High strength hot-rolled steel plate exhibiting excellent acid pickling property, chemical conversion processability, fatigue property, stretch flangeability, and resistance to surface deterioration during molding, and having isotropic strength and ductility
View Patent ↗This high strength hot-rolled steel sheet includes: in terms of percent by mass, C: 0.05 to 0.12%; Si: 0.8 to 1.2%; Mn: 1.6 to 2.2%; Al: 0.30 to 0.6%; P: 0.05% or less; S: 0.005% or less; and N: 0.01% or less, with the remainder being Fe and unavoidable impurities, wherein a microstructure includes specific ranges (in area %) of ferrite phases as well as martensite phases, and a maximum concentration of Al detected by a glow discharge emission spectroscopic analysis is in a range of 0.75 mass % or less in a region from a surface of the steel sheet to a thickness of 500 nm after being acid-pickled.
1. A high strength hot-rolled steel sheet that is superior in an acid pickling property, a chemical conversion processability, a fatigue property, a hole expandability, and a resistance to surface deterioration during forming, and that has isotropic strength and isotropic ductility, the steel sheet consisting of, in terms of percent by mass:
C: 0.05 to 0.12%;
Si: 1.0 to 1.2%;
Mn: 1.6 to 2.2%;
Al: 0.30 to 0.6%;
P: 0.05% or less;
S: 0.005% or less;
N: 0.01% or less; and
the remainder of Fe and unavoidable impurities,
wherein a microstructure comprises: 60 area % or more of ferrite phases; more than 10 area % of martensite phases; and 0 to less than 1 area % of residual austenite phases, or the microstructure comprises: 60 area % or more of ferrite phases; more than 10 area % of martensite phases; less than 5 area % of bainite phases; and 0 to less than 1% of residual austenite phases, and
a maximum concentration of Al detected by a glow discharge emission spectroscopic analysis is in a range of 0.75 mass % or less in a region from a surface of the steel sheet to a thickness of 500 nm after being acid-pickled.
2. A high strength hot-rolled steel sheet that is superior in an acid pickling property, a chemical conversion processability, a fatigue property, a hole expandability, and a resistance to surface deterioration during forming, and that has isotropic strength and isotropic ductility,
the steel sheet consisting of, in terms of percent by mass:
C: 0.05 to 0.12%;
Si: 1.0 to 1.2%;
Mn: 1.6 to 2.2%;
Al: 0.30 to 0.6%;
P: 0.05% or less;
S: 0.005% or less;
N: 0.01% or less;
one or more selected from a group consisting of
Ni: 0.002 to 1.0%,
Ti: 0.001 to 0.5%,
Nb: 0.001 to 0.5%,
Mo: 0.002 to 1.0%,
V: 0.002 to 0.2%,
Cr: 0.002 to 1.0%,
Zr: 0.002 to 0.2%,
Ca: 0.0005 to 0.0050%,
REM: 0.0005 to 0.0200%, and
B: 0.0002 to 0.0030%; and
the remainder of Fe and unavoidable impurities,
wherein a microstructure comprises: 60 area % or more of ferrite phases; more than 10 area % of martensite phases; and 0 to less than 1 area % of residual austenite phases, or the microstructure comprises: 60 area % or more of ferrite phases; more than 10 area % of martensite phases; less than 5 area % of bainite phases; and 0 to less than 1% of residual austenite phases, and
a maximum concentration of Al detected by a glow discharge emission spectroscopic analysis is in a range of 0.75 mass % or less in a region from a surface of the steel sheet to a thickness of 500 nm after being acid-pickled.
3. The high strength hot-rolled steel sheet that is superior in an acid pickling property, a chemical conversion processability, a fatigue property, a hole expandability, and a resistance to surface deterioration during forming, and that has isotropic strength and isotropic ductility according to claim 1 ,
wherein an average length of ferrite crystal grains in a rolling direction is in a range of 20 μm or less in a region from the surface of the steel sheet to a thickness of 20 μm.
4. The high strength hot-rolled steel sheet that is superior in an acid pickling property, a chemical conversion processability, a fatigue property, a hole expandability, and a resistance to surface deterioration during forming, and that has isotropic strength and isotropic ductility according to claim 2 ,
wherein an average length of ferrite crystal grains in a rolling direction is in a range of 20 μm or less in a region from the surface of the steel sheet to a thickness of 20 μm.
5. A high strength hot-rolled steel sheet that is superior in an acid pickling property, a chemical conversion processability, a fatigue property, a hole expandability, and a resistance to surface deterioration during forming, and that has isotropic strength and isotropic ductility, the steel sheet comprising, in terms of percent by mass:
C: 0.05 to 0.12%;
Si: 1.0 to 1.2%;
Mn: 1.6 to 2.2%;
Al: 0.30 to 0.6%;
P: 0.05% or less;
S: 0.005% or less; and
N: 0.01% or less,
with the remainder being Fe and unavoidable impurities,
wherein a microstructure comprises: 60 area % or more of ferrite phases; more than 10 area % of martensite phases; and 0 to less than 1 area % of residual austenite phases, or the microstructure comprises: 60 area % or more of ferrite phases; more than 10 area % of martensite phases; less than 5 area % of bainite phases; and 0 to less than 1% of residual austenite phases, and
a maximum concentration of Al detected by a glow discharge emission spectroscopic analysis is in a range of 0.75 mass % or less in a region from a surface of the steel sheet to a thickness of 500 nm after being acid-pickled.
6. The high strength hot-rolled steel sheet that is superior in an acid pickling property, a chemical conversion processability, a fatigue property, a hole expandability, and a resistance to surface deterioration during forming, and that has isotropic strength and isotropic ductility according to claim 5 ,
wherein the steel sheet further comprises, in terms of percent by mass:
one or more selected from a group consisting of
Cu: 0.002 to 2.0%,
Ni: 0.002 to 1.0%,
Ti: 0.001 to 0.5%,
Nb: 0.001 to 0.5%,
Mo: 0.002 to 1.0%,
V: 0.002 to 0.2%,
Cr: 0.002 to 1.0%,
Zr: 0.002 to 0.2%,
Ca: 0.0005 to 0.0050%,
REM: 0.0005 to 0.0200%, and
B: 0.0002 to 0.0030%.