ELECTRONIC BATTERY WITH NANO-COMPOSITE
A supercapacitor-like electronic battery exhibits a conventional electrochemical capacitor structure with a first nanocomposite electrode positioned within said conventional electrochemical capacitor structure. Said nanocomposite electrode shows nano-scale conductive particles dispersed in a electrolyte matrix, said nano-scale conductive particles being coated with a designed and functionalized organic or organometallic compound. A second nanocomposite electrode is positioned within said conventional electrochemical capacitor structure with similar properties. An electrolyte within said conventional electrochemical capacitor structure separates said first from said second nanocomposite electrode. Two current collectors in communication with said first and second nanocomposite electrode complete the electric scheme. A method for fabricating a capacitor includes forming conductive or semiconducting nanoparticles and reacting said nanoparticles with a first designed and functionalized organic or organometallic compound, said reaction forming an organic or organometallic shell surrounding each of said nanoparticles. Said treated nanoparticles are being dispersed into an electrolyte matrix to form a nanocomposite electrode.
1 . A supercapacitor-like electronic battery comprising:
a conventional electrochemical capacitor structure;
a first nanocomposite electrode positioned within said conventional electrochemical capacitor structure, said first nanocomposite electrode having first nano-scale conductive particles dispersed in a first electrolyte matrix, said first nano-scale conductive particles being coated with a first designed and functionalized oranic or organometallic compound;
a second nanocomposite electrode positioned within said conventional electrochemical capacitor structure, said second nanocomposite electrode having second nano-scale conductive particles dispersed in a second electrolyte matrix, said second nano-scale conductive particles being coated with a second designed and functionalized organic or organometallic compound;
an electrolyte within said conventional electrochemical capacitor structure, said electrolyte separating said first nanocomposite electrode from said second nanocomposite electrode;
a first current collector in communication with said first nanocomposite electrode; and
a second current collector in communication with said second nanocomposite electrode.
2 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first nano-scale conductive particles further comprising a first diameter of less than 100 nm; and
said second nano-scale conductive particles further comprising a second diameter of less than 100 nm.
3 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first nano-scale conductive particles having a first concentration such that the percolation threshold of said first nano-scale conductive particles in said first nanocomposite electrode is exceeded; and
said second nano-scale conductive particles having a second concentration such that the percolation threshold of said second nano-scale conductive particles in said second nanocomposite electrode is exceeded.
4 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first designed and functionalized organic or organometallic compound serving to prevent agglomeration of said first nano-scale conductive particles; and
said second designed and functionalized organic or organometallic compound serving to prevent agglomeration of said second nano-scale conductive particles.
5 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first functional group; and
said second designed and functionalized organic or organometallic compound further comprising a second functional group.
6 . The supercapacitor-like electronic battery according to claim 5 , further comprising:
said first functional group being wetted by said first electrolyte matrix; and
said second functional group being wetted by said second electrolyte matrix.
7 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a third functional group; and
said second designed and functionalized organic or organometallic compound further comprising a fourth functional group.
8 . The supercapacitor-like electronic battery according to claim 7 , further comprising:
said third functional group facilitating the attachment of said designed and functionalized organic or organometallic compound to said first nano-scale conductive particles; and
said fourth functional group facilitating the attachment of said designed and functionalized organic or organometallic compound to said second nano-scale conductive particles.
9 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first element exhibiting variable oxidation states; and
said second designed and functionalized organic or organometallic compound further comprising a second element exhibiting variable oxidation states.
10 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first partially unsaturated carbon skeleton; and
said second designed and functionalized organic or organometallic compound further comprising a second partially unsaturated carbon skeleton.
11 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first aliphatic organometallic compound; and
said second designed and functionalized organic or organometallic compound further comprising a second aliphatic organometallic compound.
12 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first aromatic organometallic compound; and
said second designed and functionalized organic or organometallic compound further comprising a second aromatic organometallic compound.
13 . The supercapacitor-like electronic battery according to claim 1 , further comprising:
said first nano-scale conductive particles further comprising carbon powder; and
said second nano-scale conductive particles further comprising carbon powder.
14 . A method for fabricating a capacitor comprising:
forming first conductive or semiconducting nanoparticles;
reacting said first conductive or semiconducting nanoparticles with a first designed and functionalized organic or organometallic compound, said reaction forming a first organic or organometallic shell surrounding each of said first conductive or semiconducting nanoparticles;
incorporating at least one first atom with a variable oxidation state into each of said first organic or organometallic shells surrounding said first conductive or semiconducting nanoparticles;
dispersing said first conductive or semiconducting nanoparticles surrounded by their said first organic or organometallic shells into a first electrolyte matrix to form a first nanocomposite electrode, said first nanocomposite electrode having a first surface and a second surface;
applying an electrolyte to the first surface of said first nanocomposite electrode;
forming second conductive or semiconducting nanoparticles;
reacting said second conductive or semiconducting nanoparticles with a second designed and functionalized organic or organometallic compound, said reaction forming a second organic or organometallic shell surrounding each of said second conductive or semiconducting nanoparticles;
incorporating at least one second atom with a variable oxidation state into each of said second organic or organometallic shells surrounding said second conductive or semiconducting nanoparticles;
dispersing said second conductive or semiconducting nanoparticles surrounded by their said second organic or organometallic shells into a second electrolyte matrix to form a second nanocomposite electrode, said second nanocomposite electrode having a third surface and a fourth surface;
applying said third surface of said second nanocomposite electrode to said applied electrolyte;
placing a first current collector in communication with said second surface of said first nanocomposite electrode; and
placing a second current collector in communication with said fourth surface of said second nanocomposite electrode.
15 . The method according to claim 14 , further comprising sealing said first nanocomposite electrode, said second nanocomposite electrode, said electrolyte, said first current collector and said second current collector.
16 . The method according to claim 14 , further comprising:
said first conductive or semiconducting particles further comprising a first diameter of less than 100 nm; and
said second conductive or semiconducting particles further comprising a second diameter of less than 100 nm.
17 . The method according to claim 14 , further comprising:
said first nano-scale conductive particles having a first concentration such that the percolation threshold of said first conductive or semiconducting particles in said first nanocomposite electrode is exceeded; and
said second conductive or semiconducting particles having a second concentration such that the percolation threshold of said second nano-scale conductive particles in said second nanocomposite electrode is exceeded.
18 . The method according to claim 14 , further comprising:
said first organic or organometallic shell serving to prevent agglomeration of said first conductive or semiconducting particles; and
said second organic or organometallic shell serving to prevent agglomeration of said second conductive or semiconducting particles.
19 . The method according to claim 14 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first functional group; and
said second designed and functionalized organic or organometallic compound further comprising a second functional group.
20 . The method according to claim 14 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first partially unsaturated carbon skeleton; and
said second designed and functionalized organic or organometallic compound further comprising a second partially unsaturated carbon skeleton.
21 . The method according to claim 14 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first aliphatic organometallic compound; and
said second designed and functionalized organic or organometallic compound further comprising a second aliphatic organometallic compound.
22 . The method according to claim 14 , further comprising:
said first designed and functionalized organic or organometallic compound further comprising a first aromatic organometallic compound; and
said second designed and functionalized organic or organometallic compound further comprising a second aromatic organometallic compound.
23 . The method according to claim 14 , wherein said conductive or semiconducting nanoparticles further comprising carbon powder.