THERMOPLASTIC COMPOSITIONS HAVING IMPROVED FLOWABILITY
The present invention relates to compositions comprising (i) as component (I), at least one molding composition comprising components A and B, where A) is a graft copolymer as component A, and B) is a thermoplastic copolymer as component B; and (ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II) in which R 1 is C 1 -C 10 -alkyl or C 3 -C 8 -cycloalkyl, m is 0, 1, 2, or 3, n is 2, 3, or 4, and R is hydrogen or C 1 -C 30 -alkyl; or the group —(COOR) n forms an anhydride of the formula where it is essential to the invention that component (I) comprises from 11 to 19.9% by weight of component A and from 80.1 to 89% by weight of component B, where each of the % by weight values is based on the entirety of components A and B, and the total of those values is 100% by weight, and also to a process for producing the composition of the invention, to the use of the composition of the invention for producing moldings, foils, foams, or fibers, and to moldings, foils, foams, or fibers comprising the composition of the invention.
1 .- 10 . (canceled)
11 . A composition comprising
(i) as component (I) at least one molding composition comprising components A and B, where
A) is a graft copolymer as component A, comprising
a1) from 30 to 90% by weight, based on component A, of a graft base obtainable via reaction of
a1.1) from 50 to 100% by weight, based on component al, of at least one conjugated diene, and
a1.2) from 0 to 50% by weight, based on component al, of at least one further monoethylenically unsaturated monomer; and
a2) from 10 to 70% by weight, based on component A, of a graft obtainable via reaction of
a2.1) from 60 to 95% by weight, based on component a2, of at least one vinylaromatic monomer,
a2.2) from 5 to 40% by weight, based on component a2, of acrylonitrile, and
a2.3) from 0 to 35% by weight, based on component a2, of at least one further monoethylenically unsaturated monomer in the presence of the graft base a1, and
B) is a thermoplastic copolymer as component B obtainable via reaction of
b1) from 60 to 100% by weight, based on component B, of at least one vinylaromatic monomer,
b2) from 0 to 40% by weight, based on component B, of acrylonitrile, and
b3) from 0 to 40% by weight, based on component B, of at least one further monoethylenically unsaturated monomer;
(ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II)
in which
R 1 is C 1 -C 10 -alkyl or C 3 -C 8 -cycloalkyl,
M is 0, 1, 2, or 3,
n is 2, 3, or 4, and
R is hydrogen or C 1 -C 30 -alkyl;
or
the group —(COOR) n forms an anhydride of the formula
(iii) as component (III), if appropriate, one or more further polymers;
(iv) as component (IV), if appropriate, one or more additives; and
(v) as component (V), if appropriate, one or more fillers and/or reinforcing materials,
wherein component (I) comprises from 11 to 19.9% by weight of component A and from 80.1 to 89% by weight of component B, where each of the % by weight values is based on the entirety of components A and B, and the total of those values does not exceed 100% by weight.
12 . The composition according to claim 11 , wherein the vinylaromatic monomer of component a2.1 is styrene and/or α-methylstyrene.
13 . The composition according to claim 11 , wherein the vinylaromatic monomer of component b1 is styrene and/or α-methylstyrene.
14 . The composition according to claim 11 , comprising
(i) from 95 to 99.99% by weight of component (I);
(ii) from 0.01 to 5% by weight of component (II);
where the entirety of components I and II does not exceed 100% by weight; and
(iii) from 0 to 50% by weight, based on the total weight of components I and II, of component (III);
(iv) from 0 to 50% by weight, based on the total weight of components I and II, of component (IV); and
(v) from 0 to 50% by weight, based on the total weight of components I and II, of component (V).
15 . The composition according to claim 11 , wherein the definitions of components A and B are as follows:
component A:
the graft base a1 is obtainable via reaction of
from 50 to 100% by weight, based on component al, of component all, and
from 0 to 50% by weight, based on component al, of component a1.2; and
the graft a2 is obtainable via reaction of
from 60 to 95% by weight, based on component a2, of component a2.1;
from 5 to 40% by weight, based on component a2, of component a2.2; and
from 0 to 35% by weight, based on component a2, of component a2.3;
in the presence of the graft base a1; and
component B:
the thermoplastic copolymer B is obtainable via reaction of
from 60 to 100% by weight, based on component B, of component b1;
from 0 to 40% by weight, based on component B, of component b.2; and
from 0 to 40% by weight, based on component B, of component b.3.
16 . The composition according to claim 11 , wherein component (I) comprises
from 11 to 19% by weight of component A and
from 80.1 to 89% by weight of component B,
where each of the % by weight values is based on the entirety of components A and B, and
the total of those values does not exceed 100% by weight.
17 . The composition according to claim 11 , wherein component a2 is composed of components a2.1 and a2.2,
wherein:
a2.1 is styrene, α-methylstyrene, or a mixture of these compounds;
a2.2 is acrylonitrile.
18 . The composition according to claim 17 , wherein a2.1 is styrene.
19 . The composition according to claim 11 , wherein component B is composed of components b1 and b2,
where
b1 is styrene, α-methylstyrene, or a mixture of these compounds;
b2 is acrylonitrile.
20 . The composition according to claim 19 , wherein b1 is styrene.
21 . The composition according to claim 11 , wherein component (II) is at least one cyclohexane-1,2-dicarboxylic ester selected from the group consisting of diisobutyl cyclohexane-1,2-dicarboxylate, di(2-ethylhexyl)cyclohexane-1,2-dicarboxylate, diisononyl cyclohexane-1,2-dicarboxylate, and diisodecyl cyclohexane-1,2-dicarboxylate, preferably selected from the group consisting of di(2-ethylhexyl)cyclohexane-1,2-dicarboxylate and diisononyl cyclohexane-1,2-dicarboxylate.
22 . The composition according to claim 21 , wherein component (II) is diisononyl cyclohexane-1,2-dicarboxylate.
23 . A process for producing a composition comprising
(i) as component (I) at least one molding composition comprising components A and B,
where
A) is a graft copolymer as component A, comprising
a1) from 30 to 90% by weight, based on component A, of a graft base obtainable via reaction of
a1.1) from 50 to 100% by weight, based on component al, of at least one conjugated diene, and
a1.2) from 0 to 50% by weight, based on component al, of at least one further monoethylenically unsaturated monomer, and
a2) from 10 to 70% by weight, based on component A, of a graft obtainable via reaction of
a2.1) from 60 to 95% by weight, based on component a2, of at least one vinylaromatic monomer,
a2.2) from 5 to 40% by weight, based on component a2, of acrylonitrile, and
a2.3) from 0 to 35% by weight, based on component a2, of at least one further monoethylenically unsaturated monomer in the presence of the graft base a1, and
B) is a thermoplastic copolymer as component B obtainable via reaction of
b1) from 60 to 100% by weight, based on component B, of at least one vinylaromatic monomer,
b2) from 0 to 40% by weight, based on component B, of acrylonitrile, and
b3) from 0 to 40% by weight, based on component B, of at least one further monoethylenically unsaturated monomer;
(ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II)
in which
R 1 is C 1 -C 10 -alkyl or C 3 -C 8 -cycloalkyl,
m is 0, 1, 2, or 3,
n is 2, 3, or 4, and
R is hydrogen or C 1 -C 30 -alkyl;
or
the group —(COOR) n forms an anhydride of the formula
(iii) as component (III), if appropriate, one or more further polymers;
(iv) as component (IV), if appropriate, one or more additives; and
(v) as component (V), if appropriate, one or more fillers and/or reinforcing materials,
wherein component (I) comprises from 11 to 19.9% by weight of component A and from 80.1 to 89% by weight of component B, where each of the % by weight values is based on the entirety of components A and B, and the total of those values does not exceed 100% by weight;
the process comprising mixing components (I), (II) and, if appropriate, (III) and, if appropriate, (IV) and, if appropriate, (V), in the melt.
24 . The process according to claim 23 , wherein a2.1 is styrene and/or α-methylstyrene.
25 . The process according to claim 23 , wherein b1 is styrene and/or α-methylstyrene.
26 . A method for producing moldings, foils, foams, or fibers comprising utilizing the composition according to claim 11 .
27 . A molding, a foil, a foam, or a fiber comprising the composition according to claim 11 .