Photopolymer formulation having different writing comonomers
View Patent ↗The invention relates to a photopolymer formulation comprising matrix polymers, writing monomers, and photo initiators, comprising a combination of at least two different writing monomers. The invention further relates to the use of the photopolymer formulation for producing optical elements, in particular for producing holographic elements and images, to a method for producing the photopolymer formulation and to a method for illuminating holographic media made of the photopolymer formulation.
1. A photopolymer formulation comprising matrix polymers, a combination of at least two different writing monomers and photoinitiators, wherein the matrix polymers comprise polyurethanes, and wherein the at least two different writing monomers differ in their respective refractive indices n D 20 , measured at a wavelength of 405 nm, by not more than 0.200 and in each case have a refractive index n D 20 of ≧1.45, measured at a wavelength of 405 nm, wherein the at least two different writing monomers comprise urethane acrylates and/or urethane methacrylates and wherein the photopolymer formulation further comprises plasticizers comprising fluorinated urethanes.
2. The photopolymer formulation according to claim 1 , wherein the at least two different writing monomers differ in their respective refractive indices n D 20 , measured at a wavelength of 405 nm, by not more than 0.100 and have in each case a refractive index n D 20 , measured at a wavelength of 405 nm, of ≧1.50.
3. A process for the preparation of a photopolymer formulation according to claim 2 , comprising mixing matrix polymers, writing monomers, photoinitiators, optionally plasticizers and optionally further additives to form a photopolymer formulation.
4. A process for exposing holographic media comprising the photopolymer formulation according to claim 2 , wherein the process comprises selectively polymerizing the writing monomers by electromagnetic radiation.
5. The photopolymer formulation according to claim 1 , wherein the at least two different writing monomers differ in their respective refractive indices n D 20 , measured at a wavelength of 405 nm, by not more than 0.065 and have in each case a refractive index n D 20 , measured at a wavelength of 405 nm, of ≧1.55.
6. The photopolymer formulation according to claim 1 , wherein the at least two different writing monomers are mono-, di-, tri- and/or polyfunctional.
7. The photopolymer formulation according to claim 6 , wherein the at least two different writing monomers comprise a combination of said monofunctional and of said polyfunctional writing monomers or a combination of said-di- and said trifunctional writing monomers.
8. The photopolymer formulation according to claim 1 , wherein the matrix polymers comprise polyurethanes which are obtained by reacting an isocyanate component a) with an isocyanate-reactive component b).
9. The photopolymer formulation according to claim 1 , wherein the photoinitiators comprise initiators which can be activated by actinic radiation.
10. The photopolymer formulation according to claim 1 , wherein the fluorinated urethanes plasticizers have the formula IV
wherein
n is from 1 to 8 and
R 3 , R 4 , R 5 , independently of one another, represent hydrogen or linear, branched, cyclic or heterocyclic organic radicals which are unsubstituted or optionally also substituted by heteroatoms and wherein at least one of the radicals R 3 , R 4 , R 5 are substituted by at least one fluorine atom.
11. The photopolymer formulation according to claim 10 , wherein R 3 is an organic radical having at least one fluorine atom.
12. The photopolymer formulation according to claim 1 , wherein the photopolymer formulation consists essentially of
10 to 89.999% by weight, of the matrix polymers,
10 to 60% by weight, of the writing monomers,
0.001 to 5% by weight of the photoinitiators and
optionally 0 to 4% by weight, of catalysts,
optionally 0 to 5% by weight, of free radical stabilizers,
optionally 0 to 30% by weight, of plasticizers and
optionally 0 to 5% by weight, of further additives,
wherein the sum of all constituents being 100% by weight.
13. The photopolymer formulation according to claim 1 , wherein the photopolymer formulation consists essentially of
25 to 70% by weight, of the matrix polymers,
25 to 50% by weight, of the writing monomers,
0.001 to 5% by weight of the photoinitiators, and
optionally 0 to 2% by weight, of catalysts,
0.001 to 1% by weight, of free radical stabilizers,
0.1 to 25% by weight, of plasticizers and
0.1 to 5% by weight, of further additives,
wherein the sum of all constituents being 100% by weight.
14. Holographic elements or images formed from the photopolymer formulation according to claim 1 .