 30 micrometers, would have inherent gas transmission rate of carbon dioxide of 20,000 to 100,000 cm 3 /m 2 -day and inherent gas transmission rate of oxygen of 5,000 to 60,000 cm 3 /m 2 -day.

6. The method of claim 1 , wherein the total area of the perforations in said polymeric film is 50,000 to 6,000,000 square micrometer per kilogram of bananas.

7. The method of claim 1 , wherein said step (b) is conducted while said bananas have a color stage of from 2.5 to 3.5 on the seven-stage scale.

8. The method of claim 1 , wherein said step (b) is conducted by placing said bananas into an airtight container and providing an atmosphere in said airtight container that contains concentration of cyclopropene compound of 0.5 ppb to 100 ppm.

9. The method of claim 1 , wherein said bananas are kept in said modified-atmosphere package for 48 hours or more.

10. The method of claim 1 , wherein in said step (b) said bananas are exposed to the atmosphere that contains one or more cyclopropene compounds at a concentration of 0.5 ppb to 100 ppm.

11. The method of claim 1 , wherein said one or more cyclopropene compounds comprises 1-methylcyclopropene.

12. The method of claim 1 , wherein said bananas are contained in said modified-atmosphere package during step (a).

13. The method of claim 1 , wherein said bananas are contained in said modified-atmosphere package during step (b).

14. The method of claim 1 , wherein said bananas are contained in said modified-atmosphere package prior to said step (b), and wherein said bananas remain in said modified-atmosphere package from the time they are placed therein until 48 hours or more after the conclusion of said step (b).

15. A method of handling bananas, comprising:

(a) exposing bananas to one or more ethylene-active compounds;

(b) after step (a), exposing said bananas to one or more cyclopropene compounds; and

(c) containing said bananas in a modified-atmosphere package for at least one continuous hour after the conclusion of said step (b),

wherein said modified-atmosphere package comprises a polymeric film that is microperforated to include holes of 5 micrometers to 500 micrometers in diameter, and said modified-atmosphere package has a total area of the perforations of 50,000 to 6,000,000 square micrometer per kilogram of bananas.

16. The method of claim 15 , wherein modified-atmosphere package has a transmission rate of carbon dioxide for the entire package (PCT) of 2,400 to 120,000 cubic centimeters per day per kilogram of bananas.

17. The method of claim 15 , wherein said polymeric film has an inherent gas transmission rate of carbon dioxide of 20,000 to 100,000 cm 3 /m 2 -day and an inherent gas transmission rate of oxygen of 5,000 to 60,000 cm 3 /m 2 -day.

18. The method of claim 15 , wherein said polymeric film comprises a material selected from the group consisting of polyolefins, polyvinyls, polystyrenes, polydienes, polysiloxanes, polyamides, vinylidene chloride polymers, vinyl chloride polymers, copolymers thereof, blends thereof, and laminations thereof.

19. A method of handling bananas, comprising:

(a) exposing said bananas to an atmosphere that contains one or more ethylene-active compounds while said bananas are contained in a modified-atmosphere package;

(b) after said step (a) and while said bananas remain in said modified-atmosphere package, introducing at least one cyclopropene compound to an atmosphere outside said modified-atmosphere package and allowing the at least one cyclopropene compound to diffuse through said modified-atmosphere package to contact with said bananas contained therein; and

(c) maintaining said bananas in same modified-atmosphere package for at least one continuous hour after the conclusion of said step (b),

wherein said modified-atmosphere package is formed from a polymeric film that is microperforated to include holes of 5 micrometers to 500 micrometers in diameter.

20. The method of claim 19 , wherein said modified-atmosphere package has a transmission rate of carbon dioxide for the entire package (PCT) of 2,400 to 120,000 cubic centimeters per day per kilogram of bananas, and a transmission rate of oxygen for the entire package (POT) of 2,000 to 100,000 cubic centimeters per day per kilogram of bananas.

Assignments (9)
AGREEMENT OF AGENT RESIGNATION, APPOINTMENT AND ACCEPTANCE & MASTER ASSIGNMENT OF SECURITY DOCUMENTS Recorded Jun 24, 2024
From: JPMORGAN CHASE BANK, N.A.
To: ALTER DOMUS US LLC
Reel/Frame 067914/0941 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT REEL 053316, FRAME 0561 Recorded Apr 3, 2023
From: BANK OF MONTREAL
To: AGROFRESH, INC.
Reel/Frame 063238/0901 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT REEL 036243, FRAME 0244 Recorded Apr 3, 2023
From: BANK OF MONTREAL
To: AGROFRESH, INC.
Reel/Frame 063238/0848 →
SECURITY INTEREST Recorded Mar 31, 2023
From: AGROFRESH INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 063214/0683 →
PATENT SECURITY AGREEMENT Recorded Jul 27, 2020
From: AGROFRESH, INC.
To: BANK OF MONTREAL, AS COLLATERAL AGENT
Reel/Frame 053316/0561 →
SECURITY INTEREST Recorded Jul 31, 2015
From: AGROFRESH INC.
To: BANK OF MONTREAL, AS ADMINISTRATIVE AGENT
Reel/Frame 036243/0244 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 19, 2015
From: DOW GLOBAL TECHNOLOGIES LLC; DOW AGROSCIENCES LLC; ROHM AND HAAS COMPANY
To: AGROFRESH INC.
Reel/Frame 036130/0294 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 17, 2015
From: MENNING, BRUCE
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 035850/0946 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 17, 2015
From: MIR, NAZAR; JAMES, WILLIAM NIXON, JR; URENA-PADILLA, ALVARO R; HOLCROFT, DEIRDRE MARGARET; ROSICHAN, JEFFREY L
To: ROHM AND HAAS COMPANY
Reel/Frame 035933/0959 →