Divinylarene dioxide resins

1. A hydrolyzed divinylarene dioxide resin composition comprising the reaction product of (a) a divinylarene dioxide having a mixture of meta and para isomers, and (b) water; wherein the reaction product formed comprises at least a partially hydrolyzed divinylarene dioxide resin composition.

2. The composition of claim 1 , wherein the divinylarene dioxide comprises one or more substituted divinylbenzene dioxides; wherein the one or more substituted divinylbenzene dioxides comprises divinylbenzene dioxide, divinylnaphthalene dioxide, divinylbiphenyl dioxide, divinyldiphenylether dioxide, or mixtures thereof.

3. The composition of claim 1 , wherein the divinylarene dioxide is divinylbenzene dioxide.

4. The composition of claim 1 , wherein the concentration of said divinylarene dioxide ranges from about 99 weight percent to about 1 weight percent based on the combined weight of the composition.

5. The composition of claim 1 , including a hydrolysis catalyst for the hydrolyzation of the divinylarene dioxide resin; wherein the catalyst comprises bismuth chloride, bismuth triflate, tetrabutylammonium bisulfate, tin(IV) porphyrin, iron(III) perchlorate, iron(III) trifluoroacetate, iron(III) chloride, cesium triflate, phosphoric acid, oxalic acid, ion exchange resins, metal phosphates and metal exchanged zeolites or mixtures thereof.

6. The composition of claim 5 , wherein the concentration of said catalyst ranges from about 0.01 weight percent to about 10 weight percent based on the combined weight of the composition.

7. A curable hydrolyzed divinylarene dioxide resin composition comprising (i) at least one hydrolyzed divinylarene dioxide resin composition of claim 1 ; and (ii) at least one curing agent.

8. The curable composition of claim 7 , wherein the concentration of the hydrolyzed epoxy resin ranges from about 99 weight percent to about 10 weight percent based on the combined weight of the composition.

9. The curable composition of claim 7 , wherein the curing agent comprises anhydrides, carboxylic acids, amine compounds, tertiary amines, quaternary ammonium salts, Lewis acids, Lewis acid-amine complexes; or mixtures thereof.

10. The curable composition of claim 7 , wherein the concentration of the curing agent ranges from about 1 weight percent to about 90 weight percent based on the combined weight of the composition.

11. A process for hydrolyzing a divinylarene dioxide epoxy resin comprising reacting (a) a divinylarene dioxide having a mixture of meta and para isomers, (b) water, and (c) optionally, a catalyst; under conditions to provide at least a partially hydrolyzed divinylarene dioxide resin composition.

12. A process for preparing a curable hydrolyzed divinylarene dioxide resin composition comprising admixing (i) a hydrolyzed divinylarene dioxide resin of claim 1 ; and (ii) at least one curing agent.

13. The process of claim 11 , wherein the divinylarene dioxide is divinylbenzene dioxide.

14. The process of claim 13 wherein the reaction product produced from the hydrolysis of divinylbenzene dioxide containing both an organic and liquid phase yields exclusively a dihydrolyzed product.

15. The process of claim 13 , wherein the reaction product formed during hydrolysis using a co-solvent for a single liquid phase reaction yields a monohydrolyzed divinylbenzene dioxide as the primary product.

16. The process of claim 13 , wherein the reaction product produced comprises divinylbenzene dioxide-diglycol.

17. The process of claim 13 , wherein the reaction product formed comprises divinylbenzene dioxide-monoglycol.