Organic EL device and method for manufacturing same
View Patent ↗Disclosed is an organic EL device which comprises: a pixel electrode that is arranged on a substrate; a hole injection layer that is arranged on the pixel electrode and has a photocatalytic function; an organic functional layer that is formed on the hole injection layer by a coating method; a bank made of a fluorine-containing resin and defines the region where the organic functional layer is arranged; and a counter electrode that is arranged so as to cover the bank and the organic functional layer. Due to the photocatalytic function of the hole injection layer, the bank residuals can be removed by low-energy ultraviolet light that has a longer wavelength (300-400 nm) than conventional high-energy ultraviolet light that has a short wavelength (254 nm or 172 nm).
1. An organic EL device comprising: a pixel electrode arranged on a substrate; a hole injection layer arranged on the pixel electrode, the hole injection layer made of a metal oxide having a photocatalytic function; an organic functional layer formed on the hole injection layer by coating; a bank made of a fluorine-containing resin, the bank defining a region in which the organic functional layer is arranged; and a counter electrode arranged so as to cover the bank and the organic functional layer, wherein
the hole injection layer and the bank contact each other, and
a fluorine atom concentration on the hole injection layer is 0.1 atom % or less, and an anisole contact angle on a top surface of the bank is 40 to 50°.
2. The organic EL device according to claim 1 , a fluorine atom concentration on the top surface of the bank is 5 to 10 atom %.
3. The organic EL device according to claim 1 , the bank is made in a forward tapered shape, in which a bottom surface of the bank is larger than the top surface of the bank.
4. The organic EL device according to claim 1 , wherein the hole injection layer contains titanium oxide.
5. The organic EL device according to claim 4 , wherein the hole injection layer further contains tungsten oxide.
6. The organic EL device according to claim 4 , wherein the hole injection layer further contains molybdenum oxide.
7. An organic EL display panel comprising the organic EL device according to claim 1 .
8. A method of manufacturing an organic EL device comprising:
providing a substrate;
forming a pixel electrode on the substrate;
forming on the pixel electrode a hole injection layer made of a metal oxide having a photocatalytic function;
forming a bank made of a fluorine-containing resin on the substrate so that at least part of the hole injection layer is exposed;
irradiating the hole injection layer with a ultraviolet light after the bank is formed, the ultraviolet light containing no light having wavelength of less than 300 nm;
forming an organic functional layer on the hole injection layer by coating; and
forming a counter electrode on the organic functional layer.
9. The method of manufacturing the organic EL device according to claim 8 , wherein a peak wavelength of the ultraviolet light is 300 to 400 nm.
10. The method of manufacturing the organic EL device according to claim 8 , wherein the light having wavelength of less than 300 nm is removed from a ultraviolet light with a cut filter.
11. The organic EL device according to claim 1 , a bottom surface of the bank contacts an upper surface of the hole injection layer.