Compound obtained by dimerizing with light irradiation, a compound containing a group having lyophilicity, and a compound containing a group having liquid-repellency
View Patent ↗A problem of the present invention is to prevent a base layer beneath the layer to be irradiated with light from deterioration in property and a functional thin film from deterioration in property as the fine patterning of a functional film is performed with light irradiation. Means for solving the problem is a compound obtained by dimerizing with light irradiation a compound (A) containing a group that has photosensitivity and can be photodimerized and a group having lyophilicity and a compound (B) containing a group that has photosensitivity and can be photodimerized and a group having liquid-repellency.
1. A compound represented by any one formula selected from the group consisting of:
wherein R a s independently represent a hydrogen atom or a substituent, any two adjacent R a s may be coupled with each other to form a ring that is selected from among saturated hydrocarbon rings, unsaturated hydrocarbon rings, aromatic hydrocarbon rings and heterocycles and may have a substituent, at least one of the R a s is a group having lyophilicity, and
R b s independently represent a hydrogen atom or a substituent, any two adjacent R b s may be coupled with each other to form a ring that is selected from among saturated hydrocarbon rings, unsaturated hydrocarbon rings, aromatic hydrocarbon rings and heterocycles and may have a substituent, at least one of the R b s is a group having liquid-repellency.
2. The compound according to claim 1 , wherein the group having lyophilicity is a group represented by formula (1-3):
wherein Z represents —C(═O)O—, —OC(═O)—, —OC(═O)O—, —C(═O)—, —N(R c )—, —C(═O)N(R c )—, —N(R c )C(═O)—, —N(R c )C(═O)N(R c )—, -Ak-C(═O)O—, -Ak-OC(═O)—, -Ak-OC(═O)O—, -Ak-C(═O)—, -Ak-N(R c )—, -Ak-C(═O)N(R c )—, -Ak-N(R c )C(═O)—, -Ak-N(R c )C(═O)N(R c )—, —O—, —S— or -Ak-, Ar 1 represents an aromatic hydrocarbon group having a valence of (1+y1) or a heterocyclic group having a valence of (1+y1), Ak represents an alkylene group having 1 to 12 carbon atoms, R a1 represents a hydrogen atom, a halogen atom, a hydroxyl group, an alkoxy group or an alkyl group, R c represents a hydrogen atom or a substituent, and where there are a plurality of R c s, these R c s may be the same or different, t1 represents 0 or 1, x1 represents 0 or 1, and y1 represents an integer of 1 or more, the plurality of R a1 s may be the same or different, and where there are a plurality of Aks, these Aks may be the same or different.
3. The compound according to claim 1 , wherein the group having liquid-repellency is a group represented by the following formula:
wherein Z represents —C(═O)O—, —OC(═O)—, —OC(═O)O—, —C(═O)—, —N(R c )—, —C(═O)N(R c )—, —N(R c )C(═O)—, —N(R c )C(═O)N(R c )—, -Ak-C(═O)O—, -Ak-OC(═O)—, -Ak-OC(═O)O—, -Ak-C(═O)—, -Ak-N(R c )—, -Ak-C(═O)N(R c )—, -Ak-N(R c )C(═O)—, -Ak-N(R c )C(═O)N(R c )—, —O—, —S— or -Ak-, Ak represents an alkylene group having 1 to 12 carbon atoms, R c represents a hydrogen atom or a substituent, and where there are a plurality of R c s, these R c s may be the same or different, Ar 2 represents an aromatic hydrocarbon group having a valence of (1+y2) or a heterocyclic group having a valence of (1+y2), R b1 represents a monovalent organic group containing a fluorine atom, t2 represents 0 or 1, x2 represents 0 or 1, y2 represents an integer of 1 or more, and where there are a plurality of R b1 s, these R b1 s may be the same or different.
4. The compound according to claim 3 , wherein the group having liquid-repellency is a group represented by the following formula:
wherein Ar 2 , R b1 , Ak, t2, x2 and y2 respectively represent the same meanings as those described above.
5. The compound according to claim 4 , wherein the group having liquid-repellency is a group represented by the following formula:
wherein Ar 2 , Ak, t2, x2 and y2 respectively represent the same meanings as those described above, K represents —O—, —S—, —NH— or —NR—, R represents an alkyl group or an aryl group, k represents 0 or 1, r represents an integer of 0 to 6, s represents an integer of 0 to 16, and where there are a plurality of k's, these k's may be the same or different, where there are a plurality of r's, these r's may be the same or different, and where there are a plurality of s's, these s's may be the same or different.