Liquid crystal display device
The invention is to provide an AM device containing a liquid crystal composition satisfying at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of the nematic phase, a small viscosity, a large optical anisotropy, a large positive dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to and heat, or having a suitable balance regarding at least two of the characteristics, and the AM device having a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth; wherein a liquid crystal display device contains a liquid crystal composition having a positive dielectric anisotropy and containing a specific compound having a large positive dielectric anisotropy as a first component and a specific compound having a small viscosity as a second component.
1. A liquid crystal display device that has an FFS mode as an operating mode of the liquid crystal display device and an active matrix mode as a driving mode thereof, and contains a liquid crystal composition having a positive dielectric anisotropy, wherein the liquid crystal composition contains at least one compound selected from the group of compounds represented by formula (1) as a first component, at least one compound selected from the group of compounds represented by formula (2) as a second component, and at least one compound selected from the group of compounds represented by formula (3-1) and formula (3-2) as a third component, wherein at least one of the third component is a compound selected from a group of compounds represented by formula (3-2), and a ratio of the first component is 10% by weight or more based on the total weight of the liquid crystal composition:
wherein R 1 , R 2 , R 3 , R 4 and R 5 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring A and ring B are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; ring C, ring D and ring E are independently 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine; Z 1 is independently a single bond, ethylene or carbonyloxy; Z 2 , Z 3 and Z 4 are independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; Z 5 is difluoromethyleneoxy; X 1 , X 2 , X 3 and X 4 are independently hydrogen or fluorine; Y 1 is fluorine or trifluoromethoxy; Y 2 is fluorine, chlorine or trifluoromethoxy; m is 1, 2 or 3; and n is 1 or 2.
2. The liquid crystal display device according to claim 1 , wherein the first component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (1-1) and formula (1-2):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
3. The liquid crystal display device according to claim 1 , wherein the second component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-13):
wherein R 2 and R 3 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
4. The liquid crystal display device according to claim 1 , wherein a ratio of the first component of the liquid crystal composition is in the range of 10% by weight to 50% by weight and a ratio of the second component thereof is in the range of 20% by weight to 90% by weight based on the total weight of the liquid crystal composition.
5. The liquid crystal display device according to claim 1 , wherein the third component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (3-1-1) to formula (3-1-29), and formula (3-2-6) to formula (3-2-8):
wherein R 4 and R 5 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
6. The liquid crystal display device according to claim 1 , wherein a ratio of the third component of the liquid crystal composition is in the range of 15% by weight to 60% by weight based on the total weight of the liquid crystal composition.
7. The liquid crystal display device according to claim 1 , wherein the liquid crystal composition further contains at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 6 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring F, ring G, ring H and ring I are independently 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene, tetrahydropyran-2,5-diyl or 2,5-pyrimidine; Z 6 , Z 7 , Z 8 and Z 9 are independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 5 and X 6 are independently hydrogen or fluorine; and Y 3 is fluorine, chlorine or trifluoromethoxy.
8. The liquid crystal display device according to claim 7 , wherein the fourth component of the liquid crystal composition is at least one compound selected from the group of compounds represented by formula (4-1) to formula (4-5):
wherein R 6 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; X 5 , X 6 , X 7 , X 8 , X 9 , X 10 , X 11 , X 12 and X 13 are independently hydrogen or fluorine; and Y 3 is fluorine, chlorine or trifluoromethoxy.
9. The liquid crystal display device according to claim 7 , wherein a ratio of the fourth component of the liquid crystal composition is in the range of 3% by weight to 20% by weight based on the total weight of the liquid crystal composition.
10. A liquid crystal composition, contained in the liquid crystal display device according to claim 1 .
11. The liquid crystal composition according to claim 10 , wherein a maximum temperature of a nematic phase is 70° C. or higher, an optical anisotropy (25° C.) at a wavelength of 589 nanometers is 0.08 or more, and a dielectric anisotropy (25° C.) at a frequency of 1 kHz is 10 or more.