METHOD FOR THE PRODUCING ANHYDRIDE-CONTAINING VINYL AROMATIC-VINYL CYANIDE COPOLYMERS HAVING REDUCED DIRT PARTICLE CONTENT
The present invention relates to processes for preparing copolymers A) with a reduced soil particle content, comprising 49.2 to 93.2% by weight of structural units which derive from one or more vinylaromatic monomers (component A1)), 6 to 50% by weight of structural units which derive from one or more vinyl cyanides (component A2)), 0.8 to 7% by weight of structural units which derive from one or more dicarboxylic anhydrides (component A3)) and 0 to 25% by weight of structural units which derive from further copolymerizable monomers (component A4)), where the percentages by weight are each based on the total weight of the structural units which derive from components A1), A2), A3) and A4), and together add up to 100% by weight, by bulk or solution polymerization, it being essential to the invention that the mathematical product of the percentages by weight of the structural units which derive from component A2) and the percentages by weight of the structural units which derive from component A3) in the copolymer A) is in the range from 40% 2 by weight to 65% 2 by weight. The present invention further relates to the copolymers A), to thermoplastic molding materials comprising the copolymers A), to the use of the copolymers A) and of the thermoplastic molding materials, and to the moldings, films, fibers and foams obtainable from the copolymers A) and the thermoplastic molding materials.
1 - 9 . (canceled)
10 . A process for preparing copolymers A) with a reduced soil particle content, comprising
49.2 to 93.2% by weight of structural units which derive from one or more vinylaromatic monomers (component A1)),
6 to 50% by weight of structural units which derive from one or more vinyl cyanides (component A2)),
0.8 to 7% by weight of structural units which derive from one or more dicarboxylic anhydrides (component A3)) and
0 to 25% by weight of structural units which derive from further copolymerizable monomers (component A4)),
where the percentages by weight are each based on the total weight of the structural units which derive from components A1), A2), A3) and A4), and together do not exceed 100% by weight,
by bulk or solution polymerization,
wherein the mathematical product of the percentages by weight of the structural units which derive from component A2) and the percentages by weight of the structural units which derive from component A3) in the copolymer A) is in the range from 40% 2 by weight to 65% 2 by weight.
11 . The process according to claim 10 , wherein the polymerization is initiated thermally and without addition of a polymerization initiator.
12 . The process according to claim 10 , wherein the polymerization is performed as a solution polymerization in the presence of an organic solvent.
13 . The process according to claim 10 , wherein
component A1) is styrene, α-methylstyrene, p-methylstyrene, t-butylstyrene, vinylnaphthalene or a mixture of two or more of these monomers,
component A2) is acrylonitrile, methacrylonitrile or a mixture of these monomers and component A3) is maleic anhydride, methylmaleic anhydride, itaconic anhydride or a mixture of two or more of these monomers.
14 . The process according to claim 10 , wherein the copolymer A) is a styrene-acrylonitrile-maleic anhydride copolymer.
15 . A copolymer A) with reduced soil particle content, preparable by the process according to claim 10 .
16 . A thermoplastic molding material comprising
1 to 95% by weight of the copolymer A) according to claim 15 ,
5 to 99% by weight of one or more thermoplastic polymers B) other than component A),
0 to 50% by weight of one or more rubbers C),
0 to 70% by weight of one or more particulate or fibrous fillers or reinforcers D)
and 0 to 25% by weight of one or more additives E) customary in plastics,
where the percentages by weight are each based on the total weight of components A), B), C), D) and E), and together do not exceed 100% by weight.
17 . A method of use of a copolymer A) according to claim 15 or of a thermoplastic molding material according to claim 16 for producing moldings, films, fibers and foams.
18 . A molding, film, fiber or foam obtainable from the copolymer A) according to claim 15 .
19 . A molding, film, fiber or foam obtainable from a thermoplastic molding material according to claim 16 .