Composite membranes
View Patent ↗Composite membranes, methods or processes for producing composite membranes, and systems utilizing composite membranes are generally described. In some examples, a composite membrane includes a porous halogenated polymer and a conductive polymer coupled to the porous halogenated polymer. In some examples, a process for producing a composite membrane includes coupling a conductive polymer and a porous halogenated polymer.
1. A composite membrane comprising three layers, the composite membrane comprising:
a porous halogenated polymer;
a coupling agent coated on a surface of the porous halogenated polymer, wherein the coupling agent comprises nucleophilic groups; and
a conductive polymer layer including an electrically conductive polymer bound to the coupling agent, wherein:
the conductive polymer and composite membrane have a native hydrophilicity or hydrophobicity when the conductive polymer is in an undoped state;
the conductive polymer comprises a dopant including an acid that enhances the native hydrophilicity of the conductive polymer and the composite membrane;
the conductive polymer layer has a thickness in a range of about 2 μm to about 10 μm; and
a ratio of a weight amount of the conductive polymer relative to the composite membrane is in a range of about 1% to about 30%.
2. The composite membrane of claim 1 , wherein:
the conductive polymer is selected from the group consisting of polypyrrole, polyaniline, polythiophene, polyacetylene, polyaromatic amines, and derivatives thereof; and
wherein the ratio of the weight amount of the conductive polymer relative to the composite membrane is in a range of about 2% to about 10%.
3. The composite membrane of claim 1 , wherein the porous halogenated polymer comprises a fluorinated polymer selected from the group consisting of polytetrafluoroethylene, fluorinated-ethylenepropylene, perfluoroalkoxys, polychlorotrifluoroethylene, ethylene tetrafluoroethylene, and polyvinylidene fluoride.
4. The composite membrane of claim 1 , wherein the hydrophilicity of the conductive polymer is capable of being altered by neutralizing the dopant.
5. The composite membrane of claim 1 , wherein the dopant is neutralized to render the composite membrane hydrophobic.
6. The composite membrane of claim 1 , wherein the conductive polymer comprises an oxidant to enhance the native hydrophilicity of the conductive polymer.
7. The composite membrane of claim 1 , wherein the dopant consists of carboxylic acid, sulfonic acid, straight chain aliphatic carboxylic acids, straight chain aliphatic sulfonic acids, aromatic carboxylic acids, aromatic sulfonic acids, acetic acid, butyric acid, benzoic acid, or toluenesulfonic acid.
8. The composite membrane of claim 1 , wherein the dopant is neutralized by immersing the composite membrane in a solution comprising a compound selected from the group consisting of sodium sulfate, sodium nitrate, lithium perchlorate, potassium sulfate, and potassium nitrate.
9. The composite membrane of claim 6 , wherein the oxidant consists of ammonium persulfate, ferric chloride, ferric nitrate, cerium ammonium nitrate, chloroauric acid, silver nitrate, sodium hypochlorite or hydrogen peroxide.
10. The composite membrane of claim 1 , wherein the coupling agent comprises halogen atoms.
11. The composite membrane of claim 10 , wherein the coupling agent comprises fluorine atoms.
12. The composite membrane of claim 1 , wherein the coupling agent comprises sulfonated groups.